Fe3O4-carbon spheres core–shell supported palladium nanoparticles: A robust and recyclable catalyst for suzuki coupling reaction

Suzuki-Miyaura (S-M) is regarded the most powerful way for synthesis biaryls, triaryls, or incorporating of substituted aryl moieties in organic preparation by the cross-coupling of aryl boronic acid with aryl halides using the Pd catalyst. This work reports the combining of the hydrothermal and microwave-assisted protocol to convert the glucose to magnetic carbon spheres (Fe₃O₄-CSPs) decorated with Pd nanoparticles (NPs) as the catalyst for Suzuki-Miyaura cross-coupling reactions. The physicochemical properties in the produced composite were examined using FESEM, HRTEM, nitrogen isotherms, Raman spectroscopy, FTIR, XPS, and XRD. The as-fabricated composite Pd/Fe₃O₄-CSPs is mostly spherical with a core–shell structure and possesses a great surface area of 253.2 m²·g^-1. Its catalytic performance demonstrates that the composite has excellent stability and high tolerance Suzuki-Miyaura cross-coupling reactions in 30 min at 80 ℃. Both activated and deactivated aryl halides provided excellent yield. The as-fabricated catalyst was recycled for up to four catalytic cycles without a substantial decline in performance. Moreover, this research offers a facile roadmap for synthesizing Pd/Fe₃O₄-CSPs composites and promoting the practical implementation of Pd/Fe₃O₄-CSPs catalysts for organic transformation processes.     

Microstructure and mechanical behavior of laser aided additive manufactured low carbon interstitial Fe49.5Mn30Co10Cr10C0.5 multicomponent alloy

Laser aided additive manufacturing(LAAM)was used to fabricate bulk Fe49.5Mn30Co10Cr10C0.5 interstitial multicomponent alloy using pre-alloyed powder.The room temperature yield strength(σy),ultimate tensile strength(σUTS)and elongation(εUST)were 645 MPa,917 MPa and 27.0％respectively.The as-built sample consisted of equiaxed and dendritic cellular structures formed by elemental segregation.These cellular structures together with oxide particle inclusions were deemed to strengthen the material.The other contributing components include dislocation strengthening,friction stress and grain bound-ary strengthening.The high εUTS was attributed to dislocation motion and activation of both twinning and transformation-induced plasticity(TWIP and TRIP).Tensile tests performed at-40℃and-130℃demonstrated superior tensile strength of 1041 MPa and 1267 MPa respectively.However,almost no twinning was observed in the fractured sample tested at-40℃and-130℃.Instead,higher fraction of strain-induced hexagonal close-packed(HCP)ε phase transformation of 21.2％were observed for fractured sample tested at-40℃,compared with 6.3％in fractured room temperature sample.     

在腐植酸存在的条件下动态模拟铜在贻贝类体内的富积

正依据金属生物利用度模型,腐植酸对铜的络合作用有望降低水生生物对铜的生物利用度,就如生物配体模型(BLM)。这个模型在海洋无脊椎动物胚胎或是微藻类等不进食生物中得到了证实。但对于像紫贻贝等滤食性生物体,在腐植酸存在的条件下铜的富积较高,表明摄取的铜-腐植     

2016—2017年北天山地区两次6级地震前地电场异常

地下介质在应力积累过程中，会导致岩体裂隙结构变化，从而使得大地电场E_T的优势方位角发生变化.文中收集了2016年到2017年的数据，利用大地电场优势方位角方法，提取与分析了北天山地区2016年12月8日呼图壁6.2级和2017年8月9日精河6.6级地震前地电场异常，探讨这两次6级地震前的地电场异常表现特征.结果表明:这两次地震前，震中周围的乌鲁木齐、克拉玛依台均显示出显著的地电场异常，即岩体裂隙优势方位角异常；异常特征以突跳和偏转为主；岩体裂隙结构发生异常时间上存在准同步性，表现出短临异常信息.因此，地电场岩体裂隙优势方位角方法短期内具有一定的预报效能，可为今后利用地电场方法预测地震积累经验和震例.     

水泥基材料负载二氧化钛研究进展

在空气污染问题突出的大环境下,光催化材料由于自身可降解气相污染物的特点作为一种新型环保材料得到关注。二氧化钛(TiO_2)因自身优异的光催化性能和化学稳定性是使用最为广泛的光催化材料。将对水泥基质材料负载TiO_2产生的物理性能影响和光催化性能影响进行评价,针对当前研究存在的问题进行总结和展望,并提出了TiO_2应用于水泥基质材料的研究方向。     

Protection and control of microgrids usingdynamic state estimation

High penetration of Converter Interfaced Generations (CIGs) presents challenges in both microgrid (μGrid) circuit and other system with CIG resources, such as wind farms and PV plants. Specifically, protection challenges are mainly brought by the insufficient separation between fault and load currents, especially for μGrids in islanded operation, and the short connection length in μGrids. In addition, CIG resources exhibit limited inertia and weak coupling to any rotating machinery, which can result in large transients during disturbances. To address the above challenges, this paper proposes a Dynamic State Estimation (DSE) based algorithm for protection and control of systems with substantial CIG resources such as a μGrid. It requires a high-fidelity dynamic model and time domain (sampled value) measurements. For μGrid circuit protection, the algorithm dependably and securely detects internal faults by checking the consistency between the circuit model and available measurements. For CIG control, the algorithm estimates the frequency at other parts of a μGrid using CIG local information only and then utilizes it to provide supplementary feedback control. Simulation results prove that DSE based protection algorithm detects internal faults faster, ignores external faults and has improved sensitivity towards high impedance faults when compared to conventional protection methods. DSE based CIG control scheme also minimizes output oscillation and transient during system disturbances.