Structural characteristics and flammability of low-order coal pyrolysis semi-coke

This study focused on the effects of pyrolysis temperature on the structural characteristics and combustion properties of low rank coal. The combustion performance of semi-coke at different temperatures was studied by using low-temperature pyrolysis technology and non-isothermal thermogravimetric analysis. The variation of functional groups and carbon structure was quantitatively analyzed. The results show that the temperature has a significant effect on the semi-coke structure and flammability. In the middle and low temperature pyrolysis stage, the removal of water, volatile matter and functional groups is mainly carried out, and the degree of condensation and graphitization of carbon atoms is not obvious. The semi-coke performance with a pyrolysis temperature of 1023K is close to that of anthracite. The pyrolysis process is accompanied by the destruction of carbonaceous and the formation of mesopores, which affects the combustion performance. As the temperature increases, the flammability of the semi-coke is lowered, and the chemical structure of the semi-coke is a major factor affecting the flammability. The method of Coast-Redfern integration was used to calculate the kinetic parameters of the semi-coke. As the pyrolysis temperature increases, the activation energy of the combustion reaction increases, which is consistent with the trend of combustion performance change.     

煤矿薄煤层定向钻孔水害探查技术研究

从保德煤矿水文地质条件出发，研究了矿区奥灰水突水危险性，计算了8号煤层底板安全隔水层厚度和突水系数。采用薄煤层定向钻探工艺对保德煤矿81312工作面胶带运输巷道和81313工作面辅助运输巷道底板以下岩层及10号煤层进行水害及隐伏构造探查，探明了8号煤层底板岩层地质构造及富水性，形成了区域薄煤层定向钻孔水害探查方法。研究表明，利用定向钻孔的一孔多用功能超前预抽10号煤层瓦斯，可为矿区安全开采提供保障。     

低阶煤颗粒-气/油泡间的诱导时间研究

为表征低阶煤颗粒-气/油泡间矿化过程的差异,通过Sutherland理论下固体颗粒进入泡沫产品的总概率(E)和浮选速率常数(k)之间关系,并结合低阶煤颗粒-气/油泡的浮选速率试验,求得了低阶煤颗粒-气/油泡间的诱导时间。浮选实验研究表明,在相同的捕收剂消耗量下低阶煤-油泡浮选产率均高于低阶煤-气泡浮选产率。诱导时间测试表明,低阶煤颗粒-油泡间的诱导时间(35 ms)要明显低于低阶煤颗粒-气泡间的诱导时间(93 ms)。上述实验结果表明,油泡表面的疏水性要强于传统浮选气泡表面的疏水性。然而,进一步利用Sutherland理论中固体颗粒进入泡沫产品的总概率和浮选速率常数之间的数学关系,并结合低阶煤颗粒-气/油泡的浮选速率试验求得的低阶煤颗粒-气/油泡间的诱导时间分别为9.67和8.46 ms,其与诱导时间测试仪分别测量的诱导时间差异很大。这主要是由于在实际浮选过程中气/油泡的上升速度分别为23.26和22.68 cm/s,其远高于2015EZ型诱导时间仪测试过程中气/油泡碰撞速度(2.0 cm/s)。因此,诱导时间理论计算表明气泡-颗粒间的碰撞速度对颗粒-气泡间的诱导时间影响很大。上述研究结果表明油泡浮选效果优于传统浮选的内在原因在于低阶煤颗粒-油泡间的诱导时间小于低阶煤颗粒-气泡间的诱导时间。     

高温固定流化床费托合成技术及其产物加工路线

与采用低温费托合成主产油品技术相比，产品更为多元化和高值化的高温费托合成技术在目前市场环境下显示出非常明显的优势。本文综述了高温费托合成技术的发展历程及其最新进展，重点介绍了高温费托合成过程中的核心问题，主要包括高温费托合成工艺、固定流化床反应器、费托合成催化剂；介绍了高温费托合成产物分布与特性，讨论了高温费托合成产物的加工路线，并对高温费托合成煤间接液化的工业应用前景和产业化方向进行了展望。结果表明：高温费托合成技术具有产物附加值高、兼顾油品和化学品、技术发展成熟等优势，产物中轻组分含量高、碳数分布较窄、高附加值的α-烯烃含量高；精细化、高端化、差异化加工是实现高温费托合成产物高值化利用的关键。     

8809工作面过空巷覆岩失稳规律及围岩控制技术研究

为保障8809工作面推进过空巷区域的安全生产,通过对过空巷区域时覆岩变形规律的分析,得出工作面与未支护的空巷间煤柱宽度为14m时,空巷围岩出现失稳。基于分析结果,确定J09-01和J09-02空巷采取锚网索+工字钢梁的支护技术,J09-03和J09-04空巷采用预充填技术,工作面顺利通过补强支护和充填空巷区域。     

Numerical analysis on combustion process and sodium transformation behavior in a 660 MW supercritical face-fired boiler purely burning high sodium content Zhundong coal

CHEMKIN software was used to optimize the reaction mechanism of sodium in flue gas to study the influence of targeted design for purely burning Zhundong (ZD) coal on boiler characteristics. Then, the optimized 32-step elemental reaction was combined with CFD software. An eddy-dissipation concept model considering detailed chemical reactions was used to simulate the transformation behavior of sodium-containing substances. The combustion characteristics of the 660 MW face-fired boiler under various loads were also simulated. The field distribution in the furnace and the migration path of sodium along the track of pulverized coal particles were obtained. The results show that the interference between each burner in the furnace is small at the BMCR load, and the phenomenon of “wind wrapping fire” is distinctly clear. The temperature at furnace outlet is approximately 970.98 °C. At a low load, the combustion in the furnace is stable, and the temperature at the furnace outlet reaches the design value. The sodium present in ZD coal is involved in the reaction after it is released in the form of Na and NaCl. Sodium is present in different forms in the main burner zone, mainly NaCl (67%), NaOH (12%), Na (9%), and Na₂SO₄ (7%). The forms of sodium at the furnace outlet are NaCl (50%), Na₂SO₄ (37%), Na₂Cl₂ (9%) and NaHSO₄ (4%). A small amount of Na₂SO₄ is formed by NaHSO₄ reaction in the main burner zone. It then reacts to form NaSO₄, wherein NaHSO₄ is formed by path 2. Na₂SO₄ is mainly generated in the burnout zone through path 1, and paths 2, 3, and 4 are hardly observed. The findings of this research can provide reference for the design of a purely fired ZD coal boiler and further studies on slagging observed on the heating surface.     

煤/石油焦共气化过程中AAEM的催化转化行为

以富含碱金属及碱土金属的准东煤和石油焦为原料,在热重反应器上分别进行了水蒸气及CO2条件下的共气化实验,探究了AAEM的赋存形态对其转化行为及燃料气化特性的影响规律.研究表明,准东煤与石油焦在水蒸气条件下的共气化反应速率明显快于CO2条件,来自煤中的AAEM促进了石油焦的气化.在CO2气氛中,不同赋存形态矿物的催化作用存在较大差异,盐酸溶态的Ca起主要催化作用,并在气化过程中生成CaS.而在水蒸气气氛中,不同赋存形态矿物的催化作用差异较小,气化过程中含Ca组分主要生成CaO.     

浅谈机电设备维修保养与修旧利废

随着社会经济的发展和科学技术的不断提高,对煤矿机电设备安全和生产效率的要求也越来越高,机电设备折旧与维修关系到企业的经济效益和正常的生产流程。就设备折旧维修工作中存在的问题展开论述,对煤矿机电设备正确、科学地保养、维修、废物利用进行了研究,以期为日后相关工作的顺利进行提供参考和借鉴。     

覆岩隔离注浆充填技术在新义矿业的应用研究

为解决新义矿业地表村庄压煤问题，对该矿11090工作面实施覆岩隔离注浆填充不迁村技术。通过对注浆减沉原理进行分析，结合矿井地质条件，对相关参数进行预计，在对方案可行性、适用性进行判断的基础上，设计了完善的注浆填充技术方案，并对工程效果进行了预计。该技术可有效改善地表沉降现象，避免村庄的迁移，同时解放压煤资源，实现矿区可持续发展。     

红阳二矿12号煤层标志性气体实验研究

针对红阳二矿12号煤层遗煤氧化的规律与特点，有效地进行防灭火工作，掌握采空区中遗煤氧化的速度，对红阳二矿12号煤层进行了煤样升温氧化实验，在温度不断升高的过程中检测出CO与多种烯烃气体，并且在不同温度下煤体析出气体的速度不同，最终选择CO、C₂H₄、C₂H₂作为标志性气体，产生的临界温度分别为59、176、403 ℃。在采空区检测出CO气体，说明采空区遗煤进入快速氧化阶段；检测出C₂H₄气体时，遗煤进入剧烈氧化状态；检测出C₂H₂气体时，说明采空区中已经产生明火，井下人员需要迅速撤离。通过煤体标志性气体的确定，建立12号煤层自燃预警系统，保证井下工作人员的生命安全与能源的充分利用。