Synthesis,characterization and magnetic properties of polythiophene/SrFe12-x(ZrZn)0.5xO19 nanocomposite as a microwave absorber

Ferrites are an important group of magnetic materials which are used as absorbers. The incorporation of ferrite and conducting polymer achieves great enhancement in microwave absorption properties. The nanocomposites of hexagonal ferrites embedded by conducting polymers such as polypyrrole, polyaniline and polythiophene (PTH) have been paid much attention. In the present study, strontium hexagonal ferrite doped by Zr and Zn with the final formula of SrFe_12-x(ZrZn)_0.5xO19 considering x = 0.9 and embedded by PTH was produced to achieve a nanocomposite with the highest microwave absorbing ability. In this study, after synthesis of SrFe₁₂O₁₉(ZrZn)_0.5xO19 and PTH, the nanocomposite was prepared by in situ polymerization. Wrapping the ferrite particles and PTH chains could form nanocomposite properly, and therefore acceptable interactions were observable between SrFe_12-x(ZrZn)_0.5xO19ferrite particles and PTH polymer chains in the composites. Assessing the X-ray diffraction (XRD) patterns of SrFe_12-x(ZrZn)_0.5xO19, PTH, and PTH/SrFe_12-x(ZrZn)_0.5xO19 nanocomposite indicated that the PTH characteristic peak shifts slightly and its peak intensity reduces, which may be attribute to the coating of PTH polymer chains onto SrFe_12-x(ZrZn)_0.5xO19 particles. We revealed also lower magnetic properties in the obtained nanocomposite. The morphological assessment also suggested that PTH could effectively coat the SrFe_12-x(ZrZn)_0.5xO19 particles. The synergistic effect of SrFe_12-x(ZrZn)_0.5xO19 particle plus PTH leads to microwave absorption percentage higher than 95% by PTH/SrFe_12-x(ZrZn)_0.5xO19 nanocomposite. Overall, nanocomposite creating by coupling interaction between SrFe_12-x(ZrZn)_0.5xO19 particles (x = 0.9) and PTH can effectively lead to achieve the highest rate of absorption of electromagnetic waves.     

A Regioselective Approach to Synthesize Indolyl Diketone Derivatives via Magnetic Polymeric Copper-Catalyst

Catalysis Letters - In the present paper, an efficient Cu-catalyzed regioselective acylation of indoles with phenylglyoxals was developed which is the first example of indolyl diketones synthesis...     

Green synthesis of zinc oxide nanoparticles using Amygdalus scoparia Spach stem bark extract and their applications as an alternative antimicrobial,anticancer, and anti-diabetic agent

For the first time in this study, Zinc oxide nanoparticles were biosynthesized by the eco-friendly and cost-effective procedure using Amygdalus scoparia stem bark extract then used as antibacterial, antifungal, anticancer, and anti-diabetic agents. The characterization techniques confirmed the biosynthesis, crystalline nature, structure, size, elemental composition of ZnO NPs and bioactive compounds that exist in A. scoparia extract accounting for Zn²⁺ ion reduction, capping and stabilization of ZnO NPs. The ZnO NPs displayed remarkable inhibitory activity against E. coli, E. aerigenes, S. aureus, P. oryzae, F. thapsinum, and F. semitectum compared to antibiotic standards. The ZnO NPs showed significant inhibitory effects on cancer cell lines, while it had no toxic effect on Vero normal cell line. The ZnO NPs (30 mg/kg)-treated diabetic rats showed significantly higher levels of insulin and lower AST, ALT and blood glucose compared with the STZ induced diabetic group and other treated groups (P < 0.05). The ZnO NPs- and extract-treated rats showed significantly higher levels of IR, GluT2, and GCK expression and lower TNFα expression compared with the STZ induced diabetic rats. Our findings showed that ZnO NPs represented an outstanding performance for biological applications.     

Study on single and binary catalytic systems of pyridine-imine catalysts based on nickel and iron in synthesis of reactor blends and low-density polyethylene nanocomposites

In the presence of modified methylaluminoxane as cocatalyst, the behavior of a binary catalytic system based on pyridine-imine nickel ( N ) and iron ( F ) catalysts was evaluated in order to reach a proper mixture of polyethylene (PE). A computational study along with kinetic profile suggested that the catalyst F with higher electron affinity (A) and electrophilicity (ω) in the methyl cationic active center and stronger interaction with the monomer led to high integrated monomer consumption and higher activity. In addition, the samples produced by the mixture of catalysts showed a higher value of [19.4 × 10⁴ g (PE) mol (Fe+Ni)⁻¹ h⁻¹)], melting point (127.8 °C), and crystallinity extent (41.29%) than the samples produced by the single catalysts. The addition of multiwalled carbon nanotubes (MWCNT) into the polymerization media reduced the activity of catalysts [from 7.50 × 10⁴ to 0.66 × 10⁴ g (PE) mol (Fe+Ni)⁻¹ h⁻¹] and the thermal properties of the low-density polyethylene nanocomposite samples. However, the sample containing 2.33% MWCNT_20-30 improved the total thermal stability of the neat polyethylene blend up to 400 °C. Scanning electron microscope images of the samples demonstrated irregular to virtually uniform morphologies were obtained through the in situ and solution-mixing techniques. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47376.     

Correction to: Buckling of magneto-electro-hygro-thermal piezoelectric nanoplates system embedded in a visco-Pasternak medium based on nonlocal theory

Microsystem Technologies - The original version of this article unfortunately contained a mistake. Farzad Ebrahimi was not listed among the authors.     

Characterization,in vitro bioactivity and biological studies of sol-gel-derived TiO2 substituted 58S bioactive glass

Bioactive glasses (BGs) have been used for bone formation and bone repair processes in recent years. This study investigated the titanium substitution effect on 58S BGs (Ti-BGs) 60SiO₂-(36 − X)CaO-4P₂O₅-XTiO₂ (X = 0, 3, and 5 mol.%) prepared by the sol-gel technique, and the main goal was to find the optimum amount of titanium in Ti-BGs. Synthesized BGs, which were investigated after immersion in simulated body fluid (SBF), were tested by X-ray diffraction (XRD) analysis, Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy. Moreover alkaline phosphate (ALP) activity, 3-(4,5dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay, and antibacterial studies were employed to investigate the biological properties of Ti-BGs. According to the FTIR and XRD test results, hydroxyapatite (HA) formation on Ti-BGs surfaces was confirmed. Meanwhile, the presence of 5 mol.% compared to 3 mol.% increased the HA grain distribution and their size on the Ti-BGs surface. Additionally, MTT and ALP results confirmed that the optimal amount of titanium substitution in BG was 5 mol.%. Since 5 mol.% Ti incorporated BG (BG-5) had the highest biocompatibility level, antibacterial properties, maximum cell proliferation, and ALP activity among the synthesized Ti-BGs, it is presented as the best candidate for further in vivo investigations.     

Compressive strength and wear properties of SiC/Al6061 composites reinforced with high contents of SiC fabricated by pressure-assisted infiltration

Pressure-assisted infiltration was used to synthesize SiC/Al 6061 composites containing high weight percentages of SiC. A combination of PEG and glass water was used to fabricate SiC preforms and the effect of the presence of glass water on the microstructure and mechanical properties of the preforms was evaluated by performing compression tests on the preforms. Also, the compressive strength and the hardness of the SiC/Al composites were investigated. The results revealed that the glass water improved the compressive strength of the preforms by about five times. The microstructural characterization of the composites showed that the penetration of the aluminum melt into the preforms was completed and almost no porosity could be seen in the microstructures of the composites. Moreover, the composite containing 75 wt% SiC exhibited the highest compressive strength as well as the maximum hardness. The results of the wear tests showed that increasing the SiC content reduces the wear rate so that the Al-75 wt% SiC composite has a lower wear rate and a lower coefficient of friction than those of Al-67 wt% SiC composite. This indicated higher wear resistance in these composites than the Al alloy due to the formation of a tribological layer on the surface of the composites.     

CdSnO3/SnD NPs as a Nanocatalyst for Carbonylation of o-Phenylenediamine with CO2

Catalysis Letters - In order to carbonize o-phenylenediamine with CO2, an effective approach was used with UV light irradiation by Sn(IV) doping DFNS (SnD) supported CdSnO3 as a catalyst...     

Software assurance practices for mobile applications

Mobile software applications have to cope with a particular environment that involves small size, limited resources, high autonomy requirements, competitive business models and many other challenges. To provide development guidelines that respond to these needs, several practices have been introduced; however, it is not clear how these guidelines may contribute to solve the issues present in the mobile domain. Furthermore, the rapid evolution of the mobile ecosystem challenges many of the premises upon which the proposed practices were designed. In this paper, we present a survey of the literature on software assurance practices for mobile applications, with the objective of describing them and assessing their contribution and success. We identified, organized and reviewed a body of research that spans in three levels: software development processes, software product assurance practices, and software implementation practices. By carrying out this literature survey, we reviewed the different approaches that researchers on Software Engineering have provided to address the needs that raise in the mobile software development arena. Moreover, we review the evolution of these practices, identifying how the constant changes and modernization of the mobile execution environment has impacted the methods proposed in the literature. Finally, we introduced discussion on the application of these practices in a real productive setting, opening an area for further research that may determine if practitioners have followed the proposed assurance paradigms.