Carbon-based TiO2-x heterostructure nanocomposites for enhanced photocatalytic degradation of dye molecules

Application of brown titanium dioxide (TiO_2-x) and its modified composite forms in the photocatalytic decomposition of organic pollutants in the environment is a promising way to provide solutions for environmental redemption. Herein, we report the synthesis of effective and stable TiO_2-x nanoparticles with g-C₃N₄, RGO, and multiwalled carbon nanotubes (CNTs) using a simple hydrothermal method. Among all the as-synthesized samples, excellent photocatalytic degradation activity was observed for RGO-TiO_2-x nanocomposite with high rate constants of 0.075 min^?1_, 0.083 min^?1 and 0.093 min^?1 for methylene blue, rhodamine-B, and rosebengal dyes under UV–Visible light irradiation, respectively. The altered bandgap (1.8 eV) and the large surface area of RGO-TiO_2-x nanocomposite impacts on both absorption of visible light and efficiency of photogenerated charge electron (e^?)/hole (h⁺) pair separation. This resulted in enhanced photocatalytic property of carbon-based TiO_2-x nanocomposites. A systematic study on the influence of different carbon nanostructures on the photocatalytic activity of brown TiO_2-x is carried out.     

The effect of bandwidth allocation policies on delay inunidirectional bus networks

We consider the problem of allocating bandwidth fairly to each node in a shared, unidirectional bus network. We focus on the p_i persistent protocol, since these are open loop policies designed to operate well in high speed networks, which have a very large bandwidth-delay product and feedback in the upstream direction is not available in a timely manner. First, we introduce an improvement to the basic p_i persistent protocol, in which we replace random coin tosses with a deterministic counting algorithm, and thereby reduce the delays for all nodes for any given choice of {p_i}. We then describe an exact method for calculating average packet delays and queue lengths in both the p_i persistent and our new deterministic n out of m protocols, based on the regenerative approach of Georgiades et al. (1987). These delay results, together with simulation measurements, show that both of these protocols still waste some bandwidth. After presenting a lower bounding argument to show that some wasted bandwidth is inevitable in all such distributed access control schemes, assuming a passive bus without feedback in the upstream direction, we show that changing the bus to unidirectional point-to-point links between (very simple) active interfaces at each node allows us to construct distributed access schemes that require no upstream feedback and are both work conserving and fair. To illustrate how this can be done, we introduce the p_i preemptive protocol, in which each node randomly inserts its own packets into the traffic arriving from upstream. We derive a simple and effective heuristic for calculating the preemption probability for each node, and use simulation to show how well it equalizes the delays at each node     

A 6-year clinical assessment of electronic facial thermography

The authors briefly report their experience regarding the opportunities offered by the use of current ultrasound methods in carotid surgery. They describe: a system for the quantification of athcromasic plaque used to monitor non-operated patients over time; ultrasound methods used to analyse the carotid wall to establish whether it can be utilised as an index of vascular aggression in hypertension, diabetes and atherosclerosis; the use of transcranial Doppler; criteria for the definition of high risk plaque; the applications of eco-color Doppler. The paper also illustrates a new pathology identified by the authors, defined as primary intimal fibrous hyperplasia, and the evolution of the carotid wall after endarterectomy. The structural characteristics of primary hyperplasia can only be shown using ultrasound given that arteriography cannot distinguish it from atheromatic stenosis. After endarterectomy the carotid wall is subject to hematic and hemodynamic stimuli which determine the type of evolution of the wall itself. The authors therefore examine the myointimal reaction, myointimal hyperplasia, early restenosis and late restenosis as different facets of the same phenomenon.     

A stochastic Kaczmarz algorithm for network tomography

We develop a stochastic approximation version of the classical Kaczmarz algorithm that is incremental in nature and takes as input noisy real time data. Our analysis shows that with probability one it mimics the behavior of the original scheme: starting from the same initial point, our algorithm and the corresponding deterministic Kaczmarz algorithm converge to precisely the same point. The motivation for this work comes from network tomography where network parameters are to be estimated based upon end-to-end measurements. Numerical examples via Matlab based simulations demonstrate the efficacy of the algorithm.     

Analysis of Indentation Crack as a Wedge-Loaded Half-Penny Crack

Surface cracks produced by indentation with a Vickers indenter were modeled as half-penny cracks extended by symmetric disk-shaped wedges. The wedge diameter was assumed to be equal to the hemispherical plastic zone size, and the wedge thickness was calculated by equating the wedge volume to the hardness-impression volume. The resulting equilibrium relation between the indentation load and the radius of the half-penny crack is in good quantitative agreement with similar relations obtained from fracture toughness calibration.     

Sorption,diffusion, and swelling characteristics of sodium alginate and its blend membranes with poly(vinyl alcohol) in water–acetic acid mixtures

Sorption, diffusion, and swelling characteristics of sodium alginate and its blend membranes with poly(vinyl alcohol) were investigated for water–acetic acid mixtures by using a gravimetric method at 30, 40, and 50°C. The membranes were characterized by X‐ray diffraction and Fourier transform infrared techniques. Concentration‐independent diffusion coefficients were obtained by applying Fick's relationship before completion of equilibrium sorption. Permeation coefficients were calculated from sorption and diffusion coefficients. Concentration profiles of liquids were computed considering the sheet geometry for the membrane by solving Fick's equation under suitable boundary conditions. Arrhenius activation parameters were computed for the transport processes. Experimental results and calculated quantities were discussed to understand membrane–solvent interactions. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1139–1150, 2004     

Studies on multilayer film coextrusion III. The rheology of blown film coextrusion

Multilayer blown film coextrusion was studied, both experimentally and theoretically. For the experimental study, an annular die with a feed-port system was designed and multilayer blown films were produced by rotating the inner mandrel with a one horsepower variable-speed drive at speeds from nearly 2 to 6 rpm, and by inflating the tubular molten film with air. The die has 16 feed slots and melt pressure transducers are mounted along the axial direction of the outer wall of the annular flow channel. The transducers were used to determine the pressure gradient in the annular flow channel, which then permitted determination of the reduction in pressure drop when different combinations of two polymer systems were coextruded. Polymers used for b own film coextrusion were: (1) low-density polyethylene with ethylene-vinyl acetate; (2) low-density polyethylene with high-density polyethylene; (3) low-density polyethylene with polypropylene; (4) high-density polyethylene with ethylene-vinyl acetate. For the theoretical study, stratified helical flow was analyzed using a power-law non-Newtonian model. A computational procedure was developed to predict the number of layers, layer thickness, and the volumetric flow rate as functions of certain processing variables (namely, the pressure drop in the die, and the angular speed of rotation of the inner mandrel of the die) and the rheological parameters of the individual polymers concerned. Comparison was made of the theoretical prediction of volumetric flow rate with experimental ones. Some representative results are presented of the theoretically predicted axial and angular velocity distributions, shear stress profiles, and shear rate profiles.     

Rising Crack-Growth-Resistance (R-Curve) Behavior of Toughened Alumina and Silicon Nitride

R -curves for a sinter/HIPed SiC(whisker)-reinforced alumina and a sintered silicon nitride were assessed by direct measurements of lengths of cracks associated with Vickers indentation flaws. The fracture toughness measurements based on (a) initial (as-indented) crack lengths, (b) equilibrium growth of cracks during increasing far-field loading, and (c) crack lengths corresponding to unstable fracture showed definitive trends of R -curves for both materials. The fracture mechanics analyses employed an indenter-material constant that was independently estimated using a physical model for the residual driving force and a free surface correction factor that accounted for the effects of size and shape of the cracks on stress intensity. It is shown that R -curve estimations based on crack length measurements have the intrinsic advantage that crack length dependence of fracture toughness is not assumed a priori as is done in conventional analysis based on strength. The measured fracture toughness of SiC(whisker)-reinforced alumina was in agreement with the prediction of a toughening model based on crack bridging by partially debonded whiskers.     

Articulatory and excitation source features for speech recognition in read,extempore and conversation modes

In our previous works, we have explored articulatory and excitation source features to improve the performance of phone recognition systems (PRSs) using read speech corpora. In this work, we have extended the use of articulatory and excitation source features for developing PRSs of extempore and conversation modes of speech, in addition to the read speech. It is well known that the overall performance of speech recognition system heavily depends on accuracy of phone recognition. Therefore, the objective of this paper is to enhance the accuracy of phone recognition systems using articulatory and excitation source features in addition to conventional spectral features. The articulatory features (AFs) are derived from the spectral features using feedforward neural networks (FFNNs). We have considered five AF groups, namely: manner, place, roundness, frontness and height. Five different AF-based tandem PRSs are developed using the combination of Mel frequency cepstral coefficients (MFCCs) and AFs derived from FFNNs. Hybrid PRSs are developed by combining the evidences from AF-based tandem PRSs using weighted combination approach. The excitation source information is derived by processing the linear prediction residual of the speech signal. The vocal tract information is captured using MFCCs. The combination of vocal tract and excitation source features is used for developing PRSs. The PRSs are developed using hidden Markov models. Bengali speech database is used for developing PRSs of read, extempore and conversation modes of speech. The results are analyzed and the performance is compared across different modes of speech. From the results, it is observed that the use of either articulatory or excitation source features along-with to MFCCs will improve the performance of PRSs in all three modes of speech. The improvement in the performance using AFs is much higher compared to the improvement obtained using excitation source features.