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为克服三乙醇胺早强剂对水泥抗折强度和后期强度的影响,合成了马来酸三乙醇胺酯,并通过背散射电子成像(BSE)和BET分析,研究了马来酸三乙醇胺酯对水泥水化程度、C-S-H含量和水泥水化28 d分形维数的影响。结果表明:马来酸三乙醇胺酯可促进水泥水化尤其是水泥中硅酸盐相的水化;复掺马来酸三乙醇胺酯和聚羧酸减水剂,可显著提高水泥水化产物中C-S-H的含量;三乙醇胺降低了水泥石28 d的分形维数,马来酸三乙醇胺酯单掺及与聚羧酸减水剂复掺则使水泥石28 d的分形维数提高。由此可见,马来酸三乙醇胺酯作为增强型水泥早强剂具有广阔的应用前景。 相似文献
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Jackson Gurung 《Chemical Engineering Communications》2020,207(10):1462-1473
AbstractAddition of organic solvents is known to change the properties of amphiphiles through modification of bulk phase. Amitriptyline hydrochloride (AMT) is a tricyclic amphiphilic drug which is usually used as an antidepressant. In drug delivery, the cloud point (CP) of the drug is an important parameter. This article discusses the effects of ethanol–water (EtOH–WR) compositions on the energetic parameters, such as changes in Gibbs energy of clouding (ΔsG0), enthalpy of clouding (ΔsH0), and entropy of clouding (TΔsS0) of AMT-additive systems. Monovalent alkali halide salts, cationic conventional surfactants, and gemini surfactants were used as additives in the EtOH–WR mixed media whose compositions were varied between 0 and 15% (w/w). The ΔsG0 values are positive for all the additives and the values decrease with the rise in mole fractions of the additives. The ΔsH0 and TΔsS0 were noted to be positive except for KF in 15% EtOH–WR mixed media. 相似文献
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ABSTRACTImproving the hydration resistance of CaO particle in manufacturing and application of free CaO-containing materials has practical significance. In this study, CaO granules was made from Ca(OH)2 particles, which were fabricated by the granulation method. The results showed that the hydration resistance of the CaO granules which was prepared under 1700?r?min?1 was the best, the CaO granules was sintered well in calcination process, the shell of CaO granules was relatively dense, which improves the hydration resistance of CaO granules, and the rate of hydration weight increment was 0.58% after placed in the air for 20 days under a temperature of 10–14°C and a relative humidity of 57–81%. 相似文献
5.
Shaokun Liu Yaowu Wei Jinhu Wang Nan Li Junfeng Chen Bingqiang Han 《Journal of the American Ceramic Society》2020,103(9):5302-5311
The hydration resistance of CaO materials prepared by Ca(OH)2 calcination with titanium chelating compounds is investigated in this paper. The crystalline phases and microstructure characteristics of sintered specimens were studied by X-ray diffraction (XRD), define FTIR spectroscopy, scanning electron microscopy (SEM), and energy dispersive spectrometer (EDS). The results showed that the hydration resistance of CaO samples was improved significantly, especially for samples with 9 wt% Ti chelating compound. The specimens with Ti chelating compound showed an increase in bulk density and a decrease in apparent porosity after heating when compared to the specimens without additive. The grain surface of CaO grain and the gaps between the CaO grain boundaries were covered with calcium phosphate glass phase, calcium phosphate showed two different shapes: irregular shape and rod shape. The formation and distribution of these two forms were the key factors that affecting the hydration resistance of CaO samples. 相似文献
6.
Tingjie Huang Qiang Yuan Shenghao Zuo Caijun Shi 《Journal of the American Ceramic Society》2020,103(11):6490-6504
Elastic behavior is an important aspect of fresh cement-based materials. In this paper, the elasticity development of fresh pure alite paste within 5 hours was monitored in situ by small amplitude oscillation shear. Isothermal microcalorimetry, X-ray diffraction, scanning electronic microscopy, 1H nuclear magnetic resonance, zeta potential measurements were used to investigate the underlying mechanisms. It was found that the evolution of storage modulus can be characterized by three different stages. The first stage stems from the compression of electrical double layer and the slight increase of solid volume fraction; the second stage is only controlled by the colloidal interaction; and the third stage is associated to the significant growth of solid volume fraction, the enhancement of short-range attraction and the rigidification of calcium silicate hydrate (CSH) network. Moreover, the relationship between the formation of CSH and the growth of elasticity was also quantified. 相似文献
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混凝土水化热条件下人工冻土墙与内衬结构共同作用研究 总被引:1,自引:0,他引:1
研究了在人工冻土墙形成并达稳定温度场分布呈非线性后,基坑开挖并浇注大体积混凝土衬砌时,混凝土水化热对冻土墙温度场及其耦合应力场分布的影响,分析得出了在冻土墙温度场分布改变过程中,其与内衬共同作用应力场的变化规律.内衬混凝土水化热会使其邻近的冻土融化,之后在冻结管冷源的作用下融土又回冻,冻土墙温度场会发生非线性的变化过程;在冻土墙内侧随工况进行自上而下移动的融化区域使围护结构体系的应力场不断的变化,冻土墙内侧所受径向应力增大,内衬的支护作用提高,冻土墙支护性能下降;同时,冻土墙位移趋势加大,内衬支护作用的提高并没有完全遏制冻土墙的位移发展,说明冻土墙是主要的支护结构。 相似文献
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徐淮矿区深部土体工程地质特性及失水变形机理 总被引:13,自引:4,他引:13
以研究徐淮矿区深部土体工程地质、水地质基本性质为基础,首次从吸附结合水含量及其性质方面,探讨了该区深部土体失不变形机理与同有一般认识的不同,得到该区内深部底含失水时粘土层不压缩、砂克层压缩的结论,对认识该区内井筒破裂、地面沉降等环境地质问题具有意义。 相似文献