有色冶炼二次含砷物料碱法脱砷工艺现状

分析了典型二次含砷物料化学成分特点,概括了当前有色冶炼工业中产生的二次含砷物料碱法脱砷工艺及原理,主要包括湿法脱砷工艺和火法—湿法联合脱砷工艺。其中,碱法脱砷工艺常用NaOH单碱浸出、NaOH-Na_2S混合碱浸出和NaOH+Na_2S混合碱两段浸出三种体系,并采用双氧水、加压、曝气、微波、球磨等氧化手段强化砷的浸出;火法—湿法联合脱砷工艺主要有低温碱性熔炼—水浸、焙烧预氧化—碱性浸出以及低温碱性焙烧—热水浸出工艺,低温碱性焙烧—热水浸出工艺选择性脱砷效果好,物料普适性广。最后,结合现有研究指出了碱法脱砷工艺存在的问题及二次含砷物料无害化、资源化研究方向。     

废弃电子化学品处理处置标准现状及发展方向

重点介绍了废弃电子化学品定义、产生来源、处理处置现状、处理处置标准化现状及标准发展方向。从废弃电子化学品行业实际情况出发,具体分析了行业现状、处理处置水平及标准化工作的开展情况等。通过标准的制定实施,以及其创新驱动作用的发挥,规范了行业处理处置行为,推动行业科技进步,对全面提升废弃电子化学品处理处置技术水平,实现循环经济、绿色产业和资源化利用有着十分重要的作用。     

PLC控制在气力除灰系统的应用

本文根据攀钢发电厂除灰系统的控制性能要求,采用“上位机+PLC”组成的控制系统实现对除灰系统的控制.该控制系统具有抗干扰能力强、可靠性高、操作简便、扩展方便等优点.     

关于污水处理厂自动控制系统设计分析

随着我国市场经济的快速发展，环境问题已成为了一个严重的问题，其中污水处理问题就是人们需要亟待解决的问题。目前，我国已经建立了很多污水处理厂，其中自动控制系统是污水处理的关键技术，实现了污水处理厂的自动化控制，并且对工艺参数、数据进行采集、分析和管理，保证了出水的达标，提高了生产效率，降低了生产成本。本文主要介绍了污水处理厂自动控制系统的特点和功能，并介绍了自动控制系统的总体设计原则以及对各部分设计进行分析等，希望能保证污水处理厂的自动控制系统设计更加合理。     

Assessment of tracing element characteristics of F-type fly and bottom ash mixture

Presently, fly ash–water slurry is transported to ash disposal site at very low solid concentration of approximately 15–20% (by weight), resulting in huge water and energy wastage which leads to several environmental and health problem. The production of a large amount of the toxic metal elements in the ash disposal system of the thermal power plants can pose negative environmental effects on human health and on plants. In the present study, an attempt has been made to investigate the leaching characteristics of fly ash at higher concentrations. The bottom ash was taken as an additive in the proportion of 10, 20, and 30% (by weight) to enhance the leaching characteristics of fly ash. The solid concentration of fly ash suspension was taken in the range of 40 to 60% (by weight). The addition of additive helps to reduce the tracing metal concentration of fly ash. Leaching experiment data show that leachate concentration of all tracing elements present in fly ash reduced maximum with 20% addition of bottom ash (by weight). The present study helps to improve the ash disposal system of the thermal power plant and to minimize the environmental impact.     

某烧绿石尾矿选铌试验研究

国外某地含有丰富的烧绿石资源，属碱性碳酸盐矿体，原矿Nb2O5含量大于1%，在经历长流程胺法烧绿石浮选之后，尾矿含Nb2O5较高，铌资源未能得到综合回收，该烧绿石尾矿仍具有较高的回收价值。由于该尾矿长期在尾矿库堆存，药剂污染严重、含泥量较大，本工艺预先采用“磨矿擦洗-脱泥”的工艺改善其浮选性质，然后通过“磁选-脱钙”的工艺进行杂质矿物抛废，最终采用螯合类组合捕收剂实现烧绿石的选择性高效捕收。在原料Nb2O5品位0.71%的条件下，获得了Nb2O5品位55.07%、回收率38.23%的烧绿石精矿，尾矿中烧绿石资源得到回收。     

The kinetics of copper corrosion in nitric acid

The strategy for the permanent disposal of high-level nuclear waste in Canada involves sealing it in a copper-coated steel container and burying it in a deep geologic repository. During the early emplacement period, the container could be exposed to warm humid air, which could result in the condensation of nitric acid, produced by the radiolysis of the humid air, on the copper surface. Previous studies have suggested that both nitrate and oxygen reduction will drive copper corrosion, with the nitrate reduction kinetics being dependent on the concentration of soluble copper(I) produced by the anodic dissolution of copper in the reaction with oxygen. This study focused on determining the kinetics of nitrate and oxygen reduction and elucidating the synergistic relationship between the two processes. This was investigated using corrosion potential and polarization measurements in conjunction with scanning electron microscopy and X-ray photoelectron spectroscopy. Oxygen reduction was shown to be the dominant cathodic reaction with the oxidation of copper(I) to copper(II) by nitrate, promoting the catalytic cycle involving the reaction of copper(II) with copper to reproduce copper(I).     

U.S. regulatory perspectives on the back end of the fuel cycle: EUROSAFE 2013 proceeding

For the United States Nuclear Regulatory Commission and the reactor licensees it regulates, there are a number of contemporary issues associated with the back end of the fuel cycle including, the agency's revision to its “Waste Confidence” decision and the path-forward for high-level waste disposal. Additionally, the 2012 Blue Ribbon Commission on America's Nuclear Future recommendations, the future of reprocessing, consolidated interim spent fuel storage, and maintaining technical competence within the NRC in challenging budgetary conditions are addressed. I conclude that there is confidence in the feasibility of safe storage of spent nuclear fuel following the licensed operational life of a reactor and any change in high-level waste policy will require Congressional action to amend the Nuclear Waste Policy Act.     

水泥窑协同处置固废中硒元素的测定方法探讨

本文使用原子荧光光谱仪对水泥窑协同处置固废中的硒元素进行了测定方法开发工作。方法中采用了倒王水沸水浴对固体废弃物进行消解溶样,以10%盐酸作为载流液,0.4%氢氧化钾和1.2%硼氢化钾作为还原剂,铁氰化钾作为掩蔽剂,以消除各种离子的干扰。优化了原子荧光光谱仪的测定条件,对标准样品和固废样品进行了检测。方法检出限为0.04μg/L,相对标准偏差为3.0%~10.1%。固废和污泥中加标回收率为82.8%~102.5%。