A numerical study of dynamic behaviors of a unitized regenerative fuel cell during gas purging

The gas purging states affect electricity output and energy storage capacity of unitized regenerative fuel cells. In this study, a model of unitized regenerative fuel cell is established. Cell voltages and operating temperatures influences on the dynamic distribution of thermal fluid during purging process and the discharge of residual liquid water in electrolytic cell mode are investigated. The motivation of the present study is better understanding the gas purging characteristics and its effect on reaction behaviors of unitized regenerative fuel cells. Simulation results reveal a significant influence of purging gas temperature on the water flooding and a great effect of operating voltage on the water diffusion. The operating temperature of electrolytic cell model almost has little effect on purging results at different cell temperature and the same purging gas temperature. When the purging gas temperature is changed, higher temperatures of cell and purging gas facilitate liquid water discharging out from the cell regions. In cell water flooding situation, when having large liquid content, the purging gas has little effects on the water expelling process.     

地表径流速度对城市内涝影响规律

为分析地表径流速度对城市内涝的影响,采用一维地下排水管网与二维城区地形的动态耦合模型,选取大连市某排水区块作为研究区域,设置4种地表径流速度10种设计降雨场景,模拟分析在不同重现期设计降雨及不同地表径流速度下研究区的内涝积水特性。结果表明:随着地表径流速度降低,管道排水压力变小,管道排水达标率最高可提升48.05%,且降雨重现期越短,地表径流流速对管道排水压力的削减效果越明显;地表径流流速对检查井溢流量影响显著,随着地表径流速度降低,检查井溢流量峰值最高可减小2 750 m~3,峰现时间最长可滞后56 min,同时随着降雨重现期增长,地表径流流速对检查井溢流量的削减效果减弱;研究区低、高风险区淹没面积随地表径流速度降低,最高可分别减小1.64万、8.37万m~2,但中风险区淹没面积变化反复。     

Effect of electric field intensity on domain kinetics of Pb(Mg1/3Nb2/3)O3–0.38PbTiO3 single crystal

As one of the outstanding piezoelectric materials, relaxor-PbTiO₃ single crystal also exhibits promising electro-optic and nonlinear-optic properties. Therefore, it is vital to understand the domain switching kinetics not only for optimizing strain-mediated devices performance but also for fabricating optical waveguides and periodic domain structures in optical applications. In this work, domain switching kinetics in annealed and pre-poled PMN-0.38PT single crystal under different external electric field were studied. Polarization reversal can be accomplished only by c-domain nucleation and growth in the annealed sample where the formation of the ferroelastic domains is hindered. In pre-poled sample, 90° domain switching happened by 90° domain wall reorientation under low electric field while 180° domain switching is accomplished by two-step 90° domain switching and c-domain growth under high electric field. The results are important for modulating domain structure for strain mediated and optical devices.     

Complete Photochemical Regulation of 8–17 DNAzyme Activity by Using Reversible DNA Photo-crosslinking

The regulation of DNAzyme activity is an important problem for its in vivo applications. We achieved photochemical regulation of DNAzyme activity by using reversible DNA photo-crosslinking of 3-cyanovinylcarbazole (^CNVK). The ODN containing ^CNVK photo-crosslinked to a pyrimidine base in the complementary strand after a few seconds of photoirradiation, and its photoadduct was split by photoirradiation of another wavelength. The activity of photo-crosslinked DNAzyme with ^CNVK was completely inhibited (OFF state). In contrast, after 312 nm irradiation, DNAzyme activity was recovered upon addition of a substrate strand (ON state). In addition, the photo-crosslinked DNAzyme is prone to enzymatic digestion by exonuclease. This photochemical OFF to ON switching with reversible DNA photo-crosslinking was regulated at the desired time and position; therefore, it might be possible to use it for in vivo application.     

Computing approximate blocking probabilities for transparent waveband switching based WDM networks using hierarchical cross-connects

An analytical model is presented to study the dynamics of wavelength division multiplexing (WDM) networks with waveband switching (WBS). The reduced load approximation method is considered to compute approximated network blocking probabilities in WBS-based WDM networks. The analytical model considers the link blocking probability due to insufficient link capacity and an impact of the waveband granularity (G). The analytical model also considers the node blocking probability due to unavailability of a switch port at the wavelength cross connect (WXC) layer of an Hierarchical cross connect (HXC) switch node. The set of nonlinear equations is obtained with the link independence assumption and solved using repeated substitutions. The accuracy of the analytical model is examined by comparing with simulation results considering the random-fit algorithm for waveband and wavelength assignments in different network scenarios. Lightpaths are routed between source and destination (s-d) HXC switch nodes using shortest path first (SPF) routing. An impact of the switch parameter to limit the input and the output WXC switch ports of an HXC switching node is also being investigated using the analytical model as well as through simulation results.     

黄河什四份子弯道冰期水流及冰塞特征研究

覆冰条件下,弯道水流固有的三维特性更为复杂,对河流弯道冰下水流特征及冰塞的研究有助于推进防凌减灾工作。依据2020年1月稳封期的原型观测数据,对黄河什四份子弯道冰下水流及冰塞特征进行了详细分析。结果表明,弯顶节点工程引起的回流是阻冰的重要条件,上游下潜的冰花因水动力不足及河势等因素影响发生堆积,冰塞在弯内形成并沿凹岸主槽逐渐向上游发展,同时,弯顶卡冰封河与下游较大的水流流速,促进了清沟的形成;入弯至弯顶区间,冰下水流流速垂线分布基本服从双对数分布规律;受凹岸冰塞及回流影响,纵向上,水流流速呈减小趋势,在弯顶附近开始恢复;径向上,河道主流被冰塞压迫并逐渐趋于凸岸,致使弯道主流易位,凸岸水流流速大于凹岸,清沟向凸岸偏移;弯道水流湍动能与雷诺应力主要在近底处存在较大的变幅,表明近底水流运动活跃,且二者大小与流速大小在径向与纵向分布上具有较好的一致性,受冰盖影响,水流湍动能沿水深近似呈"S"形分布,雷诺应力分布无明显规律。     

Controllability and observability of multi-agent systems with heterogeneous and switching topologies

ABSTRACT

This paper focuses on controllability and observability of multi-agent systems with heterogeneous and switching topologies, where the first- and the second-order information interaction topologies are different and switching. First, based on the controllable state set, a controllability criterion is obtained in terms of the controllability matrix corresponding to the switching sequence. Next, by virtue of the subspace sequence, two necessary and sufficient algebraic conditions are established for controllability in terms of the system matrices corresponding to all the possible topologies. Furthermore, controllability is considered from the graphic perspective. It is proved that the system is controllable if the union graph of all the possible topologies is controllable. With respect to observability, two sufficient and necessary conditions are derived by taking advantage of the system matrices and the corresponding invariant subspace, respectively. Finally, some simulation examples are worked out to illustrate the theoretical results.     

热处理对挤压态Mg-6Gd-5Y-1Zn合金组织与性能的影响

通过对Mg-6Gd-5Y-1Zn(质量分数,%)合金在固溶和时效处理状态下显微组织和力学性能的研究发现,α-Mg基体、沿挤压方向分布的条状18R-LPSO相、少量的Mg₂₄(GdYZn)₅ 相以及细层片状的14H-LPSO相构成了挤压态合金的组成相。挤压态合金经固溶(T4)处理后,一部分18R-LPSO相溶入基体,并且基体中的14H-LPSO相伸长同时粗化。挤压态合金经过固溶加时效(T6)处理后,大量β′相从α-Mg基体中析出。T6态合金的室温力学性能最好,其屈服强度、抗拉强度及伸长率分别为272 MPa、406 MPa和6.1%。β′相沉淀也发生在挤压态合金的直接人工时效(T5)处理过程,但相比于T6处理,14H-LPSO相和β′相在基体中的体积分数均偏低。     

紫金山东南矿段成矿期次、阶段浅析

通过对紫金山东南矿段铜钼(金)矿床地质矿化特征分析,指出铜钼矿化带主要赋存于花岗闪长斑岩的内外接触带,处于似斑状花岗闪长斑岩的上部,金矿化带赋存在表生氧化带的英安玢岩、隐爆角砾岩中。经过对矿石的组构特征、矿物生成顺序等特征分析,将矿床的成矿演化过程分为斑岩热液期、高硫化浅成低温热液期、表生氧化期三个主要矿化期次,进一步将斑岩热液期分为黑云母-钾长石化阶段、石英-绢云母化阶段、碳酸盐化阶段三个阶段;高硫化浅成低温热液期分为地开石化阶段、明矾石化阶段、硅化阶段三个阶段。研究结果为进一步研究矿床成因提供了依据。     

Design and control of coaxial switching system for ion cyclotron wave resonance heating system of EAST

Ion cyclotron wave resonance heating system(ICRH) which is one of the most important auxiliary system in EAST provides conditions for heating the plasma. In order to make the whole transmission network of ICRH form the required state, the coaxial switching system was developed, which mainly consists of 11 same coaxial switches. Each coaxial switch has a controller with an RS485 communication interface and is able to switch between two states. All controllers are integrated to an RS485 hub which connects to the computer. A master computer software is developed to control the coaxial switching system so as to achieve the state needs of ICRH. Moreover, several rounds of experiments show that the coaxial switching system operates reliably. The coaxial switching system has already been applied to normal use currently.