Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

臭氧氧化技术在有色金属湿法冶金中的应用研究进展

臭氧是一种氧化性极强、多功能化的绿色氧化剂。本文综述了臭氧氧化技术在有色金属湿法冶金领域的研究进展和应用现状,重点介绍了在贵金属、重金属、稀有金属及轻金属等有色金属湿法冶金领域的应用研究。详细探讨了臭氧的强氧化性对低品位金属矿和难冶金属矿浸出、溶液中低价态金属离子氧化沉淀、溶液净化除杂等方面的作用机理,并对目前面临的问题进行简要叙述,对其在有色金属湿法冶金领域的应用前景进行了展望。     

大采高综放工作面强动压端头顶板控制技术

为了解决大采高综放工作面回风侧端头顶板控制问题,针对马道头矿8211工作面的地质情况,通过对回风顺槽超前注浆加固,提高超前支护范围和支护强度,并对回风侧端头三角区煤壁和顶板进行化学浆加固的技术方案,有效控制了顺槽超前区围岩变形和工作面回风侧端头三角区煤壁片帮,保证了工作面端头区顶板安全。     

综放切顶沿空留巷围岩变形特征分析及防治

为了掌握高地应力条件下综放沿空留巷围岩变形与破坏特征，以古汉山矿1604工作面为工程背景，采用理论分析的手段研究分析了综放沿空留巷围岩变形破坏形成机制，并提出采用预裂爆破切缝、强帮护顶等围岩控制措施，总结了综放沿空留巷技术原理，确定了沿空留巷支护参数，最后在现场进行了工业性试验。研究结果表明:沿空留巷巷道整体稳定性好，顶底板最大移近量为240~320 mm，两帮最大移近量为360~410 mm，支护效果良好，成巷效果较好；解决了采掘接替紧张、巷道维护困难的难题，满足了安全生产需要，提高了煤矿生产效率。     

伞帽用高铬铸铁在热强碱腐蚀环境下的磨损分析

针对氧化铝行业中常用的Cr28和Cr20高铬铸铁伞帽在相同工况条件下的磨损机理进行分析,并对比研究了实际生产中两种失效材料的成分、组织及性能。结果表明,伞帽部件在高温强碱腐蚀条件下受到外界冲刷时,磨损量由微切削磨损与变形磨损这两种机制共同决定。含铬量较高的Cr28高铬铸铁,其冲刷和抗腐蚀磨损性能均优于Cr20高铬铸铁。伞帽服役寿命主要受浆料和表层的铸铁材料两大因素影响。两种试验材料经淬火+回火处理后,基体组织中主要为回火马氏体+M₇C₃型碳化物+少量残留奥氏体,其中含铬量较高的Cr28高铬铸铁中共晶碳化物含量更高,且分布更加弥散,其平均硬度值为64.0 HRC,高于Cr20高铬铸铁的60.2 HRC。最终确定Cr28高铬铸铁作为伞帽材质更能满足氧化铝生产及设备检修周期的需要。     

补偿强反光体表面红外测温误差的算法研究

针对运动强反光体表面温度实时测量困难、精度低这一难点,本文从红外测温原理入手,分析并揭示了红外测温精度易受到被测物体反射率、测量距离、测量环境、红外入射角等因素的影响。根据铝板材加工设备轧辊表面测温实际需要设计了一种利用红外传感器实现对强反光体表面温度点对点测量的方案。通过对测量数据的研究分析建立了一种基于斯忒藩定律的红外入射角度补偿算法,以此减小因红外入射角度变化产生的测温误差。实验结果证明本方法能较好地弥补红外入射角度变化产生的测温误差,提高测温精度。该补偿算法运算简单,适应性强,为改善入射角度变化对测温精度影响提供了新的方法。     

Selective hydrogenation of acetylene over Pd/CeO2

Five hundred ppm Pd/CeO₂ catalyst was prepared and evaluated in selective hydrogenation of acetylene in large excess of ethylene since ceria has been recently found to be a reasonable stand-alone catalyst for this reaction. Pd/CeO₂ catalyst could be activated in situ by the feed gas during reactions and the catalyst without reduction showed much better ethylene selectivity than the reduced one in the high temperature range due to the formation of oxygen vacancies by reduction. Excellent ethylene selectivity of ~100% was obtained in the whole reaction temperature range of 50°C–200°C for samples calcined at temperatures of 600°C and 800°C. This could be ascribed to the formation of Pd_xCe_1−xO_2−y or Pd-O-Ce surface species based on the X-ray diffraction and X-ray photoelectron spectroscopy results, indicating the strong interaction between palladium and ceria.     

江苏沿海滩涂开发优化的动力机制研究

江苏沿海滩涂开发具有悠久的历史,但是传统的滩涂开发模式已经不能适应江苏省"强富美高"的发展新理念,现有的滩涂开发模式亟需优化升级。经过对由经济发展、生产方式变革、自然环境等要素构成的滩涂优化开发内源动力以及由科技创新、资金保障、政策制度等要素构成的外源动力进行分析,并对其连续动力机制进行深入研究,发现滩涂开发在其内外源动力的共同作用下可以逐步缓解人地矛盾,实现经济效益和富民的效应;但是开发与环境之间互为影响,甚至可能与环境美的目标相反。研究结果表明:在滩涂开发过程中,应坚持生态优先、绿色发展,加强政府引导、理顺机制,注重高新产业、科技投入,围绕临海能源、绿化造林,只有这样才能推动滩涂开发动力机制不断正向循环,实现经济社会的可持续发展。     

Asymptotic stability of general linear methods for systems of linear neutral delay differential-algebraic equations

This paper is concerned with numerical stability of general linear methods (GLMs) for a system of linear neutral delay differential-algebraic equations. A sufficient and necessary condition for asymptotic stability of GLMs solving such system is derived. Based on this main result, we further investigate the asymptotic stability of linear multistep methods, Runge–Kutta methods, and block θ-methods, respectively. Numerical experiments confirm our theoretical result.     

千米深井大断面硐室双强壳体支护成套技术的应用

从分析深井高应力大断面巷道和硐室破碎围岩的变形破坏特点入手,指出巷道稳定性的控制机理在于及时强化失稳区围岩的残余强度,阻止初次失稳的发展,并施加高强的主动支护结构,从而使巷道进入二次稳定状态,同时采取高强的被动封闭支护技术。提出了全断面双强壳体支护设计、3S耦合协调支护设计和抗张拉强基础梁支护设计等设计方案来控制巷道变形。并对绞车房进行现场施工,支护效果良好,达到预期目标。