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91.
Bryan D. Paulsen Ruiheng Wu Christopher J. Takacs Hans-Georg Steinrück Joseph Strzalka Qingteng Zhang Michael F. Toney Jonathan Rivnay 《Advanced materials (Deerfield Beach, Fla.)》2020,32(40):2003404
The structure and packing of organic mixed ionic–electronic conductors have an especially significant effect on transport properties. In operating devices, this structure is not fixed but is responsive to changes in electrochemical potential, ion intercalation, and solvent swelling. Toward this end, the steady-state and transient structure of the model organic mixed conductor, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), is characterized using multimodal time-resolved operando techniques. Steady-state operando X-ray scattering reveals a doping-induced lamellar expansion of 1.6 Å followed by 0.4 Å relaxation at high doping levels. Time-resolved operando X-ray scattering reveals asymmetric rates of lamellar structural change during doping and dedoping that do not directly depend on potential or charging transients. Time-resolved spectroscopy establishes a link between structural transients and the complex kinetics of electronic charge carrier subpopulations, in particular the polaron–bipolaron equilibrium. These findings provide insight into the factors limiting the response time of organic mixed-conductor-based devices, and present the first real-time observation of the structural changes during doping and dedoping of a conjugated polymer system via X-ray scattering. 相似文献
92.
Rajiv K. Bedi Dr. Danzhi Huang Stefanie A. Eberle Dr. Lars Wiedmer Dr. Pawel Śledź Prof. Amedeo Caflisch 《ChemMedChem》2020,15(9):744-748
The RNA methylase METTL3 catalyzes the transfer of a methyl group from the cofactor S-adenosyl-L-methionine (SAM) to the N6 atom of adenine. We have screened a library of 4000 analogues and derivatives of the adenosine moiety of SAM by high-throughput docking into METTL3. Two series of adenine derivatives were identified in silico, and the binding mode of six of the predicted inhibitors was validated by protein crystallography. Two compounds, one for each series, show good ligand efficiency. We propose a route for their further development into potent and selective inhibitors of METTL3. 相似文献
93.
Xiuhui Huang Junfeng Li Jun Wang Zeqiu Li Jiayin Xu 《Frontiers of Chemical Science and Engineering》2020,14(4):534
In the last decades, many reports dealing with technology for the catalytic combustion of methane (CH4) have been published. Recently, attention has increasingly focused on the synthesis and catalytic activity of nickel oxides. In this paper, a NiO/CeO2 catalyst with high catalytic performance in methane combustion was synthesized via a facile impregnation method, and its catalytic activity, stability, and water-resistance during CH4 combustion were investigated. X-ray diffraction, low-temperature N2 adsorption, thermogravimetric analysis, Fourier transform infrared spectroscopy, hydrogen temperature programmed reduction, methane temperature programmed surface reaction, Raman spectroscopy, electron paramagnetic resonance, and transmission electron microscope characterization of the catalyst were conducted to determine the origin of its high catalytic activity and stability in detail. The incorporation of NiO was found to enhance the concentration of oxygen vacancies, as well as the activity and amount of surface oxygen. As a result, the mobility of bulk oxygen in CeO2 was increased. The presence of CeO2 prevented the aggregation of NiO, enhanced reduction by NiO, and provided more oxygen species for the combustion of CH4. The results of a kinetics study indicated that the reaction order was about 1.07 for CH4 and about 0.10 for O2 over the NiO/CeO2 catalyst. 相似文献
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为了鉴别不同品牌矿泉水标注水源地信息真伪,对11种不同品牌饮用水的氢氧稳定同位素(δD和δ18 O)进行测定。结果表明,水平衡法(GasBench-IRMS)和高温转化法(TC/EA-IRMS)的测定结果一致性较好,两种方法测定6种不同饮用水的δD和δ18 O的平均差异分别为(0.6±1.59)‰和(0.02±0.13)‰。水平衡法需要较长的制备和测定时间,但δD和δ18 O的测定精度明显优于高温转化法。11种饮用水δD和δ18 O变化范围较大,其δD和δ18 O受不同品牌饮用水的水源地降水影响形成明显的地域性。虽然无法区分矿泉水是否由其他类别饮用水伪造,但δD和δ18 O可以为特定区域(如高海拔与沿海地区)以及产地相近的矿泉水水源地鉴别提供依据。 相似文献
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《Advanced Powder Technology》2020,31(1):139-157
A novel mixing principle utilising oscillating liquid columns was analysed numerically with regard to particle dispersion characteristics. For producing fluid oscillations a pipe (diameter 100 mm) was immersed centrally into a vessel (diameter 450 mm) filled with liquid (filling height 700 mm) and periodically pressurised (frequency 1.2 Hz). The outlet geometry of the central pipe, just ending near the vessel bottom, has a strong effect on mixing and was optimised in this study. The principle of a FPR-mixer does not require rotating stirrers and in the turbulent regime it has power numbers comparable to propellers. The numerical calculations were conducted by a Euler/Lagrange approach neglecting two-way coupling as well as inter-particle collisions for clarity in order to only focus on the effect of interfacial forces on particle dispersion. The continuous phase was calculated in an unsteady way based on the Reynolds-averaged equations combined with the k-ω-SST (shear stress transport) turbulence model. Lagrangian tracking was conducted considering all relevant forces; drag, gravity/buoyancy, fluid inertia, added mass, Basset force and transverse lift forces due to shear and particle rotation. The importance of these forces was analysed with respect to the turbulent particle Stokes number (considered range 0.004 < St < 10.0) and particle/liquid density ratio (i.e. 1.05, 1.5 and 2.5). Finally, the significance of Basset force and shear-rotation lift force (i.e. Magnus effect) on the dispersion process was quantified by mixing parameters. 相似文献