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Salehe Gomroki Zahra Yavari Ahmad Reza Abbasian Meissam Noroozifar 《International Journal of Applied Ceramic Technology》2021,18(6):2099-2110
The spongy nickel oxide (SNO) was synthesized the solution combustion method. The SNO was selected as a promoter to boost the catalytic activity of nanoraspberry-like palladium (NRPd) toward electrooxidation of five light fuels (LFs): methanol, ethanol, formaldehyde, formic acid, and ethylene glycol. The X-ray powder diffraction, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy, and field emission scanning electron microscope techniques were used for the materials characterization. In comparison with nonpromoted Pd, the NRPd-SNO electrocatalyst shown an excellent efficiency in parameters like the electrochemical active surface area and anti-CO poisoning behavior. The turnover data and the parameters, including reaction order, activation energy, and the coefficients of electron transfer and diffusion, were evaluated for the each process of LFs electrooxidation. The outcome for NRPd-SNO activity toward LFs electrooxidation was compared to some reported electrodes. The SNO increases the removal of intermediates created in the oxidation of LFs that can poison the surface of palladium catalyst. This is due to the presence of the lattice oxygens in SNO structure and Ni switching between its high and low valances. The compatibility of the adsorption process of LFs on the surface of the NRPd-SNO catalyst with different isotherms was determined by studying the Tafel polarization and calculating the surface coverage. 相似文献
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Alexander Haseloer Tamara Lützenburg Joss Pepe Strache Dr. Jörg Neudörfl Prof. Dr. Ines Neundorf Prof. Dr. Axel Klein 《Chembiochem : a European journal of chemical biology》2021,22(4):694-704
Three chiral tridentate N^N^S coordinating pyridine-carbaldehyde (S)-N4-(α-methylbenzyl)thiosemicarbazones (HTSCmB) were synthesised along with lysine-modified derivatives. One of them was selected and covalently conjugated to the cell-penetrating peptide sC18 by solid-phase peptide synthesis. The HTSCmB model ligands, the HTSCLp derivatives and the peptide conjugate rapidly and quantitatively form very stable PtII chlorido complexes [Pt(TSC)Cl] when treated with K2PtCl4 in solution. The Pt(CN) derivatives were obtained from one TSCmB model complex and the peptide conjugate complex through Cl−→CN− exchange. Ligands and complexes were characterised by NMR, IR spectroscopy, HR-ESI-MS and single-crystal XRD. Intriguingly, no decrease in cell viability was observed when testing the biological activity of the lysine-tagged HdpyTSCLp, its sC18 conjugate HdpyTSCL-sC18 or the PtCl and Pt(CN) conjugate complexes in three different cell lines. Thus, given the facile and effective preparation of such Pt-TSC-peptide conjugates, these systems might pave the way for future use in late-stage labelling with Pt radionuclides and application in nuclear medicine. 相似文献
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对蒙古精矿在包钢624 m2带式球团的合理利用进行了全面研究。研究表明,随着蒙古精矿配比增加,球团矿品位提高,还原膨胀率增加,当配比小于20%时,还原膨胀率小于20.0%,主要是由于还原后球团矿矿物组成中析出大量金属铁,在浮氏体(FexO)转变为铁的阶段,铁晶粒自浮士体表面向外长出晶须,晶须的生长让晶粒产生位移或晶粒开裂,导致球团结构疏松发生膨胀。通过添加适量矽石,可显著降低球团还原膨胀率,当配加30%~50%的蒙古精矿时,可通过添加1.0%~2.0%的矽石,将球团还原膨胀率降低至20%以内,球团矿质量满足高炉冶炼生产要求。 相似文献
5.
《中国稀土学报(英文版)》2019,37(7):760-766
A novel process of calcification-leaching for bastnaesite concentrate(REFCO_3) was proposed. The prior calcification was carried out in the system of NaOH-CaO-H_2O and the lgC-pH pattern for Ce-F-Ca-C-H_2O system was drawn. The thermodynamics result indicates that decomposition for bastnaesite requires certain alkaline condition, but excessive alkalinity also causes decomposition of CaF_2. XRD and SEM-EDS analyses on the calcification-leaching process reveal that bastnaesite first decomposes into RE(OH)_3 and CaF_2. Then, by HCl leaching rare earths were extracted,while CaF_2 was left in the leaching residue. In addition, effects of temperature, time, NaOH and CaO on the calcification were investigated. The results show that the leaching rate of rare earths(REs)reaches 72.5 wt%, at the same time 99.2 wt% of F is left in leaching residue with 20 wt% NaOH and 38 wt% CaO at 493 K for 180 min. 相似文献
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准确测定辛酸铑催化剂中杂质元素含量,是判定产品是否合格的重要指标之一。以往常采用直流电弧发射光谱法(摄谱法)进行检测,但测定周期长,且重复性较差。用电感耦合等离子体原子发射光谱法(ICP-AES)测定辛酸铑催化剂中微量杂质元素时,辛酸铑催化剂样品中含有的大量有机组分和铑基体会对测定有严重干扰。实验采用反复滴加硝酸消解样品中有机组分,再用王水溶解盐类,选用合适背景点扣除的方式消除铑基体的干扰,建立了使用ICP-AES测定辛酸铑催化剂中0.001%~0.1%(质量分数)Pt、Pd、Pb、Fe、Cu、Al、Ni等7种微量杂质元素的方法。各元素在0.10~10.00μg/mL范围内与其发射强度呈线性关系,相关系数均大于0.9999;方法检出限(μg/mL)为0.075(Pt)、0.0033(Pd)、0.015(Pb)、0.0036(Fe)、0.010(Cu)、0.001(Al)、0.012(Ni)。实验方法用于测定辛酸铑催化剂样品中Pt、Pd、Pb、Fe、Cu、Al、Ni,结果的相对标准偏差为(RSD,n=7)为1.4%~9.6%。按照实验方法测定辛酸铑催化剂中Pt、Pd、Pb、Fe、Cu、Al、Ni,并与直流电弧发射光谱法的测定结果进行比对,结果相一致。 相似文献
8.
针对湖南柿竹园铋精矿火法冶炼过程中存在的成本高、低浓度SO2和散烟排放污染环境、有价金属综合回收率低等问题, 以柿竹园铋精矿为原料, 提出了加压氧化氨浸分离铋与铜、硫的新工艺, 研究了氨水加入量、浸出温度、浸出时间、浸出压力及浸出液固比等因素对铜、硫、铋浸出率的影响。在氨水用量1.8 mL/g铋精矿、液固比4∶1、釜压2.8 MPa、浸出温度160 ℃、浸出时间5 h、搅拌速度600 r/min的优化工艺条件下, 铜、硫浸出率分别达93.57%和92.87%, 铋不浸出并以氧化铋形态全部入渣, 实现了铜、硫与铋的高效分离。 相似文献
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广东某复杂铜铅锌矿石中的矿物嵌布粒度较细且相互包裹,导致现场铜、铅、锌浮选分离困难,为解决此问题进行了选矿试验研究。结果表明:在选铜时,选用FK 1与DS组合抑制铅锌,可有效解决精矿的互含问题;在高碱工艺下,采用先铜后锌的优先浮选工艺,铜铅粗泡再磨后经2次精选,能获得铜品位为2110%、回收率为8088%的铜精矿,铅锌总含量为1023%,达到铜精矿四级品要求;采用1粗2精2扫流程处理选铜尾矿,获得了锌品位为5217%、回收率为9278%的锌精矿。试验所用药剂全部为常规药剂,试验流程结构简单,现场实施比较容易,可作为现场改造的依据。 相似文献
10.
Newsha Omrani Khiabanian Ali Motamedzadegan Shahram Naghizadeh Raisi Mazdak Alimi 《Journal of texture studies》2020,51(3):488-500
Replacement of milk protein with protein isolates from vegetable resources can significantly influence the characteristics of feta whey less cheese and also decrease the cost of final production. In this study, various blends of milk protein concentrate (MPC) and pea protein isolate (PPI) were mixed at levels of 12% MPC and 0% PPI (MP0), 10% MPC and 2% PPI (MP2), 9% MPC and 3% PPI (MP3), 8% MPC and 4% PPI (MP4), 7% MPC and 5% PPI (MP5), 6% MPC and 6% PPI (MP6) and used in the manufacture of wheyless feta cheese. The chemical, textural, rheological, and sensorial properties, as well as the microstructure of the cheese samples, were evaluated after 1, 15, and 30 days of storage. The general linear model procedure of SAS statistical software was used for statistical analysis. Duncan's multiple range tests was used to compare the means of different treatments. The results showed that all properties of the cheeses were influenced by different levels of PPI due to different total solids content. The use of high concentrations of PPI resulted in a more open protein network, softer structure and decreasing the storage (G′) and loss (G″) moduli in the cheeses. Sensory evaluation of the samples revealed that total score in terms of flavor, texture and overall acceptability was gradually decreased with increasing PPI levels, but still preferable for the panelists. Furthermore, for each sample, with increasing levels of PPI, the whiteness and the greenness were decreased, but the yellowness was increased. 相似文献