Study on Effect of Flux on CeMgAl11O19：Tb^3＋ Phosphor

High calcination temperature is an important factor in the preparation process of CeMgAl11O19:Tb^3 . To decrease the temperature, different fluxes (H3BO3, MgF2 and AlF3) were tested in order to compare their influence on the luminescence property and particle size distribution of CeMgAl11O19: Tb^3 . The result shows that when the content of MgF2 is 0.1 mol/mol, the intensity of luminescence can attain a maximum. Furthermore, MgF2 can improve the particle size quality of the phosphor. So MgF2 can take the place of the conventional flux H3BO3 to prepare high quality CeMgAl11O19:Tb^3 phosphor. In addition, the relation between phosphor property and content of AlF3 was also studied. The crystal structure of the phosphor was analyzed by XRD method. The phase composition analysis shows that the reason of decrease of the brightness of CeMgAl11O19:Tb^3 phosphor is the emergence of TbAlO3 and α-Al2O3 during the preparation process.     

晶界富集元素和沉淀相对1Cr11Ni2W2MoV钢性能的影响

富集于晶界的有害元素导致电渣重熔的１Ｃｒ１１Ｍ２Ｗ２ＭｏＶ钢韧性严重下降，它是该钢“６００℃；回火脆性”的主要诱因；颗粒细小、均布于基体和晶界的Ｍ＿（２３）Ｃ＿６沉淀相，使１Ｃｒ１１Ｍ２Ｗ２ＭｏＶ钢具有优良的抗点蚀、应力腐蚀和蠕变性能；反之，颗粒粗大的Ｍ＿（２３）Ｃ＿６晶界沉淀相会使该钢的上述性能严重下降。为此建议修改目前仍推荐的５４０～６００℃不合理的回火制度。     

西门子S7-200系列PLC在串行通信上的实现

本文介绍了在自由端口模式下利用S7-200系列PLC实现串行通信的分析与研究,讨论了通信过程中电缆切换时间、异或校验及起始字符与数据字符易混淆等问题,并给出了主从通信方式下的编程实例.