Manufacturing catalyst-coated membranes by ultrasonic spray deposition for PEMFC: Identification of key parameters and their impact on PEMFC performance

This study deals with the manufacturing of catalyst-coated membranes (CCMs) for newcomers in the field of coating. Although there are many studies on electrode ink composition for improving the performance of proton-exchange membrane fuel cells (PEMFCs), there are few papers dealing with electrode coating itself. Usually, it is a know-how that often remains secret and constitutes the added value of scientific teams or the business of industrialists. In this paper, we identify and clarify the role of key parameters to improve coating quality and also to correlate coating quality with fuel cell performance via polarization curves and electrochemical active surface area measurements. We found that the coating configurations can affect the performance of lab-made CCMs in PEMFCs. After the repeatability of the performance obtained by our coating method has been proved, we show that: (i) edge effects, due to mask shadowing - cannot be neglected when the active surface area is low, (ii) a heterogeneous thickness electrode produces performance lower than a homogeneous thickness electrode, and (iii) the origin and storage of platinum on carbon powders are a very important source of variability in the obtained results.     

Synthesis and characterization of ZnO NRs with spray coated GO for enhanced photocatalytic activity

Zinc oxide nanorods, ZnO NRs, were synthesized on a clean glass and coated with graphene oxide (GO) using spray coating method to enhance the photocatalytic activity in wastewater treatment. The ZnO NRs were synthesized using the solution process synthesis that was optimized using Taguchi method. Several synthesis parameters have been optimized and studied to determine the best synthesis parameter to grow ZnO NRs for the photodegradation of organic contaminants. Field emission scanning electron microscopy (FESEM) with EDX, X-ray diffraction (XRD), Raman, ultraviolet visible near-infrared (UV-VIS-NIR), and photoluminescence (PL) spectroscopies were used to investigate the structural and optical properties of the produced nanorods. FESEM images revealed the vertical growth of ZnO NRs as well as layers of GO covering the ZnO NRs' top surface. The Raman study demonstrates the combination peak of GO and ZnO, hence proving the GO layer's successful coating. After the GO coating, decrease in the bandgap of the synthesized photocatalyst was detected by PL and UV–Vis absorption measurements. Under UVC exposure with treatment time of 6 h, the degradation of MB with ZnO NRs/GO photocatalyst reached a degradation percentage of 97.86%, which is greater than the degradation percentage achieved using pristine ZnO NRs, which is 93.28%. The results validated that the coating of GO enhances the photocatalytic activity of the host material, ZnO NRs.     

Spray dryer processed graphene oxide/reduced graphene oxide for high-performance supercapacitor

This study deals with the utility of mini spray dryer process to improve the dispersibility, of graphene oxide(GO) and its application for high-performance supercapacitor. Initially, the neutral solution of GO was obtained using the modified Hummer's method. After this, the prepared GO solution was processed by mini spray dryer to obtain a more purified, lighter, and dispersed form of GO which is named as spray dryer processed GO (SPGO). The SPGO thus obtained showed excellent dispersibility behavior with various solvents, which is not found in case of conventional oven drying. Furthermore, utility of SPGO and its reduced form (r-SPGO) for supercapacitor applications have been investigated. Results obtained from the cyclic voltammetry(CV) analysis, impedance, and charge-discharge behavior of supercapacitor fabricated using r-SPGO shows enhanced features. Therefore, the simple spray dried GO and its reduced form, that is, r-SPGO can be utilized as a potential candidate for the supercapacitor application. Herein, as synthesized SPGO exhibited the specific capacitance of 12.07 and 37.6 F/g with PVA-H₃PO₄ and 1 mol/L H₃PO₄, respectively, at a scan rate of 5 mV/s. On the other hand, reduced form of SPGO, that is, r-SPGO showed the specific capacitance of 27.16 and 230 F/g with PVA-H₃PO₄ and 1 mol/L H₃PO₄, respectively.     

喷射成形Al-Zn-Mg-Cu合金挤压态的组织和力学性能

研究了利用喷射成形辅以挤压制备Al-5.72Zn-2.36Mg-1.66Cu合金后优化的组织结构特征和力学性能。结果表明,合金基体组织均匀细化,晶粒形貌趋于圆整,平均晶粒大小达到10 μm左右。当合金的冷却条件通过快速凝固技术改变时,会产生不同程度的固溶强化效果和第二相弥散强化效果,从而改善了合金的整体性能。合金的屈服强度和抗拉强度分别平均提高了20%左右,且伸长率也略有提高。     

Inhalation risk of indoor aerosol spray products commercially available in Bangladesh

Today, urbanised people spend most of their time in indoor environments, and the risk of exposure to toxic materials in an indoor environment is of great concern. This paper considers sources for the inhalation risk of aerosol sprays by measuring the particle size distributions of some of the most popular products that are commercially available in Bangladesh, and examines the degree of toxicity and the health risk via the respirability of the products. Results show that thoracic and respirable fractions of the suspended particulate matter are present in the tested samples and hence the spray products may pose a significant health risk.     

海水淡化用空心锥喷嘴喷淋性能理论及实验研究

设计开发一种具有高通量、低流阻特征的空心锥喷嘴,并通过理论与实验方法研究空心锥喷嘴的喷淋性能,基于准自由涡理论建立空心锥喷嘴内部流体流动的数学模型,阐明流量系数、喷淋锥角、喷嘴流量与喷嘴结构参数之间的定量关系,并利用多效蒸馏海水淡化喷淋实验台对理论计算结果进行实验测试和验证。研究结果表明:正常工作状态下喷嘴流量系数、喷淋锥角、喷淋流量等参数理论值与测量值之间的误差小于5%,验证了设计模型的准确性。同时根据实验测试数据,拟合得到该类型空心锥喷嘴喷淋锥角与雷诺数之间的经验公式,可为蒸馏海水淡化用大流量空心锥喷嘴的结构设计、工艺选型提供理论指导和数据支持。     

喷淋液滴在空气环境下的运动特性

本文以喷淋液滴在空气环境下运动特性为工程背景，建立单个液滴在常温、常压空气环境中的动量方程，分析液滴沉降特性、追赶特性及运动轨迹行为。计算结果表明，不同喷淋液滴初始条件下，短时间内存在重力大于曳力和重力小于曳力两种情况，但最终减速液滴均会达到受力平衡状态；液滴离开喷淋头后，垂向位移均迅速增大，液滴粒径越大、初始速度越大，垂向位移增长的速率也越大，达到相同位移的用时越短；液滴尺寸、初始速度相差越大，液滴追赶所用的时间越短，追赶位移越小，液滴尺寸、初始速度越接近，液滴追赶所用的时间越长，追赶位移越大；液滴初始速度越大、初始直径越大、喷射角度越大，横向速度消失越慢，达到的横向位移越大，喷射液滴覆盖的面积也越大。计算结果有助于优化工程实际中喷淋系统的设计与布置。     

板栗壳黄酮结构分析及其对胰脂肪酶活力的抑制作用

在分析板栗壳黄酮结构的基础上，研究其对胰脂肪酶的抑制作用及类型。采用醇提法提取板栗壳中的黄酮，并用AB-8大孔吸附树脂进行纯化，冻干后得到的黄酮含量为（107.50±1.00）mg/g，提取得率为（5.66±0.05）%。利用超高效液相色谱-四极杆/静电场轨道阱质谱联用技术对板栗壳黄酮进行结构分析，鉴定出8 种黄酮类化合物。采用对硝基苯酚法测定胰脂肪酶活力，分别考察板栗壳黄酮对胰脂肪酶的抑制效果及不同反应条件下板栗壳黄酮对胰脂肪酶活性的影响，结果表明，板栗壳黄酮对胰脂肪酶有较好的抑制作用，半抑制浓度（half maximal inhibitory concentration，IC50）为0.074 mg/mL，且使胰脂肪酶最适pH值向碱性偏移。通过Lineweaver-Burk双倒数作图法确定其抑制类型为非竞争性抑制，抑制常数Ki＝53.19 mg/mL。由此可见，板栗壳黄酮是一种效果良好的胰脂肪酶抑制剂。     

Effects of feed composition,protein denaturation and storage of milk serum protein/lactose powders on lactosylation

During whey powder production, the feed is subjected to several heat treatments which can cause lactosylation of proteins. In this study, lactosylation of whey proteins was evaluated in spray-dried powders before and after storage by varying the native protein fraction as well as the serum protein/lactose ratio in the powders. The lactosylation of native α-lactalbumin and β-lactoglobulin in the powders before storage was not affected to a large extent by the protein denaturation or if the feed had been heat treated in a high or low lactose environment. After storage (relative humidity of 23.5%, 30 °C, 25 days), the kinetic of lactosylation tended to increase with increasing native protein fraction and bulk protein content in the powders. An explanation could be that proteins dissolved in the lactose glassy structure might have a lower reactivity, while proteins present in the protein glassy structure with dissolved lactose may display higher lactosylation reactivity.     

HVOF制备MCrAlY涂层过程中WC杂质颗粒的演变遗传行为研究

在热喷涂工业生产过程中,喷涂制备不同材料体系的涂层之前需要对送粉路径(送粉罐、送粉盘、搅拌器、送粉管路、送粉针)进行清理,但由于送粉路径内部结构复杂且存在静电吸附效应,使得残留于喷涂系统的粉末无法被完全去除,通常以微量杂质颗粒的形式被带入新涂层,进而影响新涂层的性能。为此,本文研究了在单晶基材表面采用高速火焰(HVOF)喷涂制备MCrAlY涂层过程中,送粉路径残留的WC杂质颗粒(WC-10Co4Cr)在涂层及涂层与基材界面处的遗传演变行为,分别采用SEM、EDS分析了WC杂质在喷涂态、热处理态涂层中的微观组织和相组成。研究结果表明,WC杂质颗粒确实存在于MCrAlY涂层中,并在后期热处理及氧化试验中进一步分解而固溶于涂层中,甚至扩散至单晶基材内部引起含W碳化物的生成,影响涂层及单晶基材的显微组织,改变局部的成分均匀性。同时,本文还采用ThermoCalc软件进行了热力学计算模拟,辅助分析了WC分解及W与C元素在显微组织中的遗传特性。对于WC类粉末和MCrAlY粉末共用的HVOF喷涂设备,建议给MCrAlY粉末配备单独的送粉路径,以确保涂层的纯净度与质量。