全文获取类型
收费全文 | 7429篇 |
免费 | 873篇 |
国内免费 | 428篇 |
专业分类
电工技术 | 221篇 |
技术理论 | 2篇 |
综合类 | 674篇 |
化学工业 | 522篇 |
金属工艺 | 35篇 |
机械仪表 | 40篇 |
建筑科学 | 940篇 |
矿业工程 | 211篇 |
能源动力 | 312篇 |
轻工业 | 554篇 |
水利工程 | 4270篇 |
石油天然气 | 302篇 |
武器工业 | 17篇 |
无线电 | 64篇 |
一般工业技术 | 211篇 |
冶金工业 | 82篇 |
原子能技术 | 19篇 |
自动化技术 | 254篇 |
出版年
2024年 | 15篇 |
2023年 | 107篇 |
2022年 | 174篇 |
2021年 | 233篇 |
2020年 | 223篇 |
2019年 | 246篇 |
2018年 | 198篇 |
2017年 | 263篇 |
2016年 | 316篇 |
2015年 | 331篇 |
2014年 | 481篇 |
2013年 | 433篇 |
2012年 | 552篇 |
2011年 | 580篇 |
2010年 | 427篇 |
2009年 | 416篇 |
2008年 | 415篇 |
2007年 | 515篇 |
2006年 | 486篇 |
2005年 | 431篇 |
2004年 | 312篇 |
2003年 | 245篇 |
2002年 | 260篇 |
2001年 | 195篇 |
2000年 | 137篇 |
1999年 | 136篇 |
1998年 | 105篇 |
1997年 | 87篇 |
1996年 | 75篇 |
1995年 | 52篇 |
1994年 | 47篇 |
1993年 | 45篇 |
1992年 | 55篇 |
1991年 | 25篇 |
1990年 | 19篇 |
1989年 | 25篇 |
1988年 | 21篇 |
1987年 | 13篇 |
1986年 | 6篇 |
1985年 | 10篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1980年 | 5篇 |
1979年 | 1篇 |
排序方式: 共有8730条查询结果,搜索用时 15 毫秒
1.
《Journal of the European Ceramic Society》2021,41(15):7886-7892
To elucidate the crystal growth process of hematite in high-temperature lead-free multicomponent alkali borosilicate glass, which is essentially important to control the color of red overglaze enamels, frit and hematite mixture is heat-treated and subjected to microscopic observations. Hematite particles slightly grew due to sintering at low temperature. Once the glass matrix formed near the softening point of frit, hematite dissolved into glass fluid. Hematite crystal growth concomitantly ensued with decrease in the number of hematite particles via Ostwald ripening as the temperature increased. The grown particles exhibited an anisotropic morphology with straight outlines reflecting crystal planes, the morphology of which is completely different from those grown by sintering and particles prior to heating. These results suggest that comprehensive understanding of frit and hematite from the perspectives of glass science and chemistry as well as powder technology are important to truly control the color of red overglaze enamels. 相似文献
2.
寒区河道凌汛灾害河势“弯道效应”的量化评估十分重要。基于分形理论提出河道横断面-纵剖面-平面多维度河势分形维数计算方法及其物理机制,并探讨黄河内蒙古段不同维度河势演变分形特征及其与凌汛灾害的关联关系。结果表明,黄河内蒙古段不同维度河势均具有多尺度自相似分形特征,且具有多年记忆周期的长程相关性;冰坝(严重性冰塞)发生频次与河道主槽弯曲分形维数呈正相关指数型函数关系,与河相系数、深泓点高程和河段平均底坡分形维数负相关,与水深-面积分形维数正相关,总体表明冰坝灾害更易发生于主槽偏移摆动大、蜿蜒曲折、河湾发育程度高的宽浅型弯曲河道,研究成果可为凌汛期冰塞冰坝灾害易发河段诊断及预测提供重要理论依据。 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(12):7836-7845
Catalyst samples for CH4 decomposition were prepared from red mud (RM) by an acid-leaching neutralization precipitation approach. Water-washing the resultant precipitates multiple times, followed by drying at 105 °C and calcination at 500 °C, resulted in a threshold of residual Na2O, equivalent to 96% Na2O removal. Drying the precipitate at a higher temperature of 200 °C, followed by repeated water washing, provided a deeper Na2O removal of 99% and made the resultant samples more active for the targeted reaction. Subsequently, four catalyst samples with a simulated red mud composition and NaOH contents from 0 to 0.3 wt% were prepared and the catalytic test results revealed that the Na2O remaining in the RM-derived catalysts did not only inhibit their activation in CH4 but also lower their maximal activities for CH4 decomposition. Finally, two catalysts with the same simulated red mud composition and their Na impregnated respectively on Fe2O3 and a mixture support of Al2O3-SiO2-TiO2 were prepared and tested to explore the effect of Na distribution on the activation behavior of RM-derived catalysts for CH4 decomposition. The activity testing results showed that it was the Na residual dispersed on iron oxides in the RM-derived samples to significantly inhibit the activation of CH4 decomposition. 相似文献
4.
Qian Wu Xiangmei Liu Bo Li Lei Tan Yong Han Zhaoyang Li Yanqin Liang Zhenduo Cui Shengli Zhu Shuilin Wu Yufeng Zheng 《材料科学技术学报》2021,67(8):70-79
Pathogens pose a serious challenge to environmental sanitation and a threat to public health.The frequent use of chemicals for sterilization in recent years has not only caused secondary damage to the environment but also increased pathogen resistance to drugs,which further threatens public health.To address this issue,the use of non-chemical antibacterial means has become a new trend for environmental disinfection.In this study,we developed red phosphorus nanoparticles(RPNPs),a safe and degradable photosensitive material with good photocatalytic and photothermal properties.The red phosphorus nanoparticles were prepared using a template method and ultrasonication.Under the irradiation of simulated sunlight for 20 min,the RPNPs exhibited an efficiency of 99.98%in killing Staphylococcus aureus due to their excellent photocatalytic and photothermal abilities.Transmission electron microscopy and ultraviolet–visible spectroscopy revealed that the RPNPs exhibited degradability within eight weeks.Both the RPNPs and their degradation products were nontoxic to fibroblast cells.Therefore,such RPNPs are expected to be used as a new type of low-cost,efficient,degradable,biocompatible,and eco-friendly photosensitive material for environmental disinfection. 相似文献
5.
Peixin Gao Peng Dong Zeyun Zhou Qian Li Honghui Li Zhi Zhou Mao Xia Peihua Zhang 《Ceramics International》2021,47(12):16588-16596
Deep-red light emitting phosphors are widely used in LEDs for indoor plant growth because of the critical role played by red light in plant growth. The luminescence properties of deep-red phosphors are still not well understood at present. An energy transfer strategy is a common and effective method to improve luminescence properties. In principle, the energy transfer process may occur when the sensitizer's emission spectra overlap with the activator's excitation spectra. In this work, Bi3+ and Mn4+ were incorporated into the matrix of Gd2MgTiO6 as sensitisers and activators, respectively. Mn4+ ions tend to occupy the [TiO6] octahedral site and the Bi3+ ions are expected to substituted in the site of Gd3+. The energy transfer process from Bi3+ to Mn4+ was realised and the photoluminescence (PL) intensity of Mn4+ increased with the doping content of Bi3+. Upon excitation at 375 nm, the PL intensity of Mn4+ increased to 116.4% when the doping concentration of Bi3+ reached 0.3%. Finally, the pc-LED devices were prepared by a Gd2MgTiO6:Bi3+, Mn4+ phosphor. The high red luminescence indicated that this phosphor has potential applications in indoor LED lighting. 相似文献
6.
《Ceramics International》2022,48(13):18793-18802
The luminescence center energy transfer, crystal field strength, and covalency are limited by the crystal structure of the host and subsequently affect the luminescence efficiency, color, and intensity. Here, we report an excellent red phosphor BaLaLiWO6:0.40Eu3+ and the dependence between symmetry and luminous performance. A model for changing symmetry is drawn by analyzing the Coulomb potential and structure for the application of a double-perovskite phosphor BLLWO: Dy3+, Eu3+ in white light LEDs. The addition of Dy3+/Eu3+ makes the W-O bond formed by the B-site and oxygen ion longer and the Li-O bond shorter, and the difference between the eight octahedral around the A-site is reduced, increasing the symmetry of the A-site. Local symmetry was successfully modulated by changing the Eu3+ concentration to control the Y/B ratio of Dy3+ and the R/O ratio of Eu3+ and smoothly achieved (0.382, 0.373) warm white light color coordinate. The phosphor has excellent thermal stability and still has 92.3% intensity at 475 K. The above results show that the wavelength composition of the luminescence is tunable by changing the symmetry of the environment in which the doped ions are located. It applies to single hosts for the regulation of white light emission. 相似文献
7.
8.
9.
NiMo nanocatalysts supported on activated red mud with different zeolite beta contents were successfully prepared by impregnation technique. Their hydrocracking and hydrodesulfurization activities were evaluated with two different kinds of diesel feed (iso diesel and heavy diesel) in a fixed bed reactor at ambient pressure and 500 °C. Physico-chemical properties of synthesized samples were characterized using the methods of XRF, XRD, FESEM, BET, FTIR and NH3-TPD. The results indicated that zeolite incorporation resulted in a significant increase in specific surface area (BET result) and acidic strength (TPD result) of nanocatalysts. FESEM analysis confirmed that the particles size of zeolite-containing NiMo/ARM was less than 100 nm and the average size of particles was about 30 nm. Hydrocracking results illustrated that incorporation of zeolite beta improved cracking activity considerably. In addition, NiMo nanocatalyst containing 37.5 wt% of zeolite had the highest yields of desirable products (naphtha, kerosene and diesel) and the highest conversion. Moreover, the flash point and viscosity of the liquid product decreased notably the nanocatalysts with 37.5 wt% and 12.5 wt% of zeolite were able to remove approximately 96% and 72% of the sulfur content of iso diesel and heavy diesel, respectively. 相似文献
10.
单传感器捕获的彩色-近红外(RGB-NIR)图像存在光谱干扰,从而导致重建出的标准彩色图像(RGB)图像与近红外(NIR)图像存在色彩失真以及细节信息模糊。针对这个问题提出一种基于深度学习的去马赛克方法,通过引入跳远连接与稠密连接解决了梯度消失和梯度弥散问题,使得网络更容易训练,并且提升了网络的拟合能力。首先,用浅层特征提取层提取了马赛克图像的像素相关性以及通道相关性等低级特征;然后,将得到的浅层特征图输入到连续多个的残差稠密块以提取专门针对去马赛克的高级语义特征;其次,为充分利用低级特征与高级特征,将多个残差稠密块提取到的特征进行组合;最后,通过全局跳远连接恢复最终的RGB-NIR图像。在深度学习框架Tensorflow上使用公共的图像与视觉表示组(IVRG)数据集、有植被的户外多光谱图像(OMSIV)数据集和森林(Forest)三个公开数据集进行实验。实验结果表明,所提方法优于基于多级自适应残差插值、基于卷积卷积和神经神经网络以及基于深度残差U型网络的主流的RGB-NIR图像去马赛克方法。 相似文献