Twin-Related Tetragonal Variants in Yttria Partially Stabilized Zirconia

Crystals of yttria partially stabilized zirconia were grown by the arc-image floating-zone technique and studied by transmission electron microscopy. Crystals annealed at 1700°C consist of tetragonal precipitates and a cubic matrix. The platelike domains in a precipitate are twin-related tetragonal variants stacked alternately parallel to the (011) twin plane. The axial relations between the tetragonal precipitate and the cubic matrix are [100]_tetragonal|[100]_cubic, [011]_tetragonal|[011]_cubic.     

Electrical resistivity and Seebeck coefficient of La1−x M x MnO3 (M = Ca,Sr) single crystals

The temperature dependence of the electrical resistivity and Seebeck coefficient was measured on single crystals of La_1–x Ca _x MnO₃(0 <x 0.3) and La_1–x Sr _x MnO 3 (0 <x 0.4) grown by the arc-image floating zone method. The electrical conduction for La_1–x crystals withx 0.2 was of the activation type aboveT _c and of the degenerate type belowT _c, while that for the crystal withx = 0.1 was of the activation type over the whole measured temperature range between –170 and 400°C. The conduction behaviour of La_{1– x} Sr _x MnO₃ was essentially the same as that of La_1–x Ca _x MnO₃ except that the conduction of the crystals withx = 0.3 and 0.4 was of the degenerate type aboveT _c. A distinct difference in Seebeck data was observed between the calcium and the strontium compounds.     

Preparation of spherical fine ZnO particles by the spray pyrolysis method using ultrasonic atomization techniques

An ultrasonic atomizer was used in the spray pyrolysis method to prepare fine, spherical and uniform ZnO particles. Almost spherical particles were obtained successfully which had a mean particle size of 0.15 m and had a very narrow particle size distribution. By using alcohol as the solvent, it was found that the particles do not have hollow shell layers which could usually be observed in the spray pyrolysis process by using water as the solvent. The morphology of the ZnO particles was strongly affected by the concentration of the starting solution.     

Formation of monodispersed Ta2O5 powders

The Ta₂O₅ powders synthesized by the hydrolysis of tantalum pentaethoxide, Ta(OC₂H₅)₅ in alcoholic solution were monodispersed fine oxide particles, which were a uniform, spherical shape, non-agglomerate, and had a narrow size distribution. They grew to 1.2m after ageing for 1 h after hydrolysis. Powder X-ray diffraction and differential thermal analysisthermogravimetric analysis showed the particles were amorphous and hydrated. These particles lost the water at 290° C and gave well-crystalline Ta₂O at 740° C. Throughout these thermal processes, the particle morphology was kept almost the same.     

Effect of Silicon Dioxide on the Thermal Diffusivity of Aluminum Nitride Ceramics

The thermal diffusivity of AlN ceramics was significantly decreased by the addition of SiO₂. The AlN ceramics with 4 wt% SiO₂ could not be densified by pressureless sintering in the temperature range 1400° to 1800°C. The thermal diffusivity of these samples was very low because of their porous structure. The AlN ceramics containing 2, 4, and 8 wt% SiO₂ were densified by hot-pressing and also had low thermal diffusivity. In these samples, the grains of the 27R polytype that resulted from the reaction between AlN and SiO₂ were dispersed, obstructing the conduction of heat. The relation between the amount of 27R polytype and the thermal diffusivity of the AlN ceramics was determined.     

Nonequilibrium dynamics of a reacting network system

The nonlinear nonequilibrium properties of reacting network systems are studied by computer simulations. It is shown that the fluctuation in the population of each chemical species obeys a log-normal distribution, not the normal Gaussian distribution. The reaction rate shows power-law decay with activation cost (energy), not the Arrhenius-type exponential decay observed in a linear nonequilibrium regime. These two characteristic features will explain the diversity, plasticity, and adaptivity observed in complex biological reaction networks. This work was presented in part at the 13th International Symposium on Artifical Life and Robotics, Oita, Japan, January 31–February 2, 2008     

Response analysis for identifying the origin of photo-modulated current contrasts in scanning tunneling microscopic imaging semiconductor surfaces

Inhomogeneities in semiconductor solids can be imaged by two-dimensional mapping of the amplitude of periodically modulated tip current in scanning tunneling microscopy that is induced by illumination of semiconductor samples with a chopped light. It has been shown that it is possible to distinguish between plural origins of the photo-modulated current by analyzing the response properties of the current signal. A judicial choice of the modulation frequency is important for the required contrasts to be obtained.     

Huge-scale molecular dynamics simulation of multibubble nuclei

We have developed molecular dynamics codes for a short-range interaction potential that adopt both the flat-MPI and MPI/OpenMP hybrid parallelizations on the basis of a full domain decomposition strategy. Benchmark simulations involving up to 38.4 billion Lennard-Jones particles were performed on Fujitsu PRIMEHPC FX10, consisting of 4800 SPARC64 IXfx 1.848 GHz processors, at the Information Technology Center of the University of Tokyo, and a performance of 193 teraflops was achieved, which corresponds to a 17.0% execution efficiency. Cavitation processes were also simulated on PRIMEHPC FX10 and SGI Altix ICE 8400EX at the Institute of Solid State Physics of the University of Tokyo, which involved 1.45 billion and 22.9 million particles, respectively. Ostwald-like ripening was observed after the multibubble nuclei. Our results demonstrate that direct simulations of multiscale phenomena involving phase transitions from the atomic scale are possible and that the molecular dynamics method is a promising method that can be applied to petascale computers.     

A survey of perfluorooctane sulfonate and related perfluorinated organic compounds in water,fish, birds,and humans from Japan

Occurrence of perfluorooctane sulfonate (PFOS) in the tissues of humans and wildlife is well documented. In this study, concentrations and distribution of PFOS, perfluorohexane sulfonate (PFHS), and perfluorobutane sulfonate (PFBS) were determined in samples of surface water, fish and bird blood and livers, and human blood collected in Japan. Notable concentrations of PFOS were found in surface water and fish from Tokyo Bay. PFOS was found in all of the 78 samples of fish blood and liver analyzed. Based on the concentrations of PFOS in water and in fish livers, bioconcentration factors were calculated to range from 274 to 41 600. Concentrations of PFOS in the blood of Japanese human volunteers ranged from 2.4 to 14 ng/mL. PFHS was detected in 33% of the fishes analyzed, at concentrations severalfold less than those of PFOS.     

Growth Mechanism of Monodispersed ZrO2 Particles

Monodispersed ZrO₂ seed particles which were prepared by hydrolysis of zirconium alkoxide solutions were allowed to grow by further addition of zirconium alkoxide and water under conditions in which new particles do not nucleate and grow. The particle growth mechanism is presumed to be a surface reaction in which the rate-determining step is a first-order polynuclearlayer growth mechanism. With this method of powder preparation, it is possible to precisely control the particle size, and it may be useful for applications in ceramic processing.