屏幕作为建筑元素的发展历程

立面和立面设计是建筑的基本要素,媒体立面是立面设计相对较新的分支领域。文章概述了媒体立面的设计与研究过程,并以六个项目为例介绍立面设计涉及的元素与子元素如何与通信技术相互结合。     

Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.     

Nickel phosphonate MOF as efficient water splitting photocatalyst

A novel microporous two-dimensional(2D)Ni-based phosphonate metal-organic framework(MOF;denoted as IEF-13)has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational techniques.Structure resolution by single-crystal X-ray diffraction reveals that IEF-13 crystallizes in the triclinic space group Pi having bi-octahedra nickel nodes and a photo/electroactive tritopic phosphonate ligand.Remarkably,this material exhibits coordinatively unsaturated nickel(II)sites,free-P0₃H₂and-P0₃H acidic groups,a C0₂accessible microporosity,and an exceptional thermal and chemical stability.Further,its in-deep optoelectronic characterization evidences a photoresponse suitable for photocatalysis.In this sense,the photocatalytic activity for challenging H₂generation and overall water splitting in absence of any co-catalyst using UV-Vis irradiation and simulated sunlight has been evaluated,constituting the first report for a phosphonate-MOF photocatalyst.IEF-13 is able to produce up to 2,200 fimol of H₂per gram using methanol as sacrificial agent,exhibiting stability,maintaining its crystal structure and allowing its recycling.Even more,170μmol of H₂per gram were produced using IEF-13 as photocatalyst in the absence of any co-catalyst for the overall water splitting,being this reaction limited by the 0₂reduction.The present work opens new avenues for further optimization of the photocatalytic activity in this type of multifunctional materials.     

兰陵县谷子高产栽培技术

谷子是山东省兰陵县优势特色杂粮作物,近年来,兰陵县农业农村局近年来大力集成推广谷子高产栽培技术,增产增收效果显著。对兰陵县谷子高产栽培技术10个环节进行阐述,旨在为同类地区谷子高产优质栽培提供参考。     

试论城市燃气爆炸事故及其防治对策

在城市经济建设飞快发展的过程中,作为具有高效性、清洁性的新型能源,城市燃气已经广泛的应用到了人们日常生活和各行各业的生产活动中,让城乡居民的生活质量得到了大大的提升,在降低空气污染的同时还改善了环境。但随之而来的城市燃气爆炸事故给国家财产和人民的生命安全造成了巨大的损失,本文笔者就天然气的危险性入手分析,对发生燃气爆炸事故的原因和预防措施进行探索。     

红外碳硫仪测定矿石中高含量硫

矿石中富含多种化学元素,对其准确测定十分关键。文章重点对红外碳硫仪对矿石中高含量硫的测定。     

找乐要乘早 莫负黄金周——欢度五一超完美规划

五一长假是众多上班族在春节后就一直在企盼的大日子，七天的胜利大逃亡是驱散疲劳、实现梦想、增进感情、宣泄压抑的最佳机会。而机会只留给有准备的人，只有早做打算、谋划周详，才能成竹在胸、悠然度假。否则，黄金周倏忽而逝，好时光一去不还，留给碌碌无为者的只有追悔莫及。《文萃》以为读者找乐为己任，特推出本期“特别制造”为大家的假日行动出谋划策，相信经过IT技能的全方位辅助，一年一度的节日将过得更加欢畅淋漓、多姿多彩![编者按]     

热处理对Ti-Mo-V-Nb-Al合金微观结构的影响

形状记忆合金由于其优良的超弹性和形状记忆效应而在医学上有着广泛的应用，其中由于NiTi形状记忆合金相较其它形状记忆合金具有更好的超弹性和生物相容性而得到了广泛的应用。但由于镍元素的毒性，使得开发一种生物相容性更好、无镍且具有良好力学性能的形状记忆合金成为必需。Ti-Mo-V-Nb-Al五元合金就是为此而开发的一种新型形状记忆合金。本研究用X射线衍射（XRD）、透射电子显微镜（TEM）和高分辨电子显微镜（HREM）研究了不同热处理条件对Ti-Mo-V-Nb-Al形状记忆合金微观结构的影响。     

硫酸厂主鼓风机的主要设计准则

论述现代硫酸厂主鼓风机设计时必须考虑的关键因素，通过实例讨论操作费用与投资之间的平衡关系以及对装置竞争力的影响。建议在硫酸厂严酷的操作条件下改进风机特性，提高耐磨性并采用维修友好的设计。