The effect of citrate esters as plasticizers on the thermal and mechanical properties of poly(methyl methacrylate)

Plasticizers play a key role in the formulation of polymers and in determining their physical properties and processability. This study examines the effects of citrate esters, triethylcitrate, and triacetine as plasticizers on the thermal and mechanical properties of poly(methyl methacrylate). The samples were characterized by differential scanning calorimetry, dynamical mechanical analysis, and mechanical testing under different plasticizer contents. Both citrate esters proved to be effective as plasticizers, DSC data for the triacetine additive fits with Fox equation. Microstructure and relaxation properties were studied by dynamic mechanical analysis where loss modulus shows clearly that absorbed plasticizer shifts the α‐transition to lower temperature and β‐relaxations associated to ester side groups are unchanged even up to 30 wt % plasticizer. Mechanical properties were evaluated with an Instron testing machine. Both additives produced (1) an initial plasticization, with a decrease in tensile strength and modulus; (2) an antiplasticization, reflected as an increase in tensile strength; and modulus and (3) a final plasticization, with a notable decrease in tensile strength and modulus and an increase in elongation where a 35 wt % of triethylcitrate added to the poly(methyl methacrylate) increased in 200% its elongation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Comparison of color gamuts among several types of paper with the same printing technology

In this work, we have studied the relationship among the colorimetric properties of different types of paper, having different finishing and grammage. Their color reproduction capability has also been analyzed by using the same printing technology (inkjet printing). On the one hand, we have plotted CIELAB data under the illuminant D50 into constant lightness and hue‐angle planes to be compared with MacAdam limits and with Pointer's real‐world surface color. On the other hand, we have calculated the volume gamut of the color solid associated to each color paper gamut. Analyzing the results, we have checked that there is not any clear relationship among the colorimetric properties of paper (for instance, CIE whiteness index, etc.) and the color gamut volume associated. However, the colorimetric parameters associated to the printed sample showed a quite good linear correlation between the minimum lightness (or the maximum blackness value) of the printed color chart and the color gamut volume. In particular, the greatest color gamut volume corresponds to the glossy papers taking into account this correlation for inkjet printing. © 2009 Wiley Periodicals, Inc. Col Res Appl, 34, 330–336, 2009     

Optimal allocation of bioassays in the case of parametrized covariance functions: an application to Lung’s retention of radioactive particles

In this paper, we investigate the effect of employing a parametrized covariance function in a regression experiment on corresponding optimum designs. We demonstrate these effects in the framework of a real example for measuring the lung’s retention of radioactive particles. Also, two different covariance functions are considered, and it is shown that this choice can play a crucial role.      

Acidic Activated Carbons: An Efficient Catalyst for the Epoxide Ring-Opening Reaction with Ethanol

The epoxides (styrene oxide and 1,2-epoxyhexane) reaction with ethanol was carried out, catalysed with acidic activated carbons. The reactions were carried out under microwave irradiation. In the 1,2-epoxyhexane reaction, high yields were attained in some of the reaction conditions tested, although the regioselectivity was not high. For the styrene oxide reaction, the conversion was higher and the regioselectivity was high in most cases. For comparison, the reactions have been also performed in a batch reactor system under thermal activation.     

Theoretical considerations on small color differences ascribed to the standard observer made on the basis of individual color‐matching functions

An analytical method to determine how color‐matching functions influence the perception of chromaticity differences is proposed. We show that, as a consequence of the observer metamerism, a metameric color‐match perceived by one observer may appear to be a significant mismatch to a different observer. It is also shown that, on average, the differences between the color‐matchings made by two different observers can be estimated to be in the order of 2 CIELAB units. © 2009 Wiley Periodicals, Inc. Col Res Appl, 34, 194–200, 2009     

Effect of treatment with α‐galactosidase,tannase or a cell‐wall‐degrading enzyme complex on the nutritive utilisation of protein and carbohydrates from pea (Pisum sativum L.) flour

The effect of treatment with α‐galactosidase, tannase or a cell‐wall‐degrading enzyme complex under optimal conditions of pH, temperature and length of incubation time on the chemical composition and nutritive utilisation of protein and carbohydrates from pea (Pisum sativum L.) flour was studied. Soaking of pea flours in combination with enzyme treatment led to reductions of 77–90% in the levels of α‐galactosides, and of 60–80% in the levels of trypsin inhibitor activity, increasing the content of total available sugars, which was highest in the pea flour treated with the cell‐wall‐degrading enzyme complex. All the treatments assayed caused a significant improvement in daily food intake, whereas the nutritive utilisation of protein was not increased in any of the pea products tested when compared to the raw pea flour. However, all the soaking and enzymatic treatments led to a significant improvement in daily weight gain associated with a higher dietary intake of food and total available sugars. Copyright © 2007 Society of Chemical Industry     

Surface application of calcium‐containing gels to improve quality of late maturing peach cultivars

BACKGROUND: A strategy to supply Ca directly to fruits as a tool for improving peach quality has been devised and tested under field conditions. Since peaches in the area of study (Calanda, Spain) are routinely bagged shortly after thinning, a method based on the application of Ca gels to the fruit surface was introduced. The effect of surface treatments was assessed in terms of quality, nutrient balance and surface deposition. RESULTS: Application of Ca‐containing formulations increased mesocarp and exocarp Ca concentrations, providing evidence for the penetration of Ca through the peach skin. Surface Ca treatments had a particular mode of deposition and in some instances improved the shelf life of fruits without affecting their quality. CONCLUSION: Surface treatment with Ca‐containing gels appears to be a viable approach to increase fruit Ca, quality and storability of bagged peach cultivars and should be optimised in future studies. Copyright © 2009 Society of Chemical Industry     

Timing error estimation for baseband multicarrier modulation

In this paper, the topic of timing error estimation for baseband discrete multitone modulation is addressed in the context of high‐speed digital subscriber line applications. To the authors' best knowledge, this problem is sparsely and not in depth treated in the literature. In this study the modified Cramer–Rao lower bound is derived, two conventional estimators are considered and a new one is proposed. Behavior of these estimators is evaluated in terms of bias, variance and computational complexity in a wide variety of scenarios, concluding that the proposed estimator appears to be superior in all instances. Copyright © 2008 John Wiley & Sons, Ltd.