Boosting discharge capability of α-Ni(OH)2 by cobalt doping based on robust spherical structure

α-Ni(OH)₂ is a promising candidate of the currently commercialized β-Ni(OH)₂ due to its higher theoretical discharge capacity in alkaline solution; however, its instability and poor conductivity plague the practical application. Herein, we propose α-Ni(OH)₂ with Co doping and spherical structure to strengthen the stability and enhance the conductivity and use it as the cathode for nickel-metal hydride batteries. Studies show that proper Co doping promotes the electrochemical reaction between the active materials and the electrolyte due to the spherical α-Ni(OH)₂ with enlarged interlayer distance and abundant hole channels, as well as high conductivity of Co, therefore, the obtained spherical α-Ni(OH)₂ with 7 mol% Co doping delivers significantly improved discharge capability, which is 384.6 mAh g^?1 at 70 mA g^?1 (0.2 C), increased by 54.3 mAh g^?1 compared with pure α-Ni(OH)₂, and at a high current of 5 C, it still gives 269.4 mAh g^?1, in contrast 218.5 mA g^?1 for the pure α-Ni(OH)₂. Besides, the cycling stability of the α-Ni(OH)₂ with 7 mol% Co doping maintains 340 cycles at a capacity retention of 80% (1C), which is extended 110 cycles in contrast to the pure α-Ni(OH)₂. These results provide the underpinning platform of α-Ni(OH)₂ for battery applications with high discharge ability and cycle life.     

白云鄂博铌资源特征及开发利用新进展

对白云鄂博铌资源特征、选矿技术进展及发展趋势做了详细评述，指出白云鄂博矿石性质复杂是铌资源难以有效利用的主要因素，单一选矿工艺处理白云鄂博铌资源研究较少，主要是重选、磁选和浮选等工艺联合选别以及化学选矿，针对铌资源开发利用存在的问题，提出了先采用传统选矿方法预选富集获得铌精矿，再进行氯化焙烧处理的思路，对该铌资源的开发利用有良好的应用前景。      

Evaluation of the moulding process for production of short-fibre-reinforced C/C-SiC composites

For the production of C/C-SiC brake discs via the liquid silicon infiltration method (LSI), the hot pressing process is the state of art technique for the moulding of the CFRP composites. This technique consists of several manual steps which increase production cost. The overall cost can be reduced by implementing injection moulding process.In this paper the influence of the moulding process (hot pressing, injection moulding) on the properties of semi-finished and final products during the production of short-fibre-reinforced C/C-SiC composites by means of the LSI process are examined. The starting polymer is chemically characterised. Carbon-fibre-reinforced plastic (CFRP) composites are fabricated by hot pressing, as well as injection moulding process. The CFRP composites are converted into porous C/C composites by pyrolysis. Liquid silicon is infiltrated to form dense C/C-SiC composites, which are further investigated during the course of this paper. Significant differences in properties of the composites are discussed.     

含新型有机硅缓蚀剂的制备及性能研究

为了研究缓蚀剂组分及添加条件对发射药性的影响,设计并制备了一种含新型有机硅的缓蚀剂材料;采用烧蚀管法,对比石蜡+TiO2型缓蚀剂,研究了新型有机硅缓蚀剂的静态降烧蚀效果;采用密闭爆发器研究了不同缓蚀剂添加条件对高能硝胺发射药点火和燃烧性能的影响;采用14.5mm弹道枪和壁温测试装置,研究不同缓蚀剂添加条件对膛壁温度、内弹道性能和枪口烟雾的影响。结果表明,采用含新型有机硅的缓蚀剂,降烧蚀效果更为显著;随着缓蚀剂添加量的增加,压力峰值、弹丸初速也会产生小幅下降,但总体影响幅度较小;添加缓蚀剂后,射击过程膛壁峰值温度显著下降,下降幅度随着缓蚀剂添加量的增加而增加,在缓蚀剂质量分数为3%时,对身管壁温降低幅度可达17.1%,且产生的枪口烟雾量较少;在缓蚀剂质量分数为5%时,缓蚀剂添加过量,枪口产生较大烟雾。该缓蚀剂及添加条件有望应用于低烧蚀发射药配方中。     

基于UG的正交车铣加工回转体表面微观残留仿真

正交车铣加工的回转体表面由铣刀与工件的复合相对运动形成,其形成机理独特,多个参数影响其表面微观形貌。为研究切削参数对正交车铣回转体表面微观残留的影响,基于UG建立了正交车铣回转体表面的仿真加工方法,并通过Vericut构建了虚拟五轴车铣加工环境,由此仿真研究了周向每齿进给量对正交车铣回转体表面微观残留的影响,发现已加工表面微观残留高度随周向每齿进给量增加显著增大。     

高校实验室计算机网络故障诊断技术研究

为了提升高校实验数据处理水平,高校实验室的相关建设工作已经步入正轨,但层出不穷的信息安全问题也向高校实验室计算机网络维护工作提出了新的挑战。文章从现阶段高校实验室计算机网络的相关建设工作出发,简要论述引发网络故障的具体原因,并对其诊断技术进行探讨。     

Kinetics and thermodynamics modeling of Nd(III) removal from aqueous solution using modified Amberlite XAD7

New adsorbent material was obtained by modification of commercial Amberlite XAD7 with thiourea that represents a non-toxic, cheap and environmentally friendly extractant. Prepared adsorbent was used for removal of neodymium ions from aqueous solutions. Thiourea modified Amberlite involved in this study shows good adsorption capacities (74.3 mg/g) and excellent efficiency during Nd removal process. In order to elucidate the mechanism of the Nd adsorption process kinetic, thermodynamic and equilibrium studies were performed, establishing this way which kinetic model better describes the Nd adsorption process. Moreover the thermodynamic studies prove that the Nd adsorption on thiourea modified Amberlite XAD7 is an endothermic and spontaneous process.     

基于Johnson-Cook本构模型的高强度装甲钢动态力学性能参数标定及验证

具有高屈服强度的某装甲钢广泛应用于我国装甲车辆。为准确模拟该装甲钢的动态力学行为,开展基于Johnson-Cook（J-C）本构模型的动态本构参数标定及验证。采用万能材料试验机对该装甲钢进行不同温度下的准静态拉伸试验,同时采用分离式霍普金森压杆开展不同应变率下的压缩性能测试。基于实验数据和J-C本构模型,拟合得到该装甲钢的本构参数。基于轻气炮开展泡沫铝弹丸冲击均质梁的实验研究,分别采用J-C本构模型和理想弹塑性模型进行有限元仿真计算,并将冲击实验与数值结果进行对比分析。结果表明：该装甲钢具有应变率强化效应,且温度软化效应显著;采用J-C本构模型仿真的均质梁峰值挠度与试验结果的相对误差为1.7%~6.1%,残余挠度相对误差为0.6%~7.6%。