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1.
《International Journal of Hydrogen Energy》2022,47(70):30262-30276
Pt–MoO3 was synthesized by microwave-assisted chemical reduction. The physicochemical characterization showed that the electrocatalyst contained nanoparticles of Pt and clusters of MoO3. The average particle size of the catalytic material was 2.5 nm. The electrochemical results showed that the Pt–MoO3/C was suitable to carry out the electrooxidation reactions of ethanol and methanol indistinctly, avoiding CO poisoning. It was possible to compare the results with commercial Pt/C. The synthesized material showed a better electrochemical performance. Different simulations were performed using the Nernst equation to evaluate the influence of temperature, internal resistance, and the current density losses as a function of the fuel used. The theoretical results indicated that the electrical power of the mono-cell improves by 21.5% when the energy vector is changed from methanol to ethanol at the maximum power point, obtaining an electrical potential change ΔE = 87.02 mV and a variation of the electric power of Δp = 114.14 mW cm?2. The use of dual fuels could improve the performance of experimental fuel cells. 相似文献
2.
Liu Yang Pengfei Yu Wenyuan Li Fengliang Cao Xin Jin Sheng Xue Xianglong Zhang Tingwei Zhang Mingbo Wu Wenting Wu 《American Institute of Chemical Engineers》2022,68(9):e17760
Hydrogen peroxide (H2O2) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H2O2 is hard to timely decomposed into O2 and H2O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H2O2 decomposition, and Co core further enhance this decomposition. Benefiting from it, the H2O2 decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O2 generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H2O2 with little deep oxidation and protect the process of H2O2 utilization to achieve a safer world. 相似文献
3.
Guishang Pei Junyi Xiang Qingyun Huang Xuewei Lv 《Journal of the American Ceramic Society》2022,105(10):6359-6369
A double pyrovanadate CaMgV2O7 sample was synthesized via a facile solid-state route under an air atmosphere. The nonequilibrium formation pathways of the CaMgV2O7 were investigated via powder X-ray diffraction. A multistep reactions path (metavanadates–pyrovanadates–double pyrovanadate CaMgV2O7) was proposed to describe the formation of the CaMgV2O7 considering the thermodynamic and kinetic factors. The cell unit parameters of the CaMgV2O7 sample indicated the crystallization according to a monoclinic system with space group P12/c1(14), and the lattice parameters of a = 6.756 Å, b = 14.495 Å, c = 11.253 Å, β = 99.12, and V = 108.806 Å3. X-ray photoelectron spectroscopy also confirmed the +5 oxidation state vanadium in CaMgV2O7. The endothermic effects at 1033 and 1143 K were related to the incongruent melting and liquidus temperatures of CaMgV2O7, respectively. The comprehensive thermodynamic properties of CaMgV2O7 were established in both low- and high-temperature regions, utilizing a physical property measurement system and multi-high-temperature calorimetry (96 lines). The heat capacity (200 J mol K−1) and entropy (198 J mol K−1) at 298.15 K were computed based on the low-temperature heat capacity values, and the enthalpy of formation at 298.15 K was also estimated. The fitted high-temperature capacity can be used to obtain the changes in the enthalpy, entropy, and Gibbs free energy. This study is part of building a reliable thermodynamic database of the CaO–MgO–V2O5 system. 相似文献
4.
This work describes facile synthesis of a porous polymeric material ( T-HCP ) using readily available reagents. Specifically, T-HCP is a thermally stable and hypercrosslinked polymer (HCP) that is essentially microporous with a high BET specific surface area (940 m2 g?1). Triptycene based polymers are known to feature internal free volume. Thus, the incorporation of triptycene units and extensive crosslinking by an external cross-linker in T-HCP makes it a promising adsorbent for small gas capture applications. Experimental results show that T-HCP demonstrated good CO2 capture capacity of 132 mg g?1 (273 K, 1 bar). Molecular hydrogen storage capacity of T-HCP is estimated to be 17.7 mg g?1 (77 K, 1 bar). T-HCP revealed high CO2/N2 selectivity (up to 63) as well as promising CO2/CH4 (up to 9.1) selectivity suggesting its potential applicability for CO2 separation from flue and natural gases. 相似文献
5.
建立高效液相色谱法测定化妆品中依克多因的分析方法,采用Agilent Poroshell 120 EC-C18色谱柱(100 mm×3.0 mm,2.7μm)分离,以甲醇和p H为3.0的40 mmol/L磷酸二氢钠-10 mmol/L 1-庚烷磺酸钠缓冲溶液梯度洗脱,流速0.8 m L/min,柱温30℃,检测波长210 nm。采用外标法定量测定化妆品中的依克多因含量。结果表明,依克多因在5~800 mg/L的质量浓度范围内呈现良好线性关系,相关系数为0.999 8,方法的检出限和定量限分别为0.3和1.0 mg/L。该方法具有分离效率高、分析时间短、节省溶剂等优点,解决了依克多因在C18色谱柱上保留弱的问题。 相似文献
6.
《Ceramics International》2022,48(11):14987-14992
The ceramic compound CaMoO4 is synthesized via a solid-state reaction technique. Rietveld refinement studies were done on the powder X-ray diffraction data of CaMoO4 and revealed that the compound is crystallized in the tetragonal Scheelite structure with I41/a space group. The differential scanning calorimetry (DSC) studies on CaMoO4 divulged an anomaly around 440 °C. This anomaly is further probed using the temperature-dependent Raman and dielectric spectroscopic measurements and are corroborating with the results obtained from DSC. A detailed investigation on the temperature-dependent Raman spectroscopic data revealed that the A1g mode of CaMoO4 showed a soft phonon behavior up to the phase transition temperature. It is observed that the A1g mode displayed phonon hardening behavior with further increasing the temperature. The anomaly is attributed to an isostructural phase transition (IPT), a rarely observed phenomenon in the compounds with Scheelite structure. The IPT in CaMoO4 is elucidated with a phonon softening mechanism. 相似文献
7.
Gerasimov Sergey I. Ilyushin Mikhail A. Putis Sergey M. Dushenok Sergey A. Shugalei Irina V. Sudarikov Andrey M. 《含能材料》2022,30(4):370-378
In the present work it is found that the pyrotechnic composition VS-2 can be initiated with flash lamps IFC-500 and EVIS. VS-2 pyrotechnic composition contains 90% of mercury(Ⅱ) 5-hydrazinotetrazolate perchlorate and 10% of optically transparent copolymer of 2-methyl-5-vinyltetrazole and methacrylic acid (PVMT). We have found that the flash lamps make it possible to initiate combustion of VS-2 composition with its transition to detonation both in cylindrical charges placed in brass caps of 5 mm diameter and 2 mm high, and film charges with 10 mm×80 mm in size and surface weights of 60 mg·cm-2 and 90 mg·cm-2, showing ignition delay times 10 μs and 3 μs, respectively. We also measured detonation velocities for VS-2 composition film charges, which were 4375-4505 m·s-1 (of the charge being surface mass 60 mg·cm-2) and 4221-4281 m·s-1 (of the charge being surface mass 90 mg·cm-2) and their blasting action on the aluminum plate. The depths of the normal shock wave imprints at the charge-barrier interface were 0.6-0.7 mm (for surface mass of the film charges 60 mg·cm-2) and 1.2-1.3 mm (for surface mass of the film charges 90 mg·cm-2). 相似文献
8.
5G蜂窝网络发展迅猛,其覆盖面积将逐渐增大,因此使用5G蜂窝网络进行定位是有研究潜力的研究方向。本文提出一种新的深度学习技术来实现高效、高精度和低占用的定位,以代替传统指纹定位过程中繁重的指纹库生成以及距离计算。该方法建立了一个特殊的卷积神经网络,并根据5G天线信号的接收信号强度指示、相位和到达角等特征量,选择合适的输入数据格式构造样本组建训练集,对该卷积神经网络进行训练。训练得到的卷积神经网络可以替代指纹定位中的庞大指纹库,非常有利于直接在5G移动设备端实现定位。虽然卷积神经网络在训练过程中需要大量时间,但在训练完毕后直接进行分类定位的速度非常快,可以保障定位实现的实时性。本文所实现的卷积神经网络权重与偏置所占内存不到0.5 MB,且能够在实际应用环境中以95%的定位准确率以及0.1 m的平均定位精度实现高精度定位。 相似文献
9.
《International Journal of Hydrogen Energy》2022,47(26):12903-12913
Oxygen evolution reaction (OER) plays a decisive role in electrolytic water splitting. However, it is still challengeable to develop low-cost and efficient OER electrocatalysts. Herein, we present a combination strategy via heteroatom doping, hetero-interface engineering and introducing conductive skeleton to synthesize a hybrid OER catalyst of CNT-interconnected iron-doped NiP2/Ni2P (Fe-(NiP2/Ni2P)@CNT) heterostructural nanoflowers by a simple hydrothermal reaction and subsequent phosphorization process. The optimized Fe-(NiP2/Ni2P)@CNT catalyst delivers an ultralow Tafel slope of 46.1 mV dec?1 and overpotential of 254 mV to obtain 10 mA cm?2, which are even better than those of commercial OER catalyst RuO2. The excellent OER performance is mainly attributed to its unique nanoarchitecture and the synergistic effects: the nanoflowers constructed by a 2D-like nanosheets guarantee large specific area and abundant active sites; the highly conductive CNT skeleton and the electronic modulation by the heterostructural NiP2/Ni2P interface and the hetero-atom doping can improve the catalytic activity; porous nanostructure benefits electrolyte penetration and gas release; most importantly, the rough surface and rich defects caused by phosphorization process can further enhance the OER performance. This work provides a deep insight to boost catalytic performance by heteroatom doping and interface engineering for water splitting. 相似文献
10.