Synthesis and optical properties of novel apatite-type NaCa3Bi(PO4)3F:Dy3+ yellow-emitting fluorophosphate phosphors for white LEDs

In this study, novel yellow-emitting fluorophosphate NaCa₃Bi(PO₄)₃F phosphors doped with different concentrations of Dy³⁺ ions were first obtained via high-temperature solid-state reaction. The crystal structure, phase purity, particle morphology, photoluminescence (PL) properties, thermal stability, and luminescence decay curves of the resulting phosphors were then characterized in detail. Under the excitation of 349 nm, the three dominant peaks of the NaCa₃Bi(PO₄)₃F:Dy³⁺ are centered at 480 nm (⁴F_9/2-⁶H_15/2), 577 nm (⁴F_9/2-⁶H_13/2), and 662 nm (⁴F_9/2-⁶H_11/2). The optimal doping concentration of Dy³⁺ ions in the NaCa₃Bi(PO₄)₃F:xDy³⁺ phosphors is x = 5 mol%. The phosphors show excellent thermal stability with high activation energy (E_a = 0.32 eV). Eventually, the synthesized white light-emitting diode (w-LED) demonstrates the Commission International de L'Eclairage (CIE) chromaticity coordinates of (0.341, 0.334), a good correlated color temperature (CCT) of 5083 K, and a high color rendering index (R_a) of 92. Revealing its potential as yellow-emitting phosphors, the feasibility of the fabricated apatite-type NaCa₃Bi(PO₄)₃F:Dy³⁺ fluorophosphate phosphors was confirmed for w-LEDs.     

Ultra-high temperature ceramics based on ZrB2 obtained by pressureless sintering with addition of Cr3C2, Mo2C,and WC

ZrB₂-MeC and ZrB₂-19 vol% SiC-Me_xC_y where Me=Cr, Mo, W were obtained by pressureless sintering. The capability to promote densification of ZrB₂ and ZrB₂-SiC matrices is the highest for WC and lowest for Cr₃C₂. The interaction between the components results in the formation of new phases, such as MeB (MoB, CrB, WB), a solid solution based on ZrC, and a solid solution based on ZrB₂. The addition of Cr₃C₂ decreases the mechanical properties. On the other hand, the addition of Mo₂C or WC to ZrB₂-19 vol% SiC composite ceramics leads increased mechanical properties. Long-term oxidation of ceramics at 1500 °C for 50 h showed that, in binary ZrB₂-Me_xC_y, a protective oxide scale does not form on the surface thus leading to the destruction of the composite. On the contrary, triple composites showed high oxidation resistance, due to the formation of dense oxide scale on the surface, with ZrB₂-SiC-Mo₂C displaying the best performance.     

Pd/C-Catalyzed H2 Evolution from Tetrahydroxydiboron Hydrolysis

Catalysis Letters - The production of H2 from non-fossil sources is a key research challenge to contributing solving the forthcoming energy problem. Aqueous solutions of tetrahydroxydiboron have...     

光敏剂在光动力治疗中的应用研究进展

光动力疗法（PDT）以其超高时空分辨率、非侵入性及低毒副作用的优点，被认为是治疗癌症和各种非恶性疾病的有效疗法之一。本文主要综述了几类光敏剂发展历史、主要结构、特点及研究进展，分析了高性能光敏剂的开发动态，包括化学修饰；与具有特定细胞受体的其他配体缀合成复合光敏剂；采取纳米技术，如纳米颗粒输送，基于富勒烯的光敏剂等。基于此，指出具有临床应用前景的高性能光敏剂的基本特征、设计原则及发展趋势。     

多机器人体间动态碰撞检测方法仿真研究

当前多结合包围求碰撞检测法、Average-Case法、K-DOPs法等实现多机器人体间动态碰撞的检测,均存在寻优性能较差、检测效率较低的问题。为此提出一种基于动态粒子群的多机器人体间动态碰撞检测方法。采用OBB层次包围盒方法,缩小多机器人之间需要动态碰撞检测的区域,同时把动态碰撞检测问题转换为物体特征对间距离机制的非线性优化问题,进而构建层次拓扑框架进行局部碰撞检测,将机器人体引入到粒子群算法中建立混合进化算法,找到动态碰撞检测的最优解,实现多机器人体间动态碰撞检测。仿真结果证明,所提方法的检测效率高达96%,且具有较高的寻优性能。     

A novel minimum weight formulation of topology optimization implemented with reanalysis approach

In this paper, we develop an efficient diagonal quadratic optimization formulation for minimum weight design problem subject to multiple constraints. A high-efficiency computational approach of topology optimization is implemented within the framework of approximate reanalysis. The key point of the formulation is the introduction of the reciprocal-type variables. The topology optimization seeking for minimum weight can be transformed as a sequence of quadratic program with separable and strictly positive definite Hessian matrix, thus can be solved by a sequential quadratic programming approach. A modified sensitivity filtering scheme is suggested to remove undesirable checkerboard patterns and mesh dependence. Several typical examples are provided to validate the presented approach. It is observed that the optimized structure can achieve lighter weight than those from the established method by the demonstrative numerical test. Considerable computational savings can be achieved without loss of accuracy of the final design for 3D structure. Moreover, the effects of multiple constraints and upper bound of the allowable compliance upon the optimized designs are investigated by numerical examples.     

多因素耦合作用下地下厂房施工进度风险分析及其应用

为深入分析地下厂房施工进度风险因素之间的耦合作用及耦合效应,采用WBS-RBS法识别了影响施工进度的人、物、环境、管理4类风险因素,基于系统动力学方法揭示了同质单因素和异质双-多因素耦合关系,在此基础上建立了同质单因素耦合度模型和异质双-多因素N-K模型,运用蒙特卡罗法模拟了各风险因素对进度影响的概率分布,分析耦合强度。工程实例应用表明,各类风险子系统中存在较大的同质单因素耦合风险,应加强针对性预防和控制;异质双-多因素耦合中,有管理因素参与耦合的风险较大,实际施工中应尽可能减少多因素参与耦合。     

Two low-permittivity melilite ceramics in the SrO-MO-GeO2 (M = Mg,Zn) system and their temperature stability through compositional modifications

Two melilite ceramics Sr₂AGe₂O₇ (A = Mg, Zn) with low permittivity were prepared by a solid-state reaction method. The crystal structure and microstructure of the ceramics were characterized by X-ray diffraction, transmission electron microscopy, Raman spectroscopy, and scanning electron microscopy. Both ceramics crystallized in a single melilite structure with a tetragonal space group P-42m (113) and exhibited homogeneous microstructures. Optimum microwave dielectric properties with relative permittivity (ε_r) of 8.56, quality factor (Q × f) of 28,800 GHz, and temperature coefficient of resonance frequency (τ_f) of −70.5 ppm/°C were obtained in Sr₂MgGe₂O₇ sintered at 1330 °C. Sr₂ZnGe₂O₇ possessed ε_r of 8.81, Q × f of 35,700 GHz, and τ_f of −84.4 ppm/°C when sintered at 1290 °C. Thermal stability of resonance frequency was accessible when the negative τ_f values of Sr₂AGe₂O₇ were adjusted after the formation of composite ceramics with CaTiO₃.