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《Ceramics International》2022,48(24):36835-36844
Molybdate and tungstate with scheelite-type structure are excellent self-luminescent materials, which can be used as ideal hosts for the doping of rare-earth ions. In this study, a series of Eu3+-activated SrAO4 (A = Mo and W) phosphors were successfully synthesized, and their crystal structures, photoluminescence properties, and temperature measurement performance were analyzed in detail. These phosphors were excited by UV light (291 nm and 247 nm, respectively), with clear energy transfer (ET) (MoO42?→Eu3+ or WO42?→Eu3+). According to fluorescence intensity ratio (FIR) and Judd–Ofelt (J–O) theory, compared to SrWO4:0.01Eu3+ phosphor, SrMoO4:0.01Eu3+ phosphor exhibited better thermal stability, with relatively low Sa value (maximum values were 5.082 %K?1 and 20.74 %K?1, respectively), and their Sr values were not significantly different (maximum values were 0.864 %K?1 and 0.83 %K?1, respectively). Sa value was negatively correlated to central asymmetry of Eu3+, but the optimal Sr value tended to be more suitable for central asymmetry of Eu3+. In addition, Eu3+ exhibited stronger central asymmetry as well as covalency of Eu–O bond in SrMoO4. Results reveal that SrMoO4:xEu3+ and SrWO4:xEu3+ can be used for luminescent thermometers. 相似文献
3.
南水北调中线总干渠无在线调蓄水库,对藻类生态调度过程中出现的问题开展生态调度实现策略和实施方式研究。主要实现策略包括:划定自身的调蓄区,隔离生态调度对下游的影响;采用高效的渠池运行方式,减少生态调度时蓄量的反复调整;综合考虑安全、快速、平稳等需求,设定生态调度实施进程和方式。具体实施方式包括:将总干渠划分为流速调控区、调蓄区和正常运行区,分别实施等体积、控制蓄量和闸前常水位方式运行;将生态调度过程划分为充水阶段和泄水阶段,基于流速调控目标值、持续时长和水位降幅约束条件,确定各阶段时长和各分区的闸门群调控方案等。基于2018年3月输水工况,采用明渠一维非恒定流模型,仿真总干渠上游15个渠池的藻类生态调度过程。结果表明,生态调度可在3.5 d内完成,各渠池的平均流速由0.48 m/s增至0.93 m/s,持续时间超过2 h。在整个生态调度过程中,水位变化平稳,水位变幅符合安全阈值要求,下游渠道的正常运行未受生态调度明显影响。 相似文献
4.
为进一步提高城市生态监测的精确度,在前人开展的城市生态遥感监测研究的基础上引入“区域尺度”的概念,充分考虑小区域范围内不同地物间的交互作用,并利用移动窗口模型(Moving Window-Remote Sensing Ecology Index, MW-RSEI)对沈阳市浑南区的遥感影像进行逐像元分析。实验结果表明,MW-RSEI模型和生态遥感监测模型(Remote Sensing Ecology Index, RSEI)在整体生态评价趋势上表现出一致性。但MW-RSEI模型对城市生态中的细节区域表征更明显。考虑到建筑及裸地周围植被的影响,其较差生态区域的占比仅为6%,生态评价为优的区域占比为11%。研究区生态评价结果表现得较为连续,并未出现明显的断层现象。该结果具有现实意义且与实际生态分布更为符合。MW-RSEI模型在城市生态监测中更为适用,可为相关部门提供一定的技术参考。 相似文献
5.
Aiming at the performance degradation of the existing presentation attack detection methods due to the illumination variation, a two-stream vision transformers framework (TSViT) based on transfer learning in two complementary spaces is proposed in this paper. The face images of RGB color space and multi-scale retinex with color restoration (MSRCR) space are fed to TSViT to learn the distinguishing features of presentation attack detection. To effectively fuse features from two sources (RGB color space images and MSRCR images), a feature fusion method based on self-attention is built, which can effectively capture the complementarity of two features. Experiments and analysis on Oulu-NPU, CASIA-MFSD, and Replay-Attack databases show that it outperforms most existing methods in intra-database testing and achieves good generalization performance in cross-database testing. 相似文献
6.
《Ceramics International》2022,48(24):36802-36813
X-type samarium-cadmium co-substituted hexaferrite with compositions Ba2-xSmxCo2CdyFe28-yO46 (0.00 ≤ x ≤ 0.08, and 0 ≤ y ≤ 0.4) were prepared at 1340 °C using a simple heat treatment technique. All heated samples were characterized using FTIR, XRD, SEM, VSM, M?ssbauer, and low-frequency dielectric measurements. XRD analysis of prepared samples shows the formation of X as a major phase along with hematite. The MS value varied from 67.01 Am2/kg to 50.43 Am2/kg; whereas the Hc value changed from 2.95 kA/m to 6.17 kA/m, A high value of MS (67.01 Am2/kg) is observed in the pure sample, and a very low value of Hc (2.95 kA/m) is observed for x = 0.06, y = 0.3 compositions, but Mr/Ms < 0.5 confirm the multi-domain nature of prepared hexaferrites. Hysteresis loops of all samples are narrow, and confirmed that formed samples belong to magnetically soft. Mössbauer spectra of the three samples (S1, S3, and S5) show the existence of doublets. Significantly low values of coercivity, retentivity, and loss tangent in Sm–Cd substituted samples signified those prepared materials can be used to design electromagnets, transformer cores, electric motors, and maybe a potential candidate for lossless low-frequency applications. 相似文献
7.
Floating treatment wetlands (FTWs) use plants’ roots for water quality improvement. The plants are supported by a buoyant structure deployed at the water surface. The roots form a porous zone beneath the structure and remove pollutants carried in suspension through filtering, absorption and uptake. This paper used CFD simulation to model FTWs arranged in series and spanning the channel width and to study the effects of root length and spacing between FTWs on flow distribution and mass removal. The root zone was modelled as a porous media, and removal was computed using first-order decay, for which a range of removal constants was tested. Longer roots increased the reactive volume of the root zone, which increased the fraction of pollutant inflow entering the FTWs. Increasing the distance between FTWs allowed greater mixing between water that went through and beneath the upstream FTW. This increased the concentration entering each FTW, which enhanced mass removal per FTW. However, a larger distance between FTWs reduced the number of FTWs in the channel, reducing the reactive volume. In the tradeoff between mixing and reactive volume, the reactive volume was more important, such that total removal in the channel increased with longer roots and more units of FTW (shorter gap distance). However, removing the gap entirely was detrimental, as FTWs in series removed more mass than a continuous FTW of same volume. This study points to two design recommendations for FTWs in series. First, if resources for building FTWs are not limiting, but the channel length is, it is preferable to prioritize higher reactive volume (shorter gap distance) to achieve maximum removal per channel length. Second, if resources for FTWs are limiting, but channel length is not, it is better to place the FTWs with a longer gap distance, preferably along enough to allow mixing over the full depth between FTWs, as this will achieve maximum removal per FTW. 相似文献
8.
近年来在下扬子地区页岩气地质调查井所获取的地层岩心资料,揭示该地区下志留统风暴沉积较为发育。基于精细的岩心观察描述,详细分析了下扬子地区下志留统高家边组下段中上部风暴沉积的特征,并阐明了风暴作用对泥页岩的影响。研究表明:研究区风暴岩岩性偏细,以粉砂岩为主,石英含量较高,结构成熟度较低,具2种不同的粒度概率曲线;主要发育底部冲刷面、块状层理、平行层理、丘状交错层理、波纹交错层理、准同生变形构造等沉积构造;垂向上主要识别出4种风暴沉积序列,均具有从底到顶粒度变细的沉积特征,不同的沉积序列与风暴流能量的强弱有关。下扬子地区早志留世频繁的风暴活动与研究区的古地理背景和古气候条件具有内在联系。特大型风暴对浅海陆棚深水区的细粒泥质沉积物特征产生重要影响,包括降低有机质含量、减少单层厚度、破坏垂向连续性、改变原始沉积构造和侧向稳定性等,总体上降低了泥页岩的品质。因此,研究认为在页岩气的勘探和评价过程中应重视风暴因素对陆棚深水区原始泥质沉积物的影响。 相似文献
9.
益生菌可在肠道定植从而发挥抗炎或抗氧化活性,有利于宿主肠道健康。本实验研究了从新疆传统发酵乳制品中分离得到的8?株植物乳杆菌对大肠杆菌侵袭和过氧化氢刺激肠上皮细胞HT-29的保护作用。结果表明:在8?株植物乳杆菌中,植物乳杆菌35具有最高的黏附能力。植物乳杆菌35可通过取代、竞争、排阻的方式抑制大肠杆菌对HT-29细胞的黏附,抑制率分别为42.60%、59.17%、60.19%。植物乳杆菌35及其多糖可抑制大肠杆菌刺激HT-29细胞产生白细胞介素-8;同时保护HT-29细胞免受过氧化氢的损伤,增加超氧化物歧化酶、谷胱甘肽过氧化物酶活力水平并降低丙二醛含量。结论:植物乳杆菌35及其粗胞外多糖具有抑制大肠杆菌O157诱导的炎症性肠病的潜力。 相似文献