全文获取类型
收费全文 | 7440篇 |
免费 | 1157篇 |
国内免费 | 225篇 |
专业分类
电工技术 | 46篇 |
综合类 | 255篇 |
化学工业 | 1698篇 |
金属工艺 | 196篇 |
机械仪表 | 153篇 |
建筑科学 | 58篇 |
矿业工程 | 36篇 |
能源动力 | 100篇 |
轻工业 | 3037篇 |
水利工程 | 21篇 |
石油天然气 | 58篇 |
武器工业 | 13篇 |
无线电 | 1026篇 |
一般工业技术 | 1682篇 |
冶金工业 | 108篇 |
原子能技术 | 73篇 |
自动化技术 | 262篇 |
出版年
2024年 | 28篇 |
2023年 | 212篇 |
2022年 | 207篇 |
2021年 | 325篇 |
2020年 | 334篇 |
2019年 | 350篇 |
2018年 | 349篇 |
2017年 | 404篇 |
2016年 | 322篇 |
2015年 | 325篇 |
2014年 | 351篇 |
2013年 | 469篇 |
2012年 | 523篇 |
2011年 | 584篇 |
2010年 | 371篇 |
2009年 | 399篇 |
2008年 | 328篇 |
2007年 | 379篇 |
2006年 | 390篇 |
2005年 | 329篇 |
2004年 | 264篇 |
2003年 | 298篇 |
2002年 | 161篇 |
2001年 | 155篇 |
2000年 | 124篇 |
1999年 | 85篇 |
1998年 | 112篇 |
1997年 | 88篇 |
1996年 | 66篇 |
1995年 | 68篇 |
1994年 | 61篇 |
1993年 | 37篇 |
1992年 | 55篇 |
1991年 | 56篇 |
1990年 | 54篇 |
1989年 | 28篇 |
1988年 | 20篇 |
1987年 | 11篇 |
1986年 | 17篇 |
1985年 | 22篇 |
1984年 | 17篇 |
1983年 | 12篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1980年 | 7篇 |
1979年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有8822条查询结果,搜索用时 15 毫秒
1.
2.
Sawao Honda Kento Nakashima Taketo Yoshida Yusuke Daiko Shinobu Hashimoto Yuji Iwamoto 《Journal of the American Ceramic Society》2021,104(2):1178-1187
To quantitatively investigate the initial crystallization of zeolite beta synthesized by direct heating, the extent of the reaction was precisely evaluated by X-ray diffraction measurements and Rietveld structural refinement, and a kinetic analysis of crystallization was performed using the Avrami-Erofe'ev equation. The activation energy for crystallization was lower than that for hydrothermal synthesis. Reaction and synthesis time curves revealed that the initial zeolite beta crystallization consisted of three stages. The first was an induction period with nucleation by the generation of building units and the formation of an initial coordinated structure. The second stage was crystal growth by a diffusion-controlled reaction, and the third stage involved slowing down of crystallization by the limitation of dehydrocondensation. These stages could be analyzed by calculation of the rate constant and Avrami exponent for each stage. 相似文献
3.
4.
5.
Qi Xiao Xinyao Dong Xiumei Yin Hong Wang Hua Zhong Mingming Xing Ying Tian Yao Fu Bin Dong Xixian Luo 《Journal of the American Ceramic Society》2021,104(3):1415-1423
Multicolor upconversion luminescence materials show significantly applications in materials science. In this paper, the novel Yb3+-sensitized Na3La(VO4)2 upconversion luminescence crystals are synthesized by the solid-state reaction method. Three primary colors upconversion luminescence are successfully achieved in Na3La(VO4)2:Yb3+,Tm3+, Na3La(VO4)2:Yb3+,Er3+, and Na3La(VO4)2:Yb3+,Ho3+ crystals excited by the single 980 nm LD. Multicolor upconversion luminescence can be obtained by simply adjusting the combination ratios of these three samples. Luminescence mechanisms of the Yb3+-sensitized system are discussed in detail. In the Na3La(VO4)2 host material, the Yb3+/Ho3+ codoped system exhibits unusual red upconversion luminescence based on the short decay time of Ho3+ ion 5I6 level, which provides the possibility of three primary color luminescence under 980 nm excitation. 相似文献
6.
Callistus Nonso Ude Dominic Okechukwu Onukwuli Jonah Chukwudi Umeuzuegbu Chinemelum Chukwujekwu Chukwuka 《化学工程与技术》2021,44(1):65-76
The heterogeneous catalysis of transesterification of gmelina seed oil to biodiesel is evaluated. The oil was extracted from the seeds with n‐hexane by solvent extraction and characterized to determine its physiochemical properties. Response surface methodology was applied to optimize the effect of process variables on the biodiesel yield. The base‐activated clay catalyst performed as montmorillonite clay with the characteristic property of a Brønsted acid. It has an improved surface area after activation that enhanced its catalytic activity on transesterification reaction. Under optimal conditions, the biodiesel yield was 70.1 %, thus demonstrating that the model predicted well the biodiesel production. 相似文献
7.
Hui Jia Koushik Roy Jinfeng Pan Jan Mraz 《Comprehensive Reviews in Food Science and Food Safety》2022,21(2):1383-1408
Freezing methods have evolved over the last 30 years. This review states the effect of various freezing methods on the quality of fish and seafood. Freezing temperatures, freezing, and frozen storage temperatures were also analyzed and reviewed. The changes in the ice crystal, protein, and lipid affect the fish quality and nutritional value during freezing and frozen storage. Freezing methods when combined with various additives or preprocessing approaches help improve the efficacy of freezing and frozen storage. Several experimental or emerging methods also have positive effects on the products' quality. According to the metadata reanalysis of quality markers, freshly frozen fish using different freezing methods may vary much in terms of ice diameter, but not others. High pressure freezing or immersion freezing-derived fish retains the best quality through frozen storage. More data are required on freezing methods (electrical-assisted freezing, microwave-assisted freezing, magnetic-assisted freezing, radiofrequency-assisted freezing, and the commercial's application and investment should be considered in the future. This review sheds light on finding a balanced initial shear force during freezing and the use of certain additives to control freezing-related damages. Focusing on ice diameter alone may be futile (e.g., liquid N2 freezing). Future optimization of technologies should be in a way that several processes along the farm to fork such as freezing, frozen storage, thawing, thermal processing of fish, and even refabrication of food should mutually complement each other's needs to deliver safe and high-quality fish to the consumer's plate, even after a prolonged shelf-life. 相似文献
8.
9.
Ohjin Kwon Xiaoqian Cai Wentao Qu Feng Liu Jadwiga Szydłowska Ewa Gorecka Moon Jong Han Dong Ki Yoon Silvio Poppe Carsten Tschierske 《Advanced functional materials》2021,31(28):2102271
First examples of multichain (polycatenar) compounds, based on the π-conjugated [1]benzothieno[3,2-b]benzothiophene unit are designed, synthesized, and their soft self-assembly and charge carrier mobility are investigated. These compounds, terminated by the new fan-shaped 2-brominated 3,4,5-trialkoxybenzoate moiety, form bicontinuous cubic liquid crystalline (LC) phases with helical network structure over extremely wide temperature ranges (>200 K), including ambient temperature. Compounds with short chains show an achiral cubic phase with the double network, which upon increasing the chain length, is at first replaced by a tetragonal 3D phase and then by a mirror symmetry is broken triple network cubic phase. In the networks, the capability of bypassing defects provides enhanced charge carrier mobility compared to imperfectly aligned columnar phases, and the charge transportation is non-dispersive, as only rarely observed for LC materials. At the transition to a semicrystalline helical network phase, the conductivity is further enhanced by almost one order of magnitude. In addition, a mirror symmetry broken isotropic liquid phase is formed beside the 3D phases, which upon chain elongation is removed and replaced by a hexagonal columnar LC phase. 相似文献
10.
Zi-Zi Li Lei Lei Min-Xi Huo Zi-Rui Liu Xin-Quan Yang Yu-Lin Wang Yang Yuan 《International Journal of Food Science & Technology》2021,56(1):269-277
The objective of this paper was to investigate the complex of grape seed procyanidins (GSP) with zein hydrolysate (ZH). The interaction was determined using isothermal titration calorimetry (ITC) and fluorescence spectroscopy. The particle size, ζ-potential, scanning electronic microscopy (SEM) and stability test of the ZH-GSP complex were measured. The results of ITC, particle size and SEM suggested that there was a hydrogen bond-dominated interaction between GSP and ZH, and the ZH-GSP complex presented as a spherical shape with particle size of 234 nm, polydispersity index of 0.11 and ζ-potential of −46.4 mV. The results of the fluorescence spectroscopy showed that the fluorescence quenching effect of GSP on ZH was GSP concentration-dependent and the quenching process was mainly static quenching. The ZH-GSP complex had better physical stability in aqueous solution, and their solution was more stable than GSP solution under illumination and high-temperature treatment at 75°C. 相似文献