Ab Initio and Monte Carlo Approaches for the Magnetocaloric Effect in BaMnO<Subscript>3</Subscript> Oxide Perovskite

The self-consistent ab initio calculations, based on density functional theory approach (DFT) and using full potential linearised augmented plane wave (FLAPW) method, have been used to investigate both electronic and magnetic properties of the BaMnO₃ perovskite. Spin-polarised calculations, including the spin-orbit interaction, are used to determine the energy of the ferromagnetic (FM) and antiferromagnetic (AFM) states of BaMnO₃ perovskite. Obtained data from ab initio calculations are used as input for the Monte Carlo simulations to compute other magnetic parameters. Magnetisation, specific heat and magnetic entropy change have been given using the Monte Carlo simulations. The adiabatic temperature change, transition temperature and relative cooling power have been established.     

Ultrafine,fine, and black carbon particle concentrations in California child‐care facilities

Although many U.S. children spend time in child care, little information exists on exposures to airborne particulate matter (PM) in this environment, even though PM may be associated with asthma and other respiratory illness, which is a key concern for young children. To address this data gap, we measured ultrafine particles (UFP), PM_2.5, PM₁₀, and black carbon in 40 California child‐care facilities and examined associations with potential determinants. We also tested a low‐cost optical particle measuring device (Dylos monitor). Median (interquartile range) concentrations for indoor UFP, gravimetric PM_2.5, real‐time PM_2.5, gravimetric PM₁₀, and black carbon over the course of a child‐care day were 14 000 (11 000‐29 000) particles/cm³, 15 (9.6‐21) μg/m³, 15 (11‐23) μg/m³, 48 (33‐73) μg/m³, and 0.43 (0.25‐0.65) ng/m³, respectively. Indoor black carbon concentrations were inversely associated with air exchange rate (Spearman's rho = ?.36) and positively associated with the sum of all Gaussian‐adjusted traffic volume within a one‐kilometer radius (Spearman's rho = .45) (P‐values <.05). Finally, the Dylos may be a valid low‐cost alternative to monitor PM levels indoors in future studies. Overall, results indicate the need for additional studies examining particle levels, potential health risks, and mitigation strategies in child‐care facilities.     

Measurement of Kinematic and Thermal Characteristics of High-Speed Gas-Dynamic Processes by Means of Microwave Sounding

The paper describes a method of simultaneous measurements of kinematic parameters of a high-speed process by a microwave radio interferometer with a 3-mm range of wavelengths and the brightness temperature of the same process by the microwave radio interferometer operating in the radiometer mode. The methods of radiometer calibration and analysis of radiometric data are described. Results of experimental investigations are reported by an example of measuring the detonation velocity and estimating the brightness temperature of the detonation front in TNT.     

Deactivation of Mechanically Activated Micronized Coal

This paper describes the study of the effect of mechanically activated grinding of coal on its flammability. Coal treated in a ball pulverizer and mechanically activated coal exposed to air are compared in experiments. The experiments show a decrease in the chemical activity of mechanically activated coal.     

The Requirements for the Calibration Conditions in Large-Aperture Fizeau Interferometers

The problems that arise during the calibration of the reference plates of large-aperture interferometers are discussed and the methods for solving them are presented. It is shown that the repeatability of shapes of the reference plates after their rearrangements can be provided by selecting the mechanism of their fixing in place. It is demonstrated that the temperature deformations of the reference-plate surfaces can be determined from a numerical model. These measures have made it possible to calibrate the reference plates of the 630-mm interferometer with an accuracy of λ/1000 RMS (λ = 632.8 nm).     

Structure of a Viscoplastic Flow During the Mold-Filling Process

The flow of a viscoplastic fluid during the filling of a flat vertical channel was studied. The mathematical problem was formulated based on the complete equations of motion and natural boundary conditions on a free surface; the problem was solved by the finite-difference method. For shock-capturing, the Schwedoff–Bingham rheological equation was regularized. A parametric study of the flow characteristics and behavior of the free boundary was performed depending on the main parameters of the problem. The characteristic flow structures were demonstrated depending on the ratio of viscous, gravitational, and plastic forces in the flow.     

Characterization of superficial modification of ferrous rusted substrates subjected to dechlorination-electrochemical process

Preservation of archaeological artefacts after their removal from saline media is a difficult task due to the chloride content of the oxide layers which are unstable in atmospheric conditions, especially if the relative humidity exceeds 85%. For this reason, removal of chlorides from rust layers is one of the priorities of conservationists or restorers of historical artefacts. However, removal of chloride ions is not an easy procedure because of the many considerations involved in the process. In this research, artificially pre-rusted iron samples and an actual historical cannonball were subject to a dechlorination process in a potassium hydroxide solution to measure constant chloride release in a bulk solution. After the chloride removal process, a commercial protective layer was applied to the rust for stabilization purposes. It was calculated that the kinetics of the dechlorination process is driven by diffusion behaviour following Fick’s second law. When this diffusion process prevails, the dechlorination extraction affects the integrity of rust layers as is demonstrated with scanning electron microscopy and X-ray diffraction analyses. It was proven that the chloride removal procedure causes the studied iron layers to stiffen, provoking superficial modification and, in some cases, fractures of the rust. By means of electrochemical impedance spectroscopy it was calculated that the magnitude of the positive effect of the dechlorinated samples depends on the protective features of the rust. Therefore, this research reveals that an efficient chloride removal procedure depends on the electrochemical properties of the dechlorination process and the initial morphology of the iron rust.