Recent progress of green sorbents-based technologies for low concentration CO2 capture

The increased concentration of CO₂ due to continuous breathing and no discharge of human beings in the manned closed space, like spacecraft and submarines, can be a threat to health and safety. Effective removal of low concentration CO₂ from the manned closed space is essential to meet the requirements of long-term space or deep-sea exploration, which is an international frontier and trend. Ionic liquids (ILs), as a widespread and green solvent, already showed its excellent performance on CO₂ capture and absorption, indicating its potential application in low concentration CO₂ capture. In this review, we first summarized the current methods and strategies for direct capture from low concentration CO₂ in both the atmosphere and manned closed spaces. Then, the multi-scale simulation methods of CO₂ capture by ionic liquids are described in detail, including screening ionic liquids by COSMO-RS methods, capture mechanism by density functional theory and molecular dynamics simulation, and absorption process by computational fluid dynamics simulation. Lastly, some typical IL-based green technologies for low concentration CO₂ capture, such as functionalized ILs, co-solvent systems with ILs, and supported materials based on ILs, are introduced, and analyzed the subtle possibility in manned closed spaces. Finally, we look forward to the technology and development of low concentration CO₂ capture, which can meet the needs of human survival in closed space and proposed that supported materials with ionic liquids have great advantages and infinite possibilities in the vital area.     

Photocatalytic evolution of hydrogen over mesoporous TiO2 supported NiO photocatalyst prepared by single-step sol–gel process with surfactant template

Photocatalytic activity of mesoporous titania supported nickel oxide photocatalyst synthesized by single-step sol–gel (SSSG) process combined with surfactant-assisted template method was investigated for hydrogen evolution from an aqueous methanol solution, in comparison with one prepared by conventional incipient wetness impregnation (IWI) method. In single-step sol–gel process, nickel precursor was introduced into the titania sol prepared with the aid of a surfactant template behaving as pore-controlling agent to attain meso-scaled pore. The single-step sol–gel photocatalyst was experimentally found to enhance the photocatalytic evolution of hydrogen rather than the impregnated one. The optimum level of nickel loading in photocatalytic activity test for single-step sol–gel method was slightly higher than that for incipient wetness impregnation method. Characterization results demonstrated the significant modification of physical characteristics of the single-step sol–gel photocatalyst, anticipated to relating to the observation of higher photocatalytic hydrogen evolution activity.     

Detection of acylated homoserine lactones in gram-negative proteolytic psychrotrophic bacteria isolated from cooled raw milk

Through a mechanism called quorum sensing, bacteria are able to express specific genes in response to population density. Cell-to-cell communication in bacteria is mediated by signal molecules such as acylated homoserine lactones (AHLs). This work aimed to detect AHL production in Gram-negative psychrotrophic bacteria isolated from raw milk. A total of 84.9% of the bacteria were identified as AHL producers eliciting a diversity of responses in the AHL-monitor systems. These results demonstrate that AHL-production is common among psychrotrophic bacteria isolated from milk, and indicate that quorum sensing may play an important role in the spoilage of this product.     

软件项目质量控制流程及其技术

软件项目质量管理是贯穿整个软件生命周期的重要工作,有效地实施质量控制是提高软件质量、降低成本的重要手段。针对质量控制的难点,对质量控制流程与技术进行研究。首先,说明质量控制过程,包括事前质量控制、事中质量控制和事后质量控制;然后,通过图形研究质量控制流程;最后,通过图形并结合文字说明研究质量控制技术,包括因果图、Pareto图、控制图、运行图、统计抽样等5种常用技术。结果表明,通过对质量控制流程与技术的研究,为质量控制提供技术和方法支持,提高质量管理的科学性。     

酸碱中和反应中pH值的单神经元自适应控制研究

基于酸碱中和反应过程中pH值变化的动态模型,设计单神经元自适应控制器,解决化工生产过程中pH值的PID控制所存在的调节时间长、超调量大和系统抗干扰性差的问题。在相同条件下与PID控制器进行对比实验,实验结果表明单神经元自适应控制器明显改善pH值过程控制系统的动态性能,该控制系统具有较强的自适应性与鲁棒性。     

基于模糊AHP的大学课堂教学质量评价研究

为了对大学教师课堂教学质量进行有效的监督和管理,建立了现代信息技术环境下大学教师课堂教学质量评价指标体系,基于模糊综合评判法和层次分析法(AHP)建立了教师课堂教学质量评价模型,应用此模型实例分析某教师的课堂教学质量并提出相应的提升策略,提高了评价的科学性和实用性。     

磁性金属有机框架材料制备及吸附性能研究

利用简单的溶剂热法合成了MIL-101（Fe）/CoFe₂O₄和MIL-101（Fe）/NiFe₂O₄磁性金属有机框架纳米复合材料。通过X射线衍射仪（XRD）、扫描电子显微镜（SEM）、振动磁强计（VSM）、热重分析仪（TGA）和紫外可见分光光度计（UV）等对复合材料的相结构、形貌、磁性能和吸附性能进行了研究。将磁性金属有机框架材料用于吸附污水中罗丹明B（RhB）,研究了罗丹明B初始质量浓度对复合材料吸附能力的影响。结果表明,制备的磁性金属有机框架复合材料的形貌均匀、结晶度高,具有高的饱和磁化强度。复合物具有金属有机框架材料和磁性材料的双重优点。MIL-101（Fe）/CoFe₂O₄对罗丹明B有较高的吸附能力（97.3 mg/g）。热力学研究发现吸附等温方程符合Langmuir模型,吸附动力学研究表明吸附机制与吸附质和吸附剂有关。磁性金属有机框架纳米复合材料作为污水处理剂将具有广阔的应用前景。     

Deterministic transmission of an arbitrary single-photon polarization state through bit-flip error channel

We present two error-tolerance transmission protocols of a single-photon polarization state when bit-flip error is taken into account. For achieving the transmission target of the single-photon state, the first protocol needs to encode it to a nonmaximally entangled Bell state. Exploiting the interaction of the polarization entanglement with spatial entanglement between two photons, its success probability is 100 %. Different from the first protocol, the second one utilizes the idea of teleportation with an auxiliary Bell state. By performing quantum nondemolition measurement to analyze the parity, conventional measurement, and unitary transformation operations, the success probability of the second protocol is approximately unity. Furthermore, the second protocol can be generalized to the error-tolerance transmission of an arbitrary mixed state or the distribution of an arbitrary multi-photon entangled state.     

一种基于尾匹配q-gram的近似串匹配算法

近似串匹配是生物信息学、文本检索、信号处理等领域的一个基础问题,如何提高近似串匹配的速度一直都是研究的关键问题。提出一种新的在大文本库中快速查找近似匹配的无损过滤算法。为保证在大文本库中的匹配速度,本算法使用了查询速度较快的q-gram索引。为通过提高过滤算法的过滤效率达到提升算法整体性能的目的,详细分析了含有匹配串的文本区域,提取了一些基于尾匹配q-gram特征的新过滤条件,然后用这些特征优化了过滤算法的过滤标准。实验数据表明,新过滤条件有效地提高了算法的过滤效率,提升了算法的整体性能。结果显示新算法适合各种匹配错误率下的近似匹配,算法的通用性较强。     

1D helical ZnII metal–organic polymers: Syntheses,structures and fluorescent properties

Hydrothermal reactions of 1,1′-(1,5-pentanediyl)bis-1H-benzimidazole (pbbm) with ZnCl₂ afford two 1D helical metal–organic polymers {[ZnCl₂(pbbm)] · (H₂O)_1/8}_n (1) and {[Zn(pbbm)₂] · Cl₂ · (H₂O)_1/2}_n (2). Polymer 1 features a 1D single helical architecture, whereas 2 possesses a 1D cationic double helical chain framework. Photoluminescence investigations reveal that both of them display strong emissions in the solid state at room temperature, which could originate from a ligand-to-ligand charge-transfer (LLCT) transition, as confirmed by the molecular orbital (MO) calculations.