Novel energy-saving window coating based on F doped TiO2 nanocrystals with enhanced NIR shielding performance

To reduce the energy consumption of cooling in the hot summer days, searching for novel NIR shielding materials for buildings is of great value. In this report, monodispersed F doped TiO₂ nanocrystals with an average size of 8.6 nm were synthesized as novel solar shielding materials for energy-saving windows. All the products adopted an anatase TiO₂ structure. After doping of F ions, the morphology of TiO₂ was transformed from an irregular shape to a pseudospherical shape. The Raman shift and XPS depth analysis confirmed the successful doping of F⁻ ions into the lattice oxygen sites in the TiO₂ structure. The introduction of F⁻ ions generated free electrons and bulk Ti³⁺ in TiO₂ crystals, which activated a localized surface plasmon resonance (LSPR) absorption in the NIR region. Correspondingly, the NIR shielding performance of the TiO₂ films improved with increasing F doping amounts. The NIR shielding value of the films increased from 1.3% to 43.2% when the molar ratio of F to Ti increased from 0 to 0.3. The reason can be attributed to the enhanced NIR absorption induced by the increased electron concentration after doping of fluorine ions. The F–TiO₂ films showed superior visible transmittance (90.1–96.7%). Moreover, the F–TiO₂ films lowered the indoor temperature of the heat box by 5.3 °C in the thermal tests. Overall, the prepared F–TiO₂ nanocrystals show a great potential to be used for energy-saving windows.     

Analysis of pressure and heat distribution in a dilating or contracting filter chamber with two outlets using multivariate spectral quasilinearization method

The development of efficient filters is an essential part of industrial machinery design, specifically to increase the lifespan of a machine. In the filter chamber design considered in this study, the magnetic material is placed along the horizontal surface of the filter chamber. The inside of the filter chamber is layered with a porous material to restrict the outflow of unwanted particles. This study aims to investigate the flow, pressure, and heat distribution in a dilating or contracting filter chamber with two outlets driven by injection through a permeable surface. The proposed model of the fluid dynamics within the filter chamber follows the conservation equations in the form of partial differential equations. The model equations are further reduced to a steady case through Lie's symmetry group of transformation. They are then solved using a multivariate spectral-based quasilinearization method on the Chebyshev–Gauss–Lobatto nodes. Insights and analyses of the thermophysical parameters that drive optimal outflow during the filtration process are provided through the graphs of the numerical solutions of the differential equations. We find, among other results, that expansion of the filter chamber leads to an overall decrease in internal pressure and an increase in heat distribution inside the filter chamber. The results also show that shrinking the filter chamber increases the internal momentum inside the filter, which leads to more outflow of filtrates.     

基于CFD⁃DEM的水下切粒装置水室内颗粒流动过程数值模拟

基于CFD?DEM耦合方法，研究了颗粒在水室内的流动状态，分析了不同刀盘转速、粒子水通入量和水室出口角度对造粒过程的影响，发现提高刀盘转速、增加粒子水通入量和水室出口倾斜一定的角度都有利于水室内颗粒的排出。进一步研究了颗粒与碎屑在水室内的流动，发现在水室出口处二者的流动基本呈现出一定的分离角度。     

The operation types and operation window for high-purity hydrogen production for the sorption enhanced steam methane reforming in a fixed-bed reactor

The operation types and operation window for high-purity H₂ production for the sorption enhanced steam methane reforming (SE-SMR) with Ni/Al₂O₃ catalyst and CaO sorbent in a fixed-bed reactor are investigated by an experimentally verified 2D numerical method. Four chemical reactions including steam reforming, water gas shift, global steam reforming, and CO₂ sorption are considered. The operation window is defined as the H₂ and CO molar fractions at outlet satisfying both y_H2,out ≥ 90% and y_CO,out ≤ y_CO,allow (= 1%, 2% or 3%) in dry base. Under the conditions of y_H2,out and y_CO,allow, there are six operation types, of which 2 types are within the operation window and 4 types are not within the operation window as the temperature, weight hourly space velocity (WHSV) and steam to methane (S/C) molar ratio vary. For a common case of S/C = 3, the operation windows for y_CO,allow = 3% at WHSV = 8.5 h^?1 and 42.5 h^?1 are located at 570–670 °C and 640–690 °C respectively, based on the parameters in this work. The operation window of temperature is wider with decreasing WHSV, and it becomes wider remarkably as the S/C ratio increases. The lowest temperature inside the operation window is 550 °C. The effects of the temperature, WHSV and S/C ratio on the operating types, y_H2,out and y_CO,out are also presented and discussed in details.     

Greatly improved NIR shielding performance of CuS nanocrystals by gallium doping for energy efficient window

In this work, gallium doped copper sulfide (Ga-doped CuS) nanocrystals were prepared using a solvothermal method. The effects of Ga doping on the crystal structures, chemical composition, morphology, optical properties and thermal performance of copper sulfide (CuS) were investigated. The Ga-doped CuS nanocrystals had a hexagonal structure comparable to that of pure CuS. The Cu⁺/Cu²⁺ ratio first decreased and then increased with increasing Ga³⁺ doping. Both CuS and Ga-doped CuS exhibited nanoplate and nanorod morphologies. The visible transmittance of the Ga-doped CuS films was in the range of 61–77.1%. Importantly, the near-infrared (NIR) shielding performance of the films can be tuned by adjusting the concentration of the Ga dopant. The NIR shielding value of the optimal Ga-doped CuS film was 72.4%, which was approximately 1.5 times as high as that of the pure CuS film. This can be ascribed to the enhanced plasmonic NIR absorption that resulted from an increase in the hole concentration after doping with Ga³⁺ ions. In the thermal performance test, the Ga-doped CuS film lowered the interior temperature of the heat box by 9.1 °C. Therefore, the integration of good visible transmittance and high NIR shielding performance make the Ga-doped CuS nanocrystals a promising candidate for energy-efficient window coatings.     

Performance of surface ionic conduction single chamber fuel cell prepared by the sol gel method

The performance of surface ionic conduction single chamber fuel cell (SIC‐SCFC) prepared by the sol gel method was studied on electric characteristics due to the differences of the operating temperature and humidity, the electrode distance and electrolyte film depth, and multiple cells with the series and parallel connections. The SIC–SCFC was arranged the both anode of Pt and cathode of Au on the boehmite electrolyte. The open circuit voltage (OCV) of single cell achieved a maximum of 530mV in the dry gas mixtures of O₂/H₂=50% in room temperature operation, and but it became decrease as over 60%. The OCV was maintained the constant value between operating temperatures of 30°C to 80°C, and but it was decreased sharply at over 90°C because a humidity on the cell became lower as increasing operating temperature. Then, the cell property was improved to 120°C by adding to the humidity of 70% using a humidifier. The electrode distance and the electrolyte film depth of SIC‐SCFC found to be contributed to the reductions of the cell resistance and the surface roughness on the electrode, respectively. Moreover, the power property of SIC‐SCFC was significantly improved by cell stacks comprised of the series or parallel connection of a cell.     

基于多基表示的滑动窗口椭圆曲线多标量乘算法

标量乘运算从整体上决定了椭圆曲线密码体制的快速实现效率，在一些椭圆曲线公钥密码体制中需要计算多标量乘。多基数链的标量表示长度更短、非零比特数目更少，较好地适用于椭圆曲线标量乘的快速计算。为了提高椭圆曲线密码的效率，在已有的二进制域和素域的标量乘算法的基础上，结合滑动窗口技术、多基算法，提出新的更高效的多标量乘算法。实验结果表明，新算法与传统Shamir算法和交错NAF算法相比，其所需的运算量更少，能有效地提高椭圆曲线多标量乘算法的效率，使多标量乘的运算更高效。相比于其他算法，新算法的计算效率比已有的多标量乘算法提高了约7.9%~20.6%。     

煤矿井下避难硐室系统的构建与应用分析

为进一步减少煤矿事故发生后的人员伤亡、财产损失，在分析国内外煤矿井下避难系统发展的基础上，以何家塔煤矿井下避难硐室系统的构建设计与应用为例，详细介绍了井下避难硐室系统的分类、结构构成、功能需求和配套设施等，并通过紧急避险疏散时间的校验计算，提出避难硐室距离采掘工作面以不超过1 000 m为宜，且应按照“地面最安全，先逃生后避险”原则进行避险救援，为国内其他矿井避难硐室的构建应用和相关标准的制定提供了参考。