不同取样方向AZ31B镁合金应变率效应

采用分离式Hopkinson压杆获得了冲击压缩方向与热轧态A231B镁合金板材法向分别成90°、45°及0°的动态应力一应变曲线，利用光学显微镜及透射电子显微镜对微观组织演化过程进行了分析。结果表明：应变率约为1 200 s-1，压缩方向与板面法向成90°时，孪晶的面积分数随应变量的增大逐渐增加，孪生是主要变形机制，其曲线为凹型；压缩方向与板面法向成45°及0°时，其塑性变形以位错滑移为主，曲线形状分别为近似线型和凸型；应变率约为2 800 s-1，压缩方向与板面法向成90°时，孪晶面积分数迅速增加，大多数晶粒取向发生7改变，有利于滑移，其曲线由较低应变率的凹形变为凸型。     

Improving the sheared edge in the blanking of commercial AZ31 sheet through texture modification

Commercial rolled magnesium sheets of alloys AZ31 (Mg–3 mass%Al–1 mass%Zn) and ZE10 (Mg–1 mass% Zn–<1 mass% Rare Earths) in O-temper condition were used for blanking experiments near room temperature. A serrated fracture surface can be observed in case of AZ31 but not in case of ZE10. During the shearing process of the AZ31 sheet, many micro cracks parallel to the sheet plane are generated in the shearing zone. These micro cracks lead to the formation of loose particles during the shearing operation, which interfere with further processing of the part and incur additional costs by increasing the scrap rate.It is found that the strong basal texture of this alloy is an important reason for the generation of such serrated cracks. In this paper a new method of selective texture modification is described to locally change the mechanical properties of the AZ31 sheet. Subsequent shearing experiments show a significant change in the material behavior, especially regarding the direction of crack propagation, which leads to a better shearing performance. The commonly observed serrated crack does not occur any more after this local treatment and the sheared edge is clearly improved.     

Heterogenization of 12-tungstophosphoric acid on stabilized zeolite Y

Topics in Catalysis - 12-tungstophosphoric acid (PW12) has been supported on dealuminated zeolite Y, containing a secondary pore system with the predominant pore radii of 15 Å. The interaction...     

AZ31镁合金化学镀镍镀层分析

以H_3PO_4+HNO_3酸洗与NH_4HF_2+H_3PO_4活化为前处理工艺,对AZ31镁合金进行化学镀镍研究。应用扫描电子显微镜(SEM)、能谱分析(EDS)、X射线衍射仪(XRD)与X射线光电子能谱分析仪(XPS)等方法对化学镀镍层进行形貌、成分分布、相结构以及元素分析。结果表明:化学镀镍层表面平整光亮,镀层为高磷非晶结构。化学镀镍层表面,镍主要以单质镍(26.75%)、NiO(32.96%)以及Ni(OH)_2(40.29%)形式存在,磷主要以单质磷(20.17%)、PO2-4(17.37%)以及PO_4~(3-)(62.46%)形式存在;化学镀镍层内部,镍基本为金属单质镍,磷主要以单质磷(74.11%)以及PO_4(2-)(25.89%)形式存在。     

固相再生AZ31B镁合金的组织与力学性能

在不同的挤压温度和挤压比下,将AZ31B镁合金机加屑冷压后热挤压固结而再生镁合金。与铸锭挤压合金对比,从动态再结晶组织与屑间结合情况两个主要方面分析了加工工艺对再生合金力学性能的影响。随着挤压温度升高,再生合金的极限抗拉强度和延伸率先增加而后降低。随挤压温度升高,晶粒长大与屑间结合增强的相反作用共同导致了再生合金力学性能的变化。当挤压比从4:1 增加到 44:1,晶粒细化且屑间结合增强,使再生合金的抗拉强度增加。而当挤压比高于25:1时,由于显著的形变强化作用导致延伸率下降。     

Influence of rolling route on microstructure and mechanical properties of AZ31 magnesium alloy during asymmetric reduction rolling

Four different routes of asymmetric reduction rolling were conducted on AZ31 magnesium alloy to investigate their effect on the microstructure evolution and mechanical properties. Route A is the forward rolling; while during routes B and C the sheets are rotated 180° in rolling direction and normal direction, respectively; route D is the unidirectional rolling. The strain states of rolled sheets were analyzed by the finite element method, while the microstructure and texture were observed using optical microscopy, X-ray diffraction and electron back-scattered diffraction techniques, and the mechanical properties were measured by tensile test. The results show that route D produced the largest effective strain. Compared with other samples, sample D exhibited a homogeneous microstructure with fine grains as well as a weak and tilted texture, in corresponding, it performed excellent tensile properties, which suggested that route D was an effective way to enhance the strength and plasticity of AZ31 sheet.     

Fault-tolerant hybrid epoxy-silane coating for corrosion protection of magnesium alloy AZ31

In this work, a hybrid epoxy-silane coating was developed for corrosion protection of magnesium alloy AZ31. The average thickness of the film produced by dip-coating procedure was 14 μm. The adhesion strength of the epoxy-silane coating to the Mg substrate was evaluated by pull-off tests and was found to be higher than 16 MPa both in dry and wet conditions. The hybrid epoxy-silane coating showed high corrosion resistance both when intact and when punched through by a needle. The low frequency impedance of intact coating was higher than 1 GΩ cm² after one month of immersion in 3.5% NaCl solution. Both, artificially induced defects and corrosion sites that appeared on the metal surface did not propagate. Their passivation behavior, that we call fault-tolerance, was observed by EIS, SVET-SIET and SEM-EDS. It was ascribed to the good adhesion, high coating integrity and corrosion inhibiting effect provided by diethylenetriamine used as epoxy hardener.     

乙二胺四乙酸对镁合金阳极氧化膜的影响

将AZ31镁合金在NaOH、Na2SiO3和Na2B4O7的电解液中进行阳极氧化,考察了乙二胺四乙酸添加剂对阳极氧化膜性能的影响。用扫描电镜观察阳极氧化膜形貌,用X-射线衍射和自带能谱仪对膜层的相组织和元素含量进行分析,用交流阻抗测试氧化膜的耐蚀性能。结果表明,氧化膜主要由Mg O组成,膜层中出现了乙二胺四乙酸的特征元素C和N,Mg Si O3的衍射峰受到抑制。阳极氧化过程中的起弧电压随乙二胺四乙酸含量的增加呈上升的变化趋势。随着乙二胺四乙酸含量的增加,膜层耐蚀性先提高后降低。乙二胺四乙酸质量浓度为7.5 g/L时氧化膜具有最大的阻抗,最优的耐蚀性能。     

AZ31B镁合金低温切削的建模与仿真

表面完整性对机械部件的性能和寿命有很大的影响,而它本身则受加工技术的影响。为了减少实验成本和时间,数值模拟仿真的运用尤其是有限元法的应用和研究不断增强。在该项目中,在ABAQUS有限元软件环境下开发二维正交切削模型,利用材料的Johnson-Cook本构模型和破坏模型,使用专门设计的实验装置确定摩擦和热对流系数。此模型的应用不仅可以预测通过低温加工的AZ31B镁合金的热-力学场,还能够预测已加工表面的残余应力分布。该模型被用来研究加工的切削条件(包括刀具几何参数和冷却条件)对工件加工表面残余应力分布的影响。