全文获取类型
收费全文 | 681篇 |
免费 | 21篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 5篇 |
综合类 | 15篇 |
化学工业 | 455篇 |
金属工艺 | 21篇 |
机械仪表 | 20篇 |
建筑科学 | 6篇 |
矿业工程 | 2篇 |
能源动力 | 17篇 |
轻工业 | 14篇 |
石油天然气 | 68篇 |
武器工业 | 1篇 |
无线电 | 8篇 |
一般工业技术 | 70篇 |
冶金工业 | 3篇 |
出版年
2024年 | 5篇 |
2023年 | 9篇 |
2022年 | 8篇 |
2021年 | 14篇 |
2020年 | 14篇 |
2019年 | 16篇 |
2018年 | 12篇 |
2017年 | 23篇 |
2016年 | 15篇 |
2015年 | 18篇 |
2014年 | 25篇 |
2013年 | 47篇 |
2012年 | 52篇 |
2011年 | 46篇 |
2010年 | 33篇 |
2009年 | 37篇 |
2008年 | 35篇 |
2007年 | 30篇 |
2006年 | 26篇 |
2005年 | 35篇 |
2004年 | 28篇 |
2003年 | 46篇 |
2002年 | 29篇 |
2001年 | 21篇 |
2000年 | 18篇 |
1999年 | 18篇 |
1998年 | 18篇 |
1997年 | 11篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
排序方式: 共有705条查询结果,搜索用时 0 毫秒
1.
2.
3.
无CFC硬泡用低粘度聚醚多元醇 总被引:4,自引:0,他引:4
介绍了一种具有自乳化性、高羟值低粘度聚醚多元醇。以该聚醚多元醇为基础,制备了无CFC或CFC减半PU硬泡,包括HCFC-141b减关体系、正(异)戊烷发泡体系、全水发泡及CFC-11减半体系。实验结果表明,该聚醚与HCFC-141b、戊烷及水等相溶性好,组合料贮存稳定,硬泡物性优良,说明该聚醚可广泛应用于各种无CFC PU硬泡体系。 相似文献
4.
Natural Palm Olein Polyol as a Replacement for Polyether Polyols in Viscoelastic Polyurethane Foam
下载免费PDF全文

H. Nurul ‘Ain T. I. Tuan Noor Maznee M. N. Norhayati M. A. Mohd Noor S. Adnan P. P. Kosheela Devi S. Mohd Norhisham S. K. Yeong A. H. Hazimah Irma Campara Vahid Sendijarevic Ibrahim Sendijarevic 《Journal of the American Oil Chemists' Society》2016,93(7):983-993
The impact of replacing three polyether polyols with different levels of a single palm olein‐based natural oil polyol (NOP) was systematically correlated with the changes in foaming reactivity, cell structure, physico‐mechanical properties, and morphology of viscoelastic (VE) foams. The data show that replacing the polyether polyols with the NOP slightly increased the rate of the foaming reactivity. Increasing the NOP content resulted in increased cell size and cells remained fully open. Increased NOP content contributed to higher load bearing properties of VE foam, which can be attributed to higher functionality of NOP compared to polyether polyols. Addition of the NOP slightly increased the resilience of the foams, however, the hysteresis which is the measure of energy absorption remained mostly unaffected. Age properties, characterized by dry and humid compression sets, were mostly unaffected by the replacement of the polyether polyol with the NOP. The addition of NOP did not impact the morphology of the VE foam polymer matrix, which appears to retain a low degree of hard and soft segment domain separation. Overall, the results demonstrate a feasibility that the NOP can be used to partially replace the polyether polyols in VE polyurethane foams without significant impact on the functional performance. 相似文献
5.
Both HCFC‐ and pentane‐blown rigid polyurethane foams have been prepared from polyols derived from soybean oil. The effect of formulation variables on foam properties was studied by altering the types and amounts of catalyst, surfactant, water, crosslinker, blowing agent, and isocyanate, respectively. While compressive strength of the soy foams is optimal at 2 pph of surfactant B‐8404, it increases with increasing the amount of water, glycerin, and isocyanate. It also increases linearly with foam density. These foams were found to have comparable mechanical and thermoinsulating properties to foams of petrochemical origin. A comparison in the thermal and thermo‐oxidative behaviors of soy‐ and PPO‐based foams revealed that the former is more stable toward both thermal degradation and thermal oxidation. The lack of ether linkages in the soy‐based rather than in PPO‐based polyols is thought to be the origin of improved thermal and thermo‐oxidative stabilities of soy‐based foams. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 467–473, 2000 相似文献
6.
Glycolysis reaction kinetics of methylene diphenyl diisocyanate‐based water‐blown polyurethane foams was examined by gel permeation chromatography. Glycolysates were reacted with butyl glycidyl ether to convert toxic aromatic amines to polyols, and their products were identified by 1H‐NMR spectroscopy. To examine the quality of recycled polyol, polyurethane foams were reprepared using the virgin and recycled polyol mixtures with varying compositions. Cell structures and sizes of reprepared foams were similar to those of original ones when the recycled polyols were mixed up to 30 wt %. Density, thermal conductivity, and flexural strength of the reprepared foams were compared with those of the original ones, and no difference was observed below the recycled polyol concentration of 30 wt %. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 2646–2656, 2000 相似文献
7.
芳烃聚酯多元醇的合成及应用研究 总被引:2,自引:0,他引:2
介绍了以聚对苯对二甲酸乙二醇酯残渣和二乙二醇为主要原料制备低成本芳烃聚酯多元醇的工艺路线,讨论了温度,DEG和PET残渣的摩尔比对芳烃聚酯多元醇性能的性能。试验表明,最佳反应温度为190℃-220℃,最佳摩尔比为1.22-1.34。研究了稳定剂对聚酯多元醇组合料贮存稳定性的影响,组合料贮存期在半年以上。聚酯型聚所酯硬泡的氧指数达27.5%。 相似文献
8.
以二元醇分步加料法合成了聚酯二醇。研究结果表明,该法与一步法相比具有某些优点,例如:实际分子量与理论计算值相近,合成过程中副产物及二元醇损失为较少。研究还表明,保持最后一次加二元醇时反应体系nOH/nCOOH=2是必要的。 相似文献
9.
通过大量实验寻找出简易、有效制备PIPA多元醇的工艺,并通过红外测试证实了产物的合理性。还探讨了温度、固含量、异氰酸酯指数、水的量等因素对反应体系的影响,并指出了合成过程中,以上因素的合理用量。如果在制备PIPA多元醇时加入少许稳定剂,则可以很好地提高PIPA多元醇的稳定性。 相似文献
10.