Effect of the addition of rare earths on the activity of alumina supported copper cobaltite in CO oxidation,CH4 oxidationand NO decomposition

The effect of the addition of small amounts of rare earths(Ln=La, Ce, Nd and Gd) to alumina supported copper-cobalt spinel oxide on the catalysts efficiency in CO and CH4 oxidation and in NO decomposition was investigated. Samples of Ln/Cu Co/Al catalyst were prepared and characterized by X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), atomic absorption spectroscopy(AAS), scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS), H2-temperature-programmed reduction(H2-TPR), electron paramagnetic resonance(EPR) spectroscopy and low temperature nitrogen adsorption. The results showed that the addition of rare earths changed the surface state of the alumina supported copper-cobalt spinel catalyst. As a result, partial reduction of copper species was observed as well as migration of these species between the surface and the bulk. The Ln/Cu Co/Al catalysts behaved differently in oxidation and reduction processes. In oxidation processes where oxide structure was important, Ce/Cu Co/Al and Nd/Cu Co/Al were the most active catalysts. The catalyst Ce/Cu Co/Al was the most active in the oxidation reactions because of the availability and favorable surface distribution of the redox couples Cu+/Cu2+ and Ce3+/Ce4+. In NO decompostion, Ln-modified catalysts significantly improved the selectivity of the process to N2.     

Critical parameters near the ferromagnetic-paramagnetic phase transition in La0.67–xYxBa0.23Ca0.1MnO3 compounds（x=0.10 and x=0.15）

The critical properties of the mixed manganite La0.67–x Y x Ba0.23Ca0.1Mn O3 with x=0.10 and x=0.15 around the paramagnetic(PM)-ferromagnetic(FM) phase transition were investigated through various techniques. These involved modified Arrott plots, Kouvel-Fisher method and Widom scaling relation. Magnetic data, analyzed in the critical region, using the above methods, yielded the critical exponents for(x=0.10) La0.57Y0.10Ba0.23Ca0.1Mn O3(β=0.312±0.002 and γ=1.147±0.003 at T C=299.23±0.05 K). Moreover, the estimated critical exponents of(x=0.15) La0.52Y0.15Ba0.23Ca0.1Mn O3 were β=0.286±0.004 and γ=0.943±0.002 at T C=289.53±0.06 K. The critical exponents’ values were close to the theoretical values of 3D-Ising model and tricritical mean-field model. These results suggested that the present composition should be close to a tricritical point in the La0.67–x Y x Ba0.23Ca0.1Mn O3 phase diagram. Expressing the field dependence as ΔS M∝H n allowed us to establish a relationship between the exponent n and the critical exponents of the material and to propose a phenomenological universal curve for the field dependence of ΔS M.     

承钢精粉供应模式探索

承钢探索合理的精粉供应模式,解决了原料场地储存能力小,使用精粉矿点多、成分复杂的不利影响。通过精粉分类、前延管理、系统监控等手段,实现了混合料质量稳定,为烧结系统提供质量稳定的混合料。在目前严峻的市场条件下,探索以管理手段代替占用大量资金的传统料场管理模式的可行性。     

铁素体渗氮工艺模拟

纯铁的莱勒图被广泛用于选择合金钢的渗氮工艺。本文首次采用计算热力学来确定AISI 4140钢的莱勒图。研究表明，AISI 4140钢的莱勒图与纯铁的存在明显差异。对AISI 4140钢进行了渗氮试验，目的是验证计算热力学的预测结果。扫描电镜结果显示化合物层中存在两种相，利用透射电镜对化合物层与扩散层界面的研究结果证实了γ′-Fe4N和ε-Fe2－3（C，N）相的共存。这些试验结果与用计算热力学建立的AISI 4140钢莱勒图高度吻合。     

北京城市发展社情民意调查研究与分析

社情民意调查研究是了解民情、民智的一种研究方法。本文通过调查居民对北京城市发展的感受和建议,分析成因,提出建议。     

紫外消毒剂量计算及其对水质指标的影响

建立紫外消毒计算流体力学数值模拟技术(CFD)模型,用于模拟供水管网中水体和微生物群落的关系,通过计算该模型的UV剂量,并基于4种UV剂量(138.26、260.88、273.91 mJ/cm~2和471.64 mJ/cm~2)开展饮用水UV消毒试验,研究饮用水消毒前后主要水质指标TOC、AOC在不同UV剂量下的变化,评估饮用水的微生物风险。试验结果表明:UV消毒后出水AOC浓度随UV剂量的增加而增大;高UV剂量(471.61 mJ/cm~2)可分解水中的有机物,从而降低出水TOC;高UV剂量在降低TOC浓度的同时,将大分子有机物分解为小分子有机物,从而增大了AOC占TOC的相对比例。试验结果为后续饮用水安全消毒研究提供理论与技术支持。     

基于实车状态的发动机均值模型研究

基于实车状态下发动机的测试运行参数，提出了一种改进发动机均值模型仿真精度的方法。首先基于五电机台架对实车搭载环境下的一款自然吸气发动机进行了性能测试，分别获得发动机水温、发动机转速、发动机缸内压力、进气道压力和温度、进气歧管压力和温度、燃油体积流量、发动机飞轮端扭矩、排气歧管压力和温度、排气歧管过量空气系数、三元催化后排气压力和温度等参数；然后运用Amesim/MATLAB软件联合仿真对发动机进行了基于实车搭载环境边界下的数值建模和模型标定。研究结果表明，标定后的发动机均值模型预测结果与实际测试结果最大差值可以控制在8%以内。     

PUR发动机装饰罩表面处理有效提升整车NVH性能

PUR发泡发动机装饰罩已经成为汽车行业的一个成熟产品,和普通发动机装饰罩相比,有效提升了整车NVH性能。为了进一步提升整车NVH性能,研究了内表面针刺和去除内结皮,2种工艺的PUR发泡发动机装饰罩对整车NVH性能的影响。首先从有无表面结皮和材料厚度,2方面对原材料的吸声系数进行测试,然后从零件外表面皮纹腐蚀和内表面针刺处理、去除内表面结皮对PUR发泡发动机装饰罩完成了零部件NVH性能测试。在此基础上,完成了整车NVH性能测试。研究结果表明,内表面针刺处理和去除内表面结皮均能有效提升整车NVH性能,其中,针刺处理的效果更显著。