“电工学实验”混合教学模式的探索与实践

在大类培养改革背景下,基于“电工学实验”开放式实践教学体系现状进行了“电工学实验”混合教学模式的研究,建立了“微课”资源并通过新型教学平台进行推送,确立了完备的混合教学模式应用机制并在部分专业进行了试点,通过分析试点调查数据得出混合教学模式具有在实验教学中提高学生学习效率、激发学生学习动力、促进学生个性发展、培养学生实践应用能力的优势,是落实创新应用型人才培养目标的重要举措。     

碳中和背景下配电网差异化节能降耗潜力评估分

为了提高配电网差异化节能降耗效果，解决现有潜力评估方法存在的应用性能差的问题，提出碳中和背景下配电网差异化节能降耗潜力优化评估方法。根据配电网的空间结构，构建相应的等值电路模型。在该模型下，从设备损耗和运行附加损耗2个方面计算配电网的损耗量。根据损耗量计算结果，确定配电网差异化碳中和节能降耗方式。从静态和动态2个角度设置潜力评估指标，通过指标数据处理、指标权重求解等步骤，得出配电网差异化节能降耗潜力的综合量化评估结果。将设计潜力评估方法应用到配电网的差异化节能降耗改造工作中，能够有效降低配电网的实际线损量、降低区域损耗费用，并具有较高的应用价值。     

复杂环境下氧化铝储槽定向爆破拆除

在较为复杂的环境下,爆破拆除钢筋混凝土氧化铝储槽。该储槽自重大、呈圆形,内有4根立柱支撑下料漏斗。为使储槽顺利定向倒塌,通过爆破方案选择、参数确定,采取梯形切口和预处理以及安全防护和减振措施,使储槽爆破拆除获圆满成功。     

电子雷管技术的推广应用助力爆破器材安全管理工作

电子雷管技术提高了爆破器材的本质安全。通过对电子雷管技术发展历程的介绍,对其推广应用的可行性进行了深入分析,论述了电子雷管技术的推广应用对爆破器材安全管理工作的促进作用,并提出了今后推广应用中还需加强的工作。     

基准平面垂直断面法在爆破漏斗试验中的应用

系统阐述了基准平面垂直断面法在爆破漏斗试验中测量爆破漏斗体积的基本原理,并将隧道激光断面仪应用于金厂河矿1 750 m水平15^#采场底部切割巷道爆破漏斗试验爆破漏斗体积测量中。通过与传统体重法等计算法所得漏斗体积分析比较,结果表明基于隧道激光断面仪与3D Mine软件分析的基准平面垂直断面法实用性强、操作方便、结果直观可靠,达到试验预期目的。     

Natural hydrogen emanations in Namibia: Field acquisition and vegetation indexes from multispectral satellite image analysis

Natural hydrogen exploration is now active in various places of the world. Onshore, correlation between natural H₂ generation and the presence of iron rich rocks especially from Archean and Neoproterozoic cratons have been observed. Emanations and accumulations of H₂ have already been confirmed in such geological settings in Australia, South Africa and Brazil. The geological similitude and the presence of numerous sub circular depressions that are a good proxy for hydrogen emanations suggest that hydrogen resources may also exist in Namibia. We present here the results of a data acquisition campaign which allowed us to confirm the presence of natural hydrogen in this country in the vicinity of Neoproterozoic Banded Iron Formation. The H₂ content in the soil, as in Brazil, is variable within the depressions in time and space and is particularly time sensitive across the day. Comparison of the H₂ signal versus time within these two regions shows a similar behavior of the soils with an increase of the H₂ flow at the middle of the day. In addition, these new data allow us to better constrain the morphological characteristics of such H₂-emiting depressions. By using satellite images and digital elevation model we propose a new proxy to differentiate potentially H₂-emiting features from other type of depressions such as Salt Pan. The Landsat multispectral images and their processing through NDVI and SAVI indexes, that highlight a ring of healthy vegetation around the sub circular area with scarce vegetation already observed appear able to discriminate between H₂ emitting structures and other soft depressions.     

Ni2P(O)–Fe2P(O)/CeOx as high effective bifunctional catalyst for overall water splitting

The development of cost-effective bifunctional catalysts with excellent performance and good stability is of great significance for overall water splitting. In this work, NiFe layered double hydroxides (LDHs) nanosheets are prepared on nickel foam by hydrothermal method, and then Ni₂P(O)–Fe₂P(O)/CeO_x nanosheets are in situ synthesized by electrodeposition and phosphating on NiFe LDHs. The obtained self-supporting Ni₂P(O)–Fe₂P(O)/CeO_x exhibit excellent catalytic performances in alkaline solution due to more active sites and fast electron transport. When the current density is 10 mA cm^?2, the overpotential of hydrogen evolution reaction and oxygen evolution reaction are 75 mV and 268 mV, respectively. In addition, driven by two Ni₂P(O)–Fe₂P(O)/CeO_x electrodes, the alkaline battery can reach 1.45 V at 10 mA cm^?2.     

Electronic regulation and core-shell hybrids engineering of palm-leaf-like NiFe/Co(PO3)2 bifunctional electrocatalyst for efficient overall water splitting

Constructing efficient and stable bifunctional electrocatalysts for overall water splitting remains a challenge because of the sluggish reaction kinetics. Herein, the core-shell hybrids composed of Co(PO₃)₂ nanorod core and NiFe alloy shell in situ grown on nickel foam (NiFe/Co(PO₃)₂@NF) are synthesized. Owing to the hierarchical palm-leaf-like structures and strong adhesion between NiFe alloys, Co(PO₃)₂ and substrates, the catalyst provides a large surface area and rapid charge transfer, which facilitates active sites exposure and conductivity enhancement. The interfacial effect in the NiFe/Co(PO₃)₂ core-shell structure modulates the electronic structure of the active sites around the boundary, thereby boosting the intrinsic activity. Benefiting from the stable structure, the durability of the catalyst is not impaired by the inevitable surface reconfiguration. The NiFe/Co(PO₃)₂@NF electrode presents a low cell voltage of 1.63 V to achieve 10 mA cm^?2 and manifests durability for up to 36 h at different current densities.     

Effects of different metal corrosion inhibitors on hydrogen suppression and film formation with Mg–Zn alloy dust in NaCl solutions

To improve the safety of wet dust removal systems for processing magnesium-based alloys, a new method is proposed for preventing hydrogen generation. In this paper, hydrogen generation by Mg–Zn alloy dust was inhibited with six common metal corrosion inhibitors. The results showed that sodium dodecylbenzene sulfonate was the best hydrogen inhibitor, while CeCl₃ enhanced hydrogen precipitation. The film-forming stability of sodium dodecylbenzene sulfonate was tested with different contents, temperatures, Cl^? concentrations and perturbation rates. The results showed that this inhibitor formed stable protective films on the surfaces of Mg–Zn alloy particles, and adsorption followed the Langmuir adsorption model.     

Heterofullerene C48B12-impregnated MOF-5 and IRMOF-10 for hydrogen storage: A combined DFT and GCMC simulations study

The H₂ storage properties of isoreticular metal-organic framework materials (IRMOFs), MOF-5 and IRMOF-10, impregnated with different numbers and types of heterogeneous C₄₈B₁₂ molecules were investigated using density functional theory and grand canonical Monte Carlo (GCMC) calculations. The excess hydrogen adsorption isotherms of IRMOFs at 77 K within 20 bar indicate that suitable number and type of C₄₈B₁₂ molecules play a crucial role in improving the H₂ storage properties of IRMOFs. Among the studied pure and nC₄₈B₁₂ (n = 1, 2, 4, 8) in Ci symmetry impregnating into MOF-5, at 77 K under 6 bar, MOF-5-4C₄₈B₁₂ with a 3.5 wt% and 29.9 g/L hydrogen storage density, and at 77 K under 12 bar, the pure MOF-5 with a 4.9 wt% and 31.0 g/L hydrogen storage density has the best hydrogen storage properties. Whereas, among the studied pure and nC₄₈B₁₂ (n = 1, 2, 4, 8) in S6 symmetry impregnating into IRMOF-10, IRMOF-10-8C₄₈B₁₂ always shows the best hydrogen storage properties among the pure and C₄₈B₁₂-impregnated IRMOF-10 at 77 K within 20 bar. IRMOF-10-8C₄₈B₁₂ has a 6.0 wt% and 34.6 g/L hydrogen storage density at 77 K under 6 bar, and has a 7.1 wt% and 41.4 g/L hydrogen storage density at 77 K under 12 bar. The confinement effect of IRMOFs on C₄₈B₁₂ molecules, and steric hindrance effect of C₄₈B₁₂ molecules on IRMOFs mainly affects the H₂ uptake capacity by comparing the absolute H₂ molecules in individual IRMOFs units, C₄₈B₁₂ molecules, and IRMOFs-nC₄₈B₁₂ compounds. The absolute hydrogen adsorption profiles show that eight C₄₈B₁₂ molecules impregnating into MOF-5 can exert obvious steric effects for H₂ adsorption. The saturated gravimetric and volumetric H₂ densities of IRMOF-10-8C₄₈B₁₂ higher than those of MOF-5-8C₄₈B₁₂ due to with larger free volume.