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排序方式: 共有4128条查询结果,搜索用时 15 毫秒
1.
Lun Feng William G. Fahrenholtz Gregory E. Hilmas Frédéric Monteverde 《Journal of the European Ceramic Society》2021,41(1):92-100
Dense high-entropy (Hf,Zr,Ti,Ta,Nb)B2 ceramics with Nb contents ranging from 0 to 20 at% were produced by a two-step spark plasma sintering process. X-ray diffraction indicated that a single-phase with hexagonal structure was detected in the composition without Nb. In contrast, two phases with the same hexagonal structure, but slightly different lattice parameters were present in compositions containing Nb. The addition of Nb resulted in the presence of a Nb-rich second phase and the amount of the second phase increased as the Nb content increased. The relative densities were all >99.5 %, but decreased from ~100 % to ~99.5 % as the Nb content increased from 0 to 20 at%. The average grain size decreased from 13.9 ± 5.5 μm for the composition without Nb additions to 5.2 ± 2.0 μm for the composition containing 20 at% Nb. The reduction of grain size with increasing Nb content was due to the suppression of grain growth by the Nb-rich second phase. The addition of Nb increased Young’s modulus and Vickers hardness, but decreased shear modulus. While some Nb dissolved into the main phase, a Nb-rich second phase was formed in all Nb-containing compositions. 相似文献
2.
《Ceramics International》2022,48(9):12281-12290
Following the rapid growth of lightning technology, the development of red-emitting phosphors is effective for improving color temperature and color rendering index for w-LEDs devices. Herein, a single phased garnet phosphor with cation and polyhedron substitution modification was firstly prepared. For Mg3Gd2Ge3O12: Bi3+, Eu3+, the intensity has been remarkably improved by about 16% compared to the one without Bi3+ sensitization. The energy transfer mechanism is identified in this work. Based on cation and polyhedron substitution strategies, novel phosphors with different compositions were obtained and further modified the PL properties. With Lu3+ substitution, the bond lengths between Bi3+ ion and anion ligands are decreased and the site symmetry has been strengthened, which leads to a 21 nm blue shift when Lu3+ totally replaced Gd3+ ions. In addition, Lu3+ and [SiO4] substitution strategies both effectively increased symmetric rigid structure, which leads to a significant improvement in thermal stability, indicating the samples own great potential in optical applications This work provides a new insight to synthesis red-emitting phosphors for warm white-LEDs. 相似文献
3.
To investigate the evolution of the structural and enhanced magnetic properties of GdMnO3 systems induced by the substitution of Mn with Cr, polycrystalline GdMn1-xCrxO3 samples were synthesized via solid-state reactions. XRD characterization shows that all GdMn1-xCrxO3 compounds with single-phase structures crystallize well and that Cr3+ ions entering the lattice sites of GdMnO3 induce structural distortion. SEM results indicate that the grain size of the synthesized samples (a few microns) decreases as the Cr substitution concentration increases. Positron annihilation lifetime spectroscopy reveals that vacancy-type defects occur in GdMn1-xCrxO3 ceramics and that the vacancy size and concentration clearly change with the Cr content. The temperature and field dependence of the magnetization curves show that Cr substitution significantly influences the magnetic ordering of the gadolinium sublattice, improving the weak ferromagnetic transition temperature and magnetization of GdMn1-xCrxO3. The enhanced magnetization of GdMn1-xCrxO3 is closely related to the vacancy defect concentration. 相似文献
4.
Lightweight ciphers are increasingly employed in cryptography because of the high demand for secure data transmission in wireless sensor network, embedded devices, and Internet of Things. The PRESENT algorithm as an ultra-lightweight block cipher provides better solution for secure hardware cryptography with low power consumption and minimum resource. This study generates the key using key rotation and substitution method, which contains key rotation, key switching, and binary-coded decimal-based key generation used in image encryption. The key rotation and substitution-based PRESENT architecture is proposed to increase security level for data stream and randomness in cipher through providing high resistance to attacks. Lookup table is used to design the key scheduling module, thus reducing the area of architecture. Field-programmable gate array (FPGA) performances are evaluated for the proposed and conventional methods. In Virtex 6 device, the proposed key rotation and substitution PRESENT architecture occupied 72 lookup tables, 65 flip flops, and 35 slices which are comparably less to the existing architecture. 相似文献
5.
Alkali metal ion substitution is an effective strategy to improve the luminescence properties of phosphors. In this work, a series of red-emitting phosphors Na1-xLix/2Kx/2La0.6Eu0.4MgWO6 were prepared by a traditional high-temperature solid-state reaction. Their phase structure, microstructure, luminescence properties and potential application in phosphor-converted white light-emitting diodes (pc-WLEDs) were investigated in detail. X-ray diffraction (XRD) result revealed the formation of a solid solution when x?≤?0.3, which kept monoclinic structure of NaLaMgWO6. Photoluminescence investigation indicated that the partial substitution of Li+/K+ ions for Na+ ions improved largely the red emission of Eu3+. Based on the optimized Na0.7Li0.15K0.15La0.6Eu0.4MgWO6 sample with relatively good thermal stability, a WLED device was fabricated by combining a near-ultraviolet (NUV) chip (~400?nm) with the phosphor mixture of commercial green/blue phosphors and the optimized red phosphor. The results indicated that the optimized red phosphor in this work could be a potential candidate for WLEDs pumped by NUV chips. 相似文献
6.
《Ceramics International》2022,48(9):12537-12548
Enhancing the electrical conductivity of electrode materials via a cationic substitution strategy was recognized as an effective way of improving the electrochemical performance of Li-ion batteries. Thus, LixCa1-xFe2O4 nanoparticles were synthesized via a facile inexpensive process at low temperature. XRD peaks refer to the formation of an orthorhombic structure with the Pnma space group. HR-TEM investigations reveal orthorhombic-like shape for pure CaFe2O4, nanoplatelet-like morphology for Li0.05Ca0.95Fe2O4 and irregular distorted crystals for Li0.1Ca0.9Fe2O4. Voids and pores in Li-doped CaFe2O4 were confirmed by FESEM and BET measurements. XPS spectra of O1s prove that Li-doped CaFe2O4 have higher conductivity due to the created lattice defects and oxygen species. Li-doped CaFe2O4 anodes exhibit great improvement in their initial discharge capacities ~1219 and 1606 mAhg?1 upon substitution of Ca with 5% and 10% Li, respectively. Furthermore, 10% Li-doped CaFe2O4 anode displays the highest Li-ions diffusion coefficient and exchange current density due to the enhanced Li+ ions mobility. Moreover, the DC activation energies for the LixCa1-xFe2O4 nanoparticles decreased with increasing Li content. 相似文献
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9.
《Ceramics International》2020,46(10):16364-16371
β-tricalcium phosphate (β-TCP), a well-accepted synthetic bone grafting biomaterial, is confronted with limitations of poor phase stability and lacking the capacity to mediate the biological functions. In the current study, gallium (Ga) was substituted for calcium in the β-TCP, and the influences of Ga substitution on the phase stability, compressive strength and cellular response of β-TCP bioceramics were investigated. The results indicated that substitution of at least 2.5 mol% Ga for calcium prevented the β-TCP from transforming into α-TCP at 1250 °C. The β-TCP bioceramics substituted with 2.5 mol% Ga attained the highest compressive strength. The β-TCP bioceramics substituted with 2.5 and 5 mol% Ga showed good cytocompatibility, and suppressed in vitro osteoclastic activity as well as osteoblastic differentiation. Considering the favorable mechanical strength and the inhibitory effect on the osteoclastic activity, the β-TCP bioceramics substituted with 2.5 mol% Ga are promising for treating the bone defect in the pathological state of excessively rapid bone resorption. 相似文献
10.
Yang-huan ZHANG Ya-qin LI Hong-wei SHANG Zhong-hui HOU Yan QI Dong-liang ZHAO 《中国有色金属学会会刊》2018,28(4):711-721
The La-Mg-Ni-Co-Al-based AB2-type La0.8–xCe0.2YxMgNi3.4Co0.4Al0.1 (x=0, 0.05, 0.1, 0.15, 0.2) alloys were prepared via melt spinning. The analyses of the X-ray diffraction (XRD) and scanning electron microscopy (SEM) proved that the experimental alloys contain the main phase LaMgNi4 and the second phase LaNi5. Increasing Y content and spinning rate lead to grain refinement and obvious change of the phase abundance without changing phase composition. Y substitution for La and melt spinning make the life-span of the alloys improved remarkably, which is attributed to the improvement of anti-oxidation, anti-pulverization and anti-corrosion abilities. In addition, the discharge capacity visibly decreases with increasing the Y content, while it firstly increases and then decreases with increasing spinning rate. The electrochemical kinetics increases to the optimum performance and then reduces with increasing spinning rate. Moreover, all the alloys achieve to the highest discharge capacities just at the initial cycle without activation. 相似文献