天然橡胶/顺丁橡胶/丁苯橡胶自润滑喷蜡橡胶材料的性能

在天然橡胶(NR)/顺丁橡胶(BR)/丁苯橡胶(SBR)为基体的自润滑喷蜡橡胶材料中加入芥酸酰胺,考察芥酸酰胺作为润滑剂时对NR/BR/SBR自润滑喷蜡橡胶材料的硫化特性、力学性能、门尼黏度、摩擦系数及耐老化性能的影响。结果表明,与未加芥酸酰胺的胶料相比,当芥酸酰胺用量为10份时,胶料转矩减小,焦烧时间和正硫化时间缩短,扯断伸长率从388%增加至523%,拉伸强度降低了21.36%,邵尔A硬度、压缩永久变形分别下降5.56%和8.74%,动、静摩擦系数分别减小23.46%和24.82%,门尼黏度降低20.89%,耐热氧老化性能下降。硫化胶拉伸100%停放5 min后,表面出现明显的白色润滑膜,胶料流动性变好,各组分分散得更均匀,断面更光滑。     

The crosslinking directing dynamic behavior of polymer latex under the investigation toward waterborne damping coatings

Latex polymers with precisely designed dynamic mechanical behavior are the key for waterborne damping coatings, which are widely desired in noise and vibration reduction with additional environmental benefits. In this work, we synthesized series of polymer latexes with various crosslinking agents (CA) and network distributions through the control on emulsion polymerization processes. We have revealed that the variation on crosslinking can significantly direct the latex behavior under dynamic conditions as well as its films. The variables involve the CA composition, the functionality, the crosslinking manner, the hydrophilic-hydrophobic feature as well as the feeding method. Although all the latex films showed the damping peaks locating in the range from −10 to 70°C, their damping behaviors were quite different. Suggested by the empirical parameters of LA and TA, the product from sequential monomer feeding method tended to give good extensional damping performance. Especially when the crosslinking of diacetone acrylamide (DAAM)/adipic dihydrazide was applied, there was a linear increase on LA with the increasing dosage of DAAM from 0 to 10 mmol in the final monomer addition batch. Meanwhile, good constrained layer damping is expected on the products from the power monomer feeding method with the maximum CA dosage shown below 7.5 mmol. The best TA was achieved when the CA of divinylbenzene was used in the dosage of 5 mmol. These results would be valuable to be referenced in the engineering on organic damping materials toward modern industrial and vehicles applications.     

可再分散乳胶粉的制备研究

本文介绍了建筑材料用可分散乳胶粉的制备方法,测试了乳液的不同性能。用激光粒度测试仪测定其粒度分布情况,并表征了乳胶粒子的形态,详细分析了乳胶粒子的形成机理。     

聚合物水泥防水涂料的研制及其成膜机理

以甲基丙烯酸甲酯(MMA)、苯乙烯(St)、丙烯酸丁酯(BA)为原料,以非离子乳化剂和阴离子乳化剂的混合乳化剂为乳化体系,过硫酸铵为引发剂,引入甲基丙烯酸(MAA)功能性单体,通过采用种子乳液聚合工艺,控制聚合物乳液的玻璃化温度,制备出性能优良的丙烯酸酯乳液,确定适合聚合物水泥防水涂料的聚合物乳液的较佳配方。研究了液粉比对聚合物水泥防水涂料拉伸性能和低温柔性的影响。同时还探讨了聚合物水泥防水涂料的成膜机理。     

耐擦洗环保乳胶漆的研究

合成叔碳酸乙烯酯(VeoVa)-醋酸乙烯(VAc)共聚乳液,着重研究VeoVa用量、聚合温度和时间、乳化剂用量、保护胶用量对乳液性能的影响。研究结果表明,在聚合温度75～80℃、反应时间2～3小时条件下,在VeoVa含量为20%左右,在乳化剂含量为3%,保护胶含量为0.2%时,乳液具有稳定性好、耐水性高的优点。以叔醋共聚乳液为基料配制的内墙乳胶漆具有低VOC、环保、耐擦洗的特点。     

丙烯酸系互穿网络聚合物乳胶涂料的研究

在相同的P.V.C条件下,将IPN型乳胶漆与共聚型、共混型、核壳型乳胶漆的性能进行对比,表明IPN乳胶漆的性能优于后三者,是一种耐老化性能好、抗污能力强的外墙装饰材料。     

LB—7氯丁胶乳水泥砂浆防水剂

介绍了LB－7氯丁胶乳水泥砂浆的组成、配方、性能，探讨了影响性能的因素及机理。     

丝光、半光和有光建筑乳胶漆的耐水性和耐碱性

根据光泽对乳胶漆进行分类的基础上,分析了丝光、半光和有光乳胶漆耐水性和耐碱性问题的原因,并提 出改进措施和延长试板养护期的建议。     

聚丙烯纤维和丁苯乳液对水泥砂浆性能的影响

研究了掺量为0~0.3%(体积分数)的聚丙烯纤维,掺量为0~12%(质量分数)的丁苯乳液在单掺、复掺情况下对水泥砂浆3,28,90 d抗压、抗折强度,以及28 d龄期时磨损、冲击性能等的影响.研究结果表明,纤维的掺入大幅度提高了丁苯乳液砂浆的抗冲击和抗磨损性能,提高丁苯乳液砂浆抗磨损性能的最佳纤维掺量为0.1%;纤维掺量越大,对提高丁苯乳液砂浆的抗冲击性能越有利.丁苯乳液的掺入改善了聚丙烯纤维与基体之间的界面粘结,增强了掺纤维砂浆的长期力学性能.丁苯乳液、聚丙烯纤维的复掺效果优于这两者单掺的情况,复掺对水泥砂浆起到了双重改性的效果.