阿尔泰南缘北塔山组火山岩锆石U-Pb定年及地质意义

新疆阿尔泰南缘北塔山组火山岩较为发育。本文对新疆阿尔泰南缘默色克奥依一带北塔山组火山岩进行地球化学分析和年代学研究。研究表明：U-Pb锆石年龄为（384.3±4.0Ma）Ma，为中泥盆世；该组火山岩属于钾质钙碱性系列，全碱（Na2O+K2O=2.07%-6.49%）和YiO2（0.24%-0.64%）含量较低，K2O含量（1.11%-4.04%）变化较大，稀土元素含量（∑REE）较低。稀土元素显示其轻稀土富集且分馏不明显；δEu值均大于1，为Eu富集型；δCe值均小于1，为Ce亏损型。该组火山岩微量元素P明显富集，K、Rb、Ba等大离子亲石元素（LILE）略富集，亏损Ta、Zr、Hf、Ti等高场强元素（HISF）。结合前人研究，本文认为默色克奥依一带北塔山组火山岩形成于岛弧及与俯冲过程有关的活动大陆边缘造山带环境，为泥盆纪古大洋俯冲消减过程中，俯冲板片脱水产生的流体交代上覆地幔楔部分熔融的产物。     

Crystallization in Confinement

Many crystallization processes of great importance, including frost heave, biomineralization, the synthesis of nanomaterials, and scale formation, occur in small volumes rather than bulk solution. Here, the influence of confinement on crystallization processes is described, drawing together information from fields as diverse as bioinspired mineralization, templating, pharmaceuticals, colloidal crystallization, and geochemistry. Experiments are principally conducted within confining systems that offer well-defined environments, varying from droplets in microfluidic devices, to cylindrical pores in filtration membranes, to nanoporous glasses and carbon nanotubes. Dramatic effects are observed, including a stabilization of metastable polymorphs, a depression of freezing points, and the formation of crystals with preferred orientations, modified morphologies, and even structures not seen in bulk. Confinement is also shown to influence crystallization processes over length scales ranging from the atomic to hundreds of micrometers, and to originate from a wide range of mechanisms. The development of an enhanced understanding of the influence of confinement on crystal nucleation and growth will not only provide superior insight into crystallization processes in many real-world environments, but will also enable this phenomenon to be used to control crystallization in applications including nanomaterial synthesis, heavy metal remediation, and the prevention of weathering.     

Cofactors as Molecular Fossils To Trace the Origin and Evolution of Proteins

Due to their early origin and extreme conservation, cofactors are valuable molecular fossils for tracing the origin and evolution of proteins. First, as the order of protein folds binding with cofactors roughly coincides with protein-fold chronology, cofactors are considered to have facilitated the origin of primitive proteins by selecting them from pools of random amino acid sequences. Second, in the subsequent evolution of proteins, cofactors still played an important role. More interestingly, as metallic cofactors evolved with geochemical variations, some geochemical events left imprints in the chronology of protein architecture; this provides further evidence supporting the coevolution of biochemistry and geochemistry. In this paper, we attempt to review the molecular fossils used in tracing the origin and evolution of proteins, with a special focus on cofactors.     

因子分析在冀东峪耳崖金矿地球化学找矿中的应用

峪耳崖金矿位于华北板块北缘，矿区基底地层为太古界迁西群麻粒岩相和角闪岩相，矿体受NNE—NE向断裂构造控制，赋矿围岩为花岗岩。在矿床地质特征基础上，利用矿区土壤地球化学数据，采取传统统计法和累计频率法圈定了金矿12个元素的异常范围；运用因子分析方法划分出了Sb Hg Pb As元素组合、Au Ag Bi元素组合、Zn Cu Sn元素组合和W Mo元素组合；再对因子得分进行趋势面分析，较为有效地突出了深层次的找矿信息，更准确地圈出成矿靶区。结合研究区地质特征认为Au Ag Bi元素组合和Sb Hg Pb As元素组合为研究区最佳地球化学标志元素组合，下一步地质工作重点应放在矿区中矿带矿体深部及其南部异常高值区，同时布置少量工程在北矿带，以追索与唐杖子金矿之间的联系。     

叠合盆地凸起区多期复杂断裂特征及形成机制——以准噶尔盆地车排子凸起为例

以高精度三维地震资料为基础,结合构造演化恢复和区域构造背景,系统研究了准噶尔盆地车排子凸起断裂分布和形成机制。结果表明,车排子凸起发育深部和浅部2套断裂体系,深部断裂体系和浅部断裂体系分别发育3种断裂样式。车排子凸起共经历5个构造演化阶段,其中,晚二叠世挤压-逆冲控制了深部断裂体系的初始形成,晚侏罗世逆冲-走滑控制了深部断裂体系的最终定型,新近纪叠加掀斜、局部伸展控制了浅部断裂体系的形成。不同断裂体系在油气成藏过程中均起到了重要作用。其中:深部断裂体系的红车断裂是重要的油源断裂,低序级断层控制形成了石炭系火山岩优质储集体;浅部断裂体系使得油气向浅部层系运移调整,同时形成了断块圈闭、断鼻圈闭和断层-岩性圈闭等丰富的圈闭类型。     

马来盆地油气成藏条件及主控因素分析

马来盆地主要发育早渐新世-早始新世湖相页岩和早中新世-晚中新世河流三角洲相页岩、煤层两套烃源岩。北部烃源岩处于过成熟和生气阶段,中部和南部烃源岩以生油为主。盆地南部和东南部的砂岩储层发育,J组砂岩是马来盆地最重要的储层。挤压背斜是马来盆地最多产的圈闭类型。将马来盆地划分为8个油气成藏组合。渐新世-全新世发育的成藏组合viii,油气资源最为丰富,石油储量占整个盆地的85%,天然气储量占48%;其次是成藏组合iv。成藏控制因素主要为构造反转作用、断层活动等。构造反转作用对烃源岩生油、油气运移、保存等影响很大,是控制马来盆地油气成藏的重要因素之一。     

克拉苏构造带盐下超深层储层的构造改造作用与油气勘探新发现

塔里木盆地克拉苏构造带油气群下白垩统巴什基奇克组埋深超过6 000 m,储层基质渗透率低,裂缝普遍发育,构造对储层的改造作用明显,但博孜9井的勘探突破反映出不同区带间构造改造作用差异较大、非均质性极强,重新认识构造对储层的改造作用对于预测超深层储层、指导油气勘探生产具有重要的意义。为此,基于钻井取心、构造平衡恢复、裂缝充填物同位素测年、区块应力数值模拟等资料,结合流体包裹体、声发射古应力、铸体薄片等实验分析方法,从定性分析到定量计算、研究了克拉苏构造带油气群超深层储层的构造改造作用及其差异性。研究结果表明:①北部天山造山带及南部古隆起控制了该构造带储层的沉积格局及差异构造变形,形成巴什基奇克组储层"西薄东厚"的分布特征;②博孜区段古应力最小,构造变形主要为正向挤压、逆冲传播,局部井区为斜向压扭;③大北区段主要为斜向压扭,古应力较小,构造变形为逆冲叠置;克深区段古应力最大,构造变形主要为正向挤压、后缘逆冲抬升、前缘滑脱收缩;④差异构造变形使同一构造带不同构造变形样式的构造减孔量呈现出较大的差别,且控制了不同区段造缝期与成岩胶结的叠加影响、中晚期裂缝网络与油气成藏期的配置关系,加剧了储层的非均质性,是区段间产能差异的基础改造因素;⑤现今构造应力的大小及方向影响裂缝有效性,南部为强挤压应力区,背斜相对高部位裂缝走向与现今应力交角较小,裂缝有效性最好;⑥构造成岩环境决定了构造裂缝充填物的类型,北部区块以淡水—半碱水介质成岩环境为主,裂缝充填物类型为方解石,有利于对储层进行酸化压裂改造。     

Long-term monitoring of natural hydrogen superficial emissions in a brazilian cratonic environment. Sporadic large pulses versus daily periodic emissions

In many basins, hydrogen-emitting structures are now observed, but the estimation of the H₂ flow leading to their formation remains poorly constrained since all data show that the H₂ emissions are variable in space and time. We present here the data of a long-term monitoring campaign with a high density of permanent hydrogen detectors installed in 2 structures in the Minas Gerais State (Brazil). Results show that two kinds of signals are recorded, large sporadic pulses that affect the H₂ content of the soil for one or two days and smaller ones, with a daily periodicity, that last 6 h and during which the near surface soil concentration usually does not exceed 200 ppm. This last signal is very regular in frequency, less in amount, and the daily maximum happens around noon or in the early afternoon. We interpret the large pulses as evidences of a deep hydrogen flux, leaking either from a reservoir located in the subsurface, from an aquifer which is degassing or, although it seems unlikely, directly from the H₂ generation area.The time correlation between the pulse and the increase of the daily signal suggests that this last one corresponds to the slow release of the gas that has been captured by the soil during its transport towards the surface. This daily signal is most likely influenced by external factors such as atmospheric pressure and sub-surface bacterial activity. In map view, the lack of correlation between the highest hydrogen concentrations over time suggests that the soil is very heterogeneous and that preferential pathways exist. The results confirm that long-term monitoring, over a few months, is mandatory to catch a certain number of high pulses and so to have a better estimation of the real flow. Data also suggests that sensors with a large concentration range should be used (from 10 to several 10⁴ ppm). Even if quantification of leakage doesn't help to quantify the subsurface reserves, these new data allow a more precise evaluation of the quantity of H₂ released in surface by these structures, few hundred of kilo per day, and confirm the high H₂ prospectivity of this basin.     

“多能源同盆共存”中铀的煤地球化学研究现状及思路

在阐述“多能源同存共盆”研究理念的由来和产生背景的基础上,从煤地质学的角度,指出了多能源同盆共存理论现有认识中的不足和亟待解决的问题,阐明了在多“能源同盆共存”统一背景下铀的煤地球化学研究的必要性和紧迫性.指出,强化对煤系烃源岩型（或煤系有机岩即煤岩型及煤系泥岩型）铀的富集机理和赋存规律的专项研究是建立“多能源同盆共存”理论的重要基础,进一步深入展开对煤中微量元素、常量元素与铀的赋存状态及其相互关系研究,查明煤中某些显微组分与铀相关性、油气转化过程中铀的地球化学行为,是煤地球化学在建立“多能源同盆共存”理论中应发挥的重要作用.     

潜江凹陷潜江组盐湖地层演化与层序发育特征

结合盐湖层序地层分析，在系统测试了潜江凹陷潜江组碳、氧同位素后，对其演化规律与层序地层的关系进行了探讨，研究结果表明：潜江组内δ^13C和δ^18O值的变化范围分别是-7.37‰～2.35‰。和-6.42‰～0．23‰(PDB)。在低位体系域的初期和高位体系战的末期，由于湖水范围较小，这对如果降雨量小于蒸发量就会有盐岩的沉积，所以其碳、氧同位素的值偏大；而在水进体系战时期，由于湖平面上升，湖水的注入量大于蒸发量，所以这一对期没有盐岩的沉积，碳、氧同位素的值也偏低。然而在对潜江组的潜四段进行研究时，却发现碳、氧同位素的分布不具上述规律。在潜四段盐岩不仅分布于低位体系战的初期和高位体系战的末期，而且在水进体系域中也可见盐岩。作者认为潜江凹陷潜江组可能存在另一种成盐模式一深水事件性成盐。