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1.
《Advanced Powder Technology》2022,33(11):103833
Eliminating the gold preg-robbing effect of carbonaceous matter in carbonaceous gold ores is crucial for gold leaching. In this study, suspension oxidation roasting was proposed to accelerate the decarbonization of carbonaceous gold ore. The characteristics of oxidation reaction process and gas release were analyzed by TG-DTA-FTIR. The phase transformation and microstructure evolution of samples during roasting were analyzed by XRD, SEM and BET. The results show that the gold preg-robbing effect was eliminated after the gasification of carbonaceous matter, and the CaO generated by decomposition of carbonates can effectively capture the SO2. After roasting for 75 min at 650 °C in a 20% O2 atmosphere, the total carbon removal rate reached 99.42%, the distribution of exposed gold increased from 28.85% to 77.10% and the gold leaching efficiency increased from 4.55% to 84.83%. In addition, about 70% sulfur was mainly fixed in the roasted products in the form of sulfate. Therefore, the suspension oxidation roasting process is an efficient and clean pretreatment method for carbonaceous gold ores. 相似文献
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《Ceramics International》2022,48(8):10506-10515
The search for materials and methods capable of reducing human impacts on the environment is of utmost importance nowadays. This study's primary purpose was to analyze the technical feasibility of ceramic composites production utilizing Fundão Dam's Iron Ore Tailings (IOT), Blast Furnace Slag (BFS) from charcoal, and Foundry Sand (FS) as partial substitutes for the traditional raw materials – sand and clay – for application in building industry materials. The composites were molded in rectangular specimens and fired at temperatures of 900, 950, 1000, 1050, and 1200 °C. The developed materials were analyzed and characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Thermogravimetry (TGA), and Differential Thermal Analysis (DTA). The obtained materials had flexural strength modulus of up to 12.19 MPa, water absorption ranging from 2 to 22%, linear shrinkage ranging from 0.02 to 6.50%, and apparent density ranging from 2.03 to 1.63 g/cm3. The study of the internal structure formation process revealed the formation of amorphous structures in the composites. The results demonstrated that these waste materials may be jointly used in construction materials, contributing to the reduction of natural resource extraction, besides enabling their correct disposal, minimizing environmental impacts, and improving the life quality of the surrounding communities. 相似文献
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Joseph Turnbull Ryan Szukalo Dmitrij Zagidulin Mark Biesinger David Shoesmith 《工业材料与腐蚀》2021,72(1-2):348-360
The strategy for the permanent disposal of high-level nuclear waste in Canada involves sealing it in a copper-coated steel container and burying it in a deep geologic repository. During the early emplacement period, the container could be exposed to warm humid air, which could result in the condensation of nitric acid, produced by the radiolysis of the humid air, on the copper surface. Previous studies have suggested that both nitrate and oxygen reduction will drive copper corrosion, with the nitrate reduction kinetics being dependent on the concentration of soluble copper(I) produced by the anodic dissolution of copper in the reaction with oxygen. This study focused on determining the kinetics of nitrate and oxygen reduction and elucidating the synergistic relationship between the two processes. This was investigated using corrosion potential and polarization measurements in conjunction with scanning electron microscopy and X-ray photoelectron spectroscopy. Oxygen reduction was shown to be the dominant cathodic reaction with the oxidation of copper(I) to copper(II) by nitrate, promoting the catalytic cycle involving the reaction of copper(II) with copper to reproduce copper(I). 相似文献
6.
采用粉末冶金法将纳米单质铜(Cu0)、硅铁(FeSi)、四氧化三铁硅涂层(Fe3O4@SiO2)混合煅烧并制备出新型磁性硅铁载铜吸附剂MagFeSi-Cu0。实验研究不同烟气温度下MagFeSi-Cu0的汞吸附能力基础上,结合颗粒内扩散模型、准二阶动力学模型、Elovich模型及Bangham模型分析了MagFeSi-Cu0吸附Hg0过程的主要控制步骤。在此基础上,依据密度泛函理论(DFT)研究了不同反应温度下FeSi表面Cu0原子与Hg0原子的汞齐作用机制。研究结果表明,Bangham模型的拟合值与MagFeSi-Cu0汞吸附实验值拟合度最高,MagFeSi-Cu0表面痕量Hg0吸附由汞的外扩散和表面铜汞齐吸附共同控制;通过密度泛函计算,发现Cu0颗粒表面Cu-Hg齐吸附能为-0.534 eV,当烟气温度从80℃上升至200℃时,Hg0原子与单质Cu原子的吸附自由能从-22.47 kJ/mol下降至-13.96 kJ/mol,这些结果为深入了解Hg0在Cu(111)表面的反应机理提供了理论基础。 相似文献
7.
《Ceramics International》2022,48(9):12014-12027
The formed deposits wear out of refractory wall linings in the rotary kiln and may cause production disturbances. This study describes the chemical composition and mineralogical phase components at the deposit/refractory interface in the rotary kiln for fluxed iron ore pellets production. The main phases of refractory bricks are corundum and mullite, while the deposits mainly contain hematite and silicates. The main phases in the deposit/refractory brick contact zone are hematite, anorthite (CaAl2Si2O8), mullite, corundum, and silicates. Moreover, the hematite phases in the deposit/brick interface averagely contain 6.98 wt% Al and 1.38 wt% Ti. The silicates in the contact zone contain higher aluminium content and lower iron content than the silicates in the deposits. Finally, the thermodynamic analysis indicates that the main phases in the deposits can react with the refractory to form Al2Fe2O6, CaAl2Si2O8, feldspar, and liquid phases lead to the degradation of bricks in the kiln during the iron ore pellets production. 相似文献
8.
Chengcong Zhang 《Science & Technology of Welding & Joining》2018,23(5):394-399
The longitudinal residual stresses in the friction stir-welded plates of 5A06 aluminium and pure copper were determined using the contour method. The results revealed the presence of high tensile and compressive residual stresses on the aluminium and copper sides, respectively. The residual stresses were detected on the weld zone as well as the thermo-mechanically affected zone (TMAZ) of the aluminium plate. In contrast, the compressive residual stresses in the copper plate had a much narrower width along the weld line. Peak tensile stresses up to 240?MPa were found in the TMAZ of the aluminium plate. 相似文献
9.
不同给液方式对铜电解过程中有重要的影响,不同的循环方式会影响槽内温度分布、电解液成分及阳极泥沉降等,因此,根据铜电解生产不同情况的需要,分析对比了多种给液方式在贵冶电解车间的应用,总结了这几种给液方式的优缺点和适用条件。 相似文献
10.
采用胶接辅助钎焊方法,以TiH_2粉为活性元素源,环氧树脂为粘性载体,Ag-Cu共晶合金为钎料,Cu箔为应力缓冲层材料,实现了C_f/C复合材料与纯铜的钎焊连接,结果表明,接头界面处产生TiC,TiCu,Ag(s,s),Cu(s,s)等反应产物,其结构可表示为(C_f/C)/TiC+Ag(s,s)+Cu(s,s)+TiCu/Cu。通过钎焊工艺试验得出,在930℃保温25 min钎焊条件下接头的抗剪强度达到最大值30 MPa。 相似文献