TGA analysis of γ‐irradiated linear low‐density polyethylene

Linear low‐density polyethylene (LLDPE), based on butene‐1 or hexene‐1, was irradiated with γ‐rays under vacuum or in the presence of air. The study focused on the influence of the dose rate and the γ‐dose on the thermal properties of LLDPE. Differential scanning calorimetry, thermogravimetric analysis (TGA), and TGA/FTIR techniques were used to address the thermal behavior as a result of γ‐irradiation. During this irradiation, competition between crosslinking and scission reactions, subsequent to oxidation reactions, occurred in the polymeric material, which strongly depends on the experimental conditions. A decrease of the crystallinity for γ‐irradiated samples was observed in particular for samples irradiated under vacuum. This observation may be explained by increased hindrance of segment mobility due to crosslinking reactions that prevent crystal growth. TGA investigations revealed an enhancement of the thermal stability for samples irradiated under vacuum but not for those irradiated in air. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2790–2795, 2006     

The effect of photo-oxidation on thermal and fire retardancy of polypropylene nanocomposites

Nanocomposites of polypropylene-graft-maleic anhydride/clay were prepared by melt blending in an extruder mixer. The nanoscale dispersion of the clay in the polymer was analysed by wide-angle X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results of XRD and TEM showed that the nanocomposites obtained were a kind of intercalated-delaminated structures side by side with different dominant states, depending on the clay used and on the processing conditions. The consequences of photo-oxidation on the thermal stability and fire retardant properties of the nanocomposites were investigated using thermogravimetric analysis and cone calorimetry tests. It appeared that this degradation dramatically affected the important properties of the nanocomposites. A loss of thermal stability and fire retardant performance was observed. This was ascribed to scission reactions that occurred during the oxidative degradation prior to thermal and fire tests.     

Use of Endostemon tereticaulis (Pear.) M.Ashby and Hyptis spicigera Lam. Plant Extracts as Corrosion Green Inhibitors for Mild Steel in 1M HCl: Electrochemical and Surface Morphological Studies

Protection of Metals and Physical Chemistry of Surfaces - In the present study, we evaluated the effect of corrosion inhibition of ethanol extracts from Endostemon tereticaulis and Hyptis spicigera...     

A high pressure shock tube study of n-propylbenzene oxidation and its comparison with n-butylbenzene

Ignition delay times have been measured for mixtures of n-propylbenzene in air (≈21% O₂, ≈79% N₂) at equivalence ratios of 0.29, 0.48, 0.96 and 1.92 and at reflected shock pressures of 1, 10 and 30 atm in a heated high-pressure shock tube over a wide temperature range (1000–1600 K). The effects of reflected shock pressure and of equivalence ratio on ignition delay time were determined and common trends highlighted. Simulations were carried out using the n-propylbenzene sub-mechanism contained in an n-butylbenzene reaction mechanism available in the literature. This kinetic model was improved by including pressure dependent reactions which were not in place previously and the addition of the NUI Galway C₀–C₄ sub-mechanism. These simulations showed very good agreement with the experimental data. Additionally a comparison is made with experimental data previously obtained and published for n-butylbenzene over the same range of conditions and common trends are highlighted.     

Lipid production by Lipomyces starkeyi using sap squeezed from felled old oil palm trunks

1. Download : Download high-res image (272KB)
2. Download : Download full-size image

     

Thermal and mechanical properties of polypropylene/wood‐flour composites

In this research, polypropylene/wood‐flour composites (WPCs) were blended with different contents of wood and/or maleated polypropylene (MAPP) and clay. We found that the addition of MAPP or clay in the formulation greatly improved the dispersion of the wood fibers in the composite; this suggested that MAPP or clay may have played the role of an adhesion promoter in the WPCs. The results obtained with clay indicate that it also acted as a flame retardant. The thermal tests carried out with the produced samples showed an increased crystallization temperature (T_c), crystallinity, and melting temperature (T_m) with wood loading. The increase of the two former parameters was explained by the incorporation of wood flour, which played the role of nucleating agent and induced the crystallization of the matrix polymer. On the other hand, the T_m increase was ascribed to the insulating properties of wood, which hindered the movement of heat conduction. The effects of UV irradiation on T_m and T_c were also examined. T_c increased with UV exposure time; this implied that UV degradation generated short chains with low molecular weight that could move easily in the bulk of the sample and, thus, catalyze early crystallization. The flexural strength and modulus increased with increasing wood‐flour content. In contrast, the impact strength and tensile strength and strain decreased with increasing wood‐flour content. All of these changes were related to the level of dispersion of the wood flour in the polymeric matrix. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Study of the effect of γ-dose rate on the oxidation of polypropylene

Polypropylene PP (high and low crystallinity) was λ-oxidized, in the presence of air, using different dose rates (from 2 to 100 rad/s). Oxidation outcomes were identified and quantified by FTIR spectroscopy coupled with derivatization reactions (NO and SF₄). The difficulty to separate secondary and tertiary hydroperoxides from FTIR measurements after NO treatment was addressed. Polymer physical degradation was also monitored during the λ-irradiation process. GPC was used to follow molecular weight changes and tensile tests for elongation at break modifications. Comparison of the extent of oxidation product for-mation over λ-irradiation allowed us to investigate the importance of λ-dose rate on chemical and physical changes of PP. From this, different mechanisms of ketone and ester formation were examined; relationship between the molecular weight changes and the elongation at break modifications was also investigated. © 1996 John Wiley & Sons, Inc.     

Adaptive protocols for software distributed shared memory

We demonstrate the benefits of software shared memory protocols that adapt at run time to the memory access patterns observed in the applications. This adaptation is automatic-no user annotations are required-and does not rely on compiler support or special hardware. We investigate adaptation between singleand multiple-writer protocols, dynamic aggregation of pages into a larger transfer unit, and adaptation between invalidate and update. Our results indicate that adaptation between single- and multiple-writer and dynamic page aggregation are clearly beneficial. The results for the adaptation between invalidate and update are less compelling, showing at best gains similar to the dynamic aggregation adaptation and at worst serious performance deterioration     

影响水提取花生固形物的主要因素研究

研究了烘烤对于花生蛋白溶解性、浸泡(时间、效率)以及不同水／固形物(花生)比对总可提取固形物的影响。当烘烤温度为90～120℃，烘烤10min时，蛋白溶出率最高。最佳的浸泡时间和固形物(花生)／水比分别为6h，1：2。对于总可提取固形物而言，以其组成和粘度(2．1cps)为基准，花生／水比为1：8时最好。     

A symmetric finite element formulation for the inverse problem of aquifer transmissivity

This paper presents a symmetric isoparametric finite element formulation for the inverse problem of aquifer transmissivity calculation with known piezometric head. An important aspect of the present formulation is that the groundwater flow equation describing the aquifer behavior is transformed into a second-order differential equation by introducing an artificial variable φ. The two-dimensional, line and transition elements derived based on the weak formulation of this transformed equation possess symmetric matrices. In the formulation of the line elements φ and its derivative in η direction are retained as primary variables. This permits modelling of sudden changes in aquifer width. The transition elements provide a natural connecting link between the two-dimensional elements and the line elements. The line elements provide an efficient means of modelling aquifers with unidirectional flow. Numerical examples are given. A comparison of the results obtained here with the Galerkin finite element solution (nonsymmetric formulation) clearly demonstrates the superiority of the formulation presented here.