有机玻璃板材高低温力学行为试验研究

在温度为80～130℃、应变率为0.001～0.01/s的范围内通过WDW万能试验机对PMMA板材进行了恒应变率下的单轴拉伸试验。结果表明,PMMA板材力学行为具有明显的温度和应变率效应,玻璃态时其真应力-真应变曲线存在明显的非线性;玻璃化转变区以上时其真应力-真应变曲线近似呈线性关系。     

YB-3与DYB-3航空有机玻璃综合性能对比

本论文系统对比了YB-3、DYB-3有机玻璃的基本力学性能、缺口敏感性、耐应力-溶剂性、大气老化寿命等内容。从数据对比来看,DYB-3的冲击韧性、断裂韧度、缺口敏感性、耐应力-溶剂银纹、大气老化等指标明显优于YB-3有机玻璃。     

Higher order structures and toughening mechanisms for simultaneously polymerized polymethacrylate/polyurethane

Amorphous polymer/crystalline polymer blends can be prepared via the simultaneous polymerization of polymethacrylate/polyurethane combinations. The relationship between higher order structures and fracture mechanisms in these blends must be uncovered to elucidate the source of the increased fracture toughness of such materials. The present work involves the production of blended polymethacrylate/polyurethane and assess the internal structures of these specimens using optical and electron microscopy. These observations reveal the presence of both spherulites and elastomeric phases. The spherulites consisting of the polyurethane and are several micrometers in diameter whereas the phase-separated polyurethane elastomeric domains are approximately 100 nm in size. Multiple cracks, crack bridging and plastic deformation around the precrack tips of loaded specimens are evidently responsible for the increased toughness of these blends. The former two phenomena are attributed to the presence of spherulites while the plastic deformation of the methacrylate matrix is ascribed to cavitation of the polyurethane elastomeric phases in response to loading.     

聚甲基丙烯酸甲酯微球表面镀银的研究

用分散聚合法制备聚甲基丙烯酸甲酯(PMMA)微球,以聚乙烯吡咯烷酮(PVP)为分散剂,依次用葡萄糖和硼氢化钠还原银氨溶液,在微球表面化学镀银,得到表面覆银的PMMA-Ag微球,对其进行了表征和分析。结果表明,微球分散性好,银层光滑致密,粒径较均匀,直径约2μm;XRD图谱显示无银以外的其它物相存在;红外光谱显示银与PMMA微球的表面可能存在相互作用,是银还原沉积的影响因素;热重分析表明,PMMA-Ag耐热性有所提高(26℃);制备使用的硝酸银占PMMA微球质量分数为55%时,样品的导电率最大(330 S/cm)。     

有机玻璃在紫外光下老化机理的研究

在紫外光（50℃,313nm波长）条件下对有机玻璃进行了约70d（天）的人工加速老化试验,然后对不同老化时间的有机玻璃试样进行了力学性能测试,并进一步利用凝胶渗透色谱法、示差扫描量热法等手段,分析了老化前后的有机玻璃试样的结构和组成差异,结合老化前后有机玻璃力学性能的变化,定性的揭示了有机玻璃在紫外光条件下的老化规律和老化机理。     

PMMA／TiO2-SiO2高分子杂化材料的制备与表征

用溶胶凝胶法和共混法相结合的方法制备了PMMA/TiO2-SiO2高分子杂化材料。并用傅里叶红外光谱(FT-IR)、原子力显微镜(AFM)和透射电镜(TEM)等测试方法对所得复合微粒进行了表征。结果表明,TiO2-SiO2复合粒子呈核-壳结构,具有Ti-O-Si网络;该核壳结构可均匀地分散在聚甲基丙烯酸甲酯中,形成PMMA/TiO2-SiO2高分子杂化材料。与纯的聚合物材料相比,PMMA/TiO2-SiO2高分子杂化材料有较好的热稳定性、优良的紫外屏蔽和可见光透过特性。     

改性硅气凝胶/聚甲基丙烯酸甲酯乳液的制备与性能研究

采用HMDS(六甲基二硅氮烷)改性硅气凝胶,通过乳液聚合法,将改性硅气凝胶与甲基丙烯酸甲酯(MMA)进行聚合,制得改性硅气凝胶/聚甲基丙烯酸甲酯复合乳液,并且讨论了硅气凝胶的表面状态,以及改性气凝胶质量分数对复合乳液性能的影响。结果表明:HMDS可成功修饰于硅气凝胶表面,将改性硅气凝胶与PMMA乳液体系复合,乳液综合性能呈现较为显著的变化。HMDS修饰的硅气凝胶有助于降低乳液的导热系数,加入3%HMDS修饰的硅气凝胶可以使成膜后的乳液具有较低的导热系数。     

Investigation on replication of microfluidic channels by hot embossing

In this study, effects of embossing temperature, time, and force on production of a microfluidic device were investigated. Polymethyl methacrylate (PMMA) substrates were hot embossed by using a micromilled aluminum mold. The process parameters were altered to observe the variation of replication rate in width and depth as well as symmetry of the replicated microfluidic channels. Analysis of variance (ANOVA) on the experimental results indicated that embossing temperature was the most important process parameter, whereas embossing time and force have less impact. One distinguishing aspect of this study is that, the channels were observed to be skewed to either side of the channel depending on the location of the protrusions on the mold. The mechanism of the skewness was investigated by finite element analysis and discussed in detail. Results showed that the skewness depends on the flow characteristics of the material and could be reduced by increasing the embossing temperature. The best replication rates were obtained at parameter settings of 115°C, 10?kN, and 8?min for the molds with minimum 56?µm wide features of 120?µm depth. We also showed that the fabricated channels could be successfully sealed by solvent-assisted thermo-compressive bonding at 85°C under 5.5?kN force.     

光漂白法制备有机聚合物非线性定向耦合器

研究了用光漂白的方法制备PMMA/DR1聚合物非线性定向耦合器,提出了一种容易的制备方法来得到要求的耦合长度.测量了材料的光学非线性对定向耦合器两臂透过率的影响.实验结果表明由于光学非线性,耦合器的耦合长度随着入射光强度的改变而发生变化.     

PMMA-PET共混体系流变性能

研究了PMMA含量小于7．5％的PMMA—PET共混体系的流变性能．结果表明，共混体系为切力变稀的非牛顿流体，随着共混体系中PMMA组分的增加，非牛顿指数呈减小趋势，粘度有一定下降；在280℃低剪切应力时，ηa随着PMMA组分的增加而上升，在高剪切应力时，则相反；共混体系的粘流活化能基本上都大于纯PET。