火花放电原子发射光谱类型标准化校正方式的探讨

在国内,火花放电原子发射光谱分析广泛使用类型标准化进行方法校正。在国外,标准和文献中鲜见使用此方法的相关论述。类型标准化主要采用平移校正和转动校正两种方式,哪种方式更加合理也鲜见报道。国外设备类型标准化的默认设置优先采用转动校正方式,相关国内标准对最优校正方式的规定尚不明确,此默认设置的合理性有待探讨。实验选用低合金钢20CrNi2Mo、R407标准样品和不锈钢317L、0Cr18Ni9标准样品,引用国内相关标准,以正确度临界差为评判依据,模拟类型标准化样品和待测样品“十分接近”和“接近”两种情况下平移校正和转动校正的数据正确度。经数据统计分析,平移校正分析结果均满足要求,转动校正结果在“接近”情况下部分元素不满足要求。结合相关国家标准中元素含量范围和精密度数据进行分析,通过计算允许最大偏倚量并制作曲线图方式展开分析,得出如下结论:在满足文中类型标准化控制要点前提下,分析设置更适合于采用平移校正方式。     

Sizing of multi-stage Op Amps by combining design equations with the gm/ID method

Analog integrated circuit design has as integral parts both analytical reasoning and numerical validation in the process from topology construction to sizing. Given a circuit topology, different circuit sizing results can be obtained from different processes of sizing inference. Sizing methods by simulation-based numerical searching have been a continuously studied subject. However, almost all approaches in this category require an overwhelming number of circuit simulations to arrive at an optimized sizing result. On the other hand, many published manual sizing methods by using the conventional device equations also require repeated SPICE simulations to correct the equation-based sizing results. This paper proposes a systematic gm/ID-based initial sizing method specifically customized for designing multiple-stage operational amplifiers (Op Amps). A main feature of the proposal is to use circuit-level design equations as constraints on the gm/ID table lookup method to substantially reduce the uncertainty in the sizing calculations. As a result, a significant amount of SPICE based correction work can be reduced to complete an initial sizing. The proposed sizing procedure includes a few regular sizing rules customized to the configuration of multi-stage Op Amps. We validate the proposed sizing method by application to several multi-stage Op Amp examples with a capacitive load or Miller compensation. Simulations have justified that the produced initial sizing results can achieve most of the prespecified design targets.     

渗流作用下新型装配重力式挡土墙有限元分析

为研究渗流作用下新型装配重力式挡土墙应力变化及墙体排水通道对墙后土体固结的影响,采用ABAQUS进行有限元分析,有限元分析结果与模型试验结果相吻合,证明该模型的合理性。在此基础上研究渗流作用下墙体应力变化趋势及墙体排水通道对墙后土体固结效果的影响。研究结果表明:横向排水通道对墙后土体固结效果的影响优于纵向排水通道对土体固结效果的影响,墙体底部横向排水通道的影响作用最显著;渗流作用下墙体应力由上往下呈先增大后减小的趋势,墙体下部所受最大水平剪应力最大。     

面向噪声丢包感知的无线网络拥塞算法

针对无线网络链路干扰大、误码率高等特点，以及TCP Westwood算法（TCPW）存在估算带宽时过度依赖包的反馈，缺乏区分传输过程中丢包类型的缺点等问题，提出一种TCPW拥塞控制优化算法--TCPW-F。该算法利用发送速率等构建拥塞因子[F]作为判断丢包类型的依据，同时对判定发生噪声丢包时的拥塞窗口进一步调整，避免噪声丢包引起的窗口下降，提高该情况下窗口的发送效率。仿真结果表明，TCPW-F算法在时延性能方面表现更优，单位时间抖动趋于稳定的速度更快。在同一信道带宽下增大包生成速率，改进算法的实时吞吐量明显高于原算法，具备一定的噪声丢包感知能力，无线网络的TCP传输质量获得较大改善。     

Analyzing dissipation effects on the non-classicality witnessing by a qubit via the entangled state representation

ABSTRACT

In this paper, we study detection of the state non-classicality for a quantum harmonic oscillator by a qubit in the presence of dissipation effects. We show that dissipation can enhance the effectiveness of the method in case of using the corrected form of the related nonclassicality witness. Such an improvement is attributed to the fact that dissipation leads to probing a surface, instead of a curve, of the complex plane for non-classicality condition on normally-ordered characteristic function.     

低活化马氏体钢热变形行为及机理型本构建模研究

利用Gleeble-3500热模拟试验机研究了低活化马氏体钢在变形温度为850～950 ℃、应变速率为0.001～1 s^-1条件下的热变形行为。建立了流变应力本构方程，并评估了该方程的预测能力。绘制了低活化马氏体钢在不同应变下的热加工图。结果表明：在较高的应变速率条件下，该材料主要发生动态回复，在较高变形温度和较低应变速率下具有明显的动态再结晶特征；本构方程的预测结果与实验结果符合良好；变形温度870～930 ℃、应变速率0.001～0.01 s^-1和变形温度920～950 ℃、应变速率0.3～1 s^-1分别是真应变为0.4和0.6下最优的热加工区域。     

A values–beliefs–attitude model of local food consumption: An empirical study in China and Denmark

Consumers’ and policy makers’ interest in local foods is growing. Accordingly, researchers are also increasingly paying attention to the consumption of local foods. Studies have identified preference for local foods as an emergent consumer ideology called “locavorism”, but they have not yet addressed its antecedents or put it into a theoretical context. In addition, extant research provides several insights into local food buying behaviour in developed economies (e.g., USA, UK, Germany, or Italy); however, studies simultaneously conducted in developed and emerging economies are lacking. To address these research gaps, this study develops a conceptual framework with proposed relationships among values, beliefs (locavorism and fresh start mindset), and attitudes towards and intentions to purchase local foods in China and Denmark. We conducted an online survey in China and Denmark that evaluated our constructs with pre-developed multiple-item measures. Using structural equation modelling to test the integrated model, we find that values and long-term orientation are antecedents of consumer beliefs but the influences of values on consumer beliefs differ between collectivistic-dominated China and individualistic-dominated Denmark. Specifically, collectivistic values are significantly and positively related to locavorism in both countries, while individualistic values are strongly linked to locavorism only in Denmark; collectivistic values have no effects on fresh start mindset for the two samples, but individualistic values are significantly and positively related to a fresh start mindset in Denmark. In addition, consumer beliefs are significantly and positively associated with attitudes towards and intentions to buy local foods. Local food marketers can use our findings to target their communications more effectively.     

广西箭猪坡矿床首次发现的石英脉型锡矿体特征及 锡石微量元素地球化学意义

箭猪坡矿床是丹池成矿带南端的一个以铅锌锑为主的矿床，随着2012-2014年在箭猪坡矿床钻孔中石英脉型锡矿体的首次发现，打开了箭猪坡矿床新的找矿空间。新发现的锡矿体矿石矿物组合类型主要为锡石+闪锌矿+脆硫锑铅矿+黄铁矿+石英及锡石+脆硫锑铅矿+石英+方解石。箭猪坡矿床锡石呈自形-半自形粒状，锡石粒径多在0.1～0.2mm，少数0.02～0.05mm，分布在含硫化物的石英脉裂隙中。物相分析显示箭猪坡矿床锡主要赋存在锡石中，锡石物相占83.33%～100%。阴极发光（CL）图像显示箭猪坡矿床中的锡石经历了两期结晶作用：早期锡石（Ⅰ）和晚期锡石(Ⅱ），早期锡石CL荧光亮度较小，呈暗灰色至黑色；晚期CL荧光亮度较大，呈白色至浅灰色。锡石单矿物SnO2含量91.623%～96.288%，平均94.03%，杂质主要有Fe、W、In等，其中FeO含量0.02%～0.52%，WO3含量多在0.02～1.34%，In2O3含量在0.476%～0.954%，Sn与FeO、In2O3呈负相关，锡石中FeO、WO3、Ta2O5、Nb2O5、MnO含量指示箭猪坡锡形成于中低-中温热液环境，成矿热液来源于高度分异演化的花岗质岩浆。通过与大厂矿田西矿带上部脉状锡矿体的类比分析，具有相似的成矿条件及矿物组合，推测所揭露到的脉状锡矿（化）体相当于西矿带上部脉状锡矿（化）体，而下部的网脉状、似层状锡矿体尚未揭露到，由此预测箭猪坡矿床深部找矿空间及找矿潜力大。     

Solution combustion synthesis of cerium oxide nanoparticles as corrosion inhibitor

In this study, combustion synthesis of cerium oxide nanoparticles was reported using cerium nitrate hexahydrate as starting material as well as urea, glycine, glucose, and citric acid as fuels. The influence of fuel type on structure, microstructure, band gap, and corrosion inhibition was investigated. X-ray diffraction (XRD) patterns and scanning electron microscopy micrographs showed that CeO₂ nanoparticles with different morphologies were obtained depending on the fuel type. Microstructural changes from unreacted gel to sponge-like morphologies were resulted by varying the fuel type from urea, glycine, and glucose to citric acid. In addition to Ce–O bonds, Fourier transform infrared analysis showed carbon bonds of carbonaceous compositions from incomplete combustion which were declined during combustion reaction. Furthermore, corrosion analyses showed that samples synthesized using urea fuel released the most Ce⁺⁴ ions and could have better protection than other samples.