Role of Nd-Ni on structural,spectral and dielectric properties of strontium-barium based nano-sized X-type ferrites

The influence of neodymium and nickel substitution on structural and dielectric parameters was investigated in strontium-barium X-type hexagonal ferrites having composition SrBaCu_2?xNi_xNd_yFe_28?yO₄₆ (x = 0, 0.2, 0.4, 0.6, 0.8, 1 and y = 0, 0.02, 0.04, 0.06, 0.08, 0.1). Sol-gel method was employed for synthesizing these hexagonal ferrites. The XRD plots of all studied materials which were annealed at 1250 °C show single phase characteristics. Lattice parameter ‘c’ increased as a consequence of larger radius of rare earth ion (Nd³⁺) as compared to (Fe³⁺), while lattice parameter ‘a’ showed very small variation. The cell volume was obtained in the range 2508.32–2523.75 (ų). The inclusion of Nd-Ni also affected X-ray density, bulk density and porosity. The FTIR spectroscopy indicated the particular absorption peaks of hexagonal ferrites and it was performed in the range of 500–700 cm^?1. On account of Nd-Ni doping, the dielectric constant, dielectric loss and AC-conductivity showed decreasing trend. The occupancy of Nd³⁺ ions at octahedral site impedes the valence alternation of Fe³⁺; therefore there was decrease in dielectric permittivity. Ac conductivity has been decreased from 9.14 to 6.49 (Ω cm)^?1 at frequency of 2.7 GHz. The Cole-Cole plots of synthesized materials noticeably revealed grain boundary contribution. The appearance of single semi-circle in impedance Cole-Cole graphs confirms the exceptional role of grain boundaries in the conduction process. The considerably lower dielectric parameters of investigated nano X-type ferrites propose their feasibility for high-frequency applications (phase shifters, dielectric resonators, stealth technology etc).     

Performance comparison of space-time block coded and cyclic delay diversity MC-CDMA systems

Spatial diversity is a widely applied technique for enhancing wireless system performance since it greatly reduces the detrimental effects of multipath fading. Space-time block codes have been considered the best choice for transmit diversity in narrowband environments, but their use in broadband channels is questionable due to their inability to pick up multipath diversity. However, when used in conjunction with an MC-CDMA system, they achieve not only full spatial but also variable multipath diversity depending on the employed spreading. In comparison, cyclic delay diversity is an attractive approach to achieve spatial and multipath diversity. Its simplicity and conformability with current standards makes it desirable for multicarrier systems. Previous studies suggest that CDD is only advantageous with an outer channel code for OFDM systems. In this article, we compare STBCs and CDD applied to an MC-CDMA system in terms of complexity and performance. It is shown that for an MC-CDMA system, CDD benefits from spreading and channel coding that makes it very competitive with STBCs, particularly since it is applicable to any number of transmit antennas with no loss in rate.     

Solar ponds in alkaline lake and oil well regions

Solar ponds are probably the simplest technology available for the useful conversion of solar energy. The basic technology is proven. Solar ponds have been shown to be technically feasible and economically viable for many applications, particularly for thermal use. The electrical conversion and use of solar energy via solar ponds is still questionable, in general, for economic viability. By putting the untapped sources together in the South Plains region, it looks promising economically both for thermal and electrical conversions and applications. There are a number of alkaline lake basins randomly scattered in the South Plains region of the U.S.A. In that area, there are thousands of crude oil producing wells that produce brine in abundance. The selection of suitable alkaline lake basins as a solar pond site and as depository sites of brine from oil wells and the using of this brine and salty water from alkaline lakes makes the solar pond economically viable for both thermal and electrical demands in the area.     

Electrochemical degradation of petroleum hydrocarbons (PAHS) from synthetic aqueous solutions

Water separated from crude oil and wastewater discharge from petroleum oil refineries contains significant quantity of dissolved hydrocarbons. Polycyclic aromatic hydrocarbons (PAHs) are major toxicants in wastewater of refineries. It is difficult to treat wastewater containing PAHs due to their recalcitrant property and low solubility. Conventional techniques for the treatment of wastewater are still a concern of toxicity. Electrochemical oxidation process has been found to be a favorable for treating wastewater. Electrodes with high stability and electrocatalytic activity are important factors for a successful electrochemical oxidation of toxic organics in wastewater. In this study titanium anodes were coated with tin, antimony and iridium oxide mixture from their respective salts by thermal decomposition method. FESEM and XRD used for surface characterization of Ti/SnO₂–Sb₂O₅–IrO₂ anode. Quantification of PAHs was done using GC–MS. Results confirm the presence of respective oxides on anode surface. Their electrocatalytic capability was tested for degradation of 16 priority PAHs in aqueous solution. Results reveal the complete degradation of naphthalene, acenaphthylene, acenaphthene and fluorene without using NaCl electrolyte. While in the presence of NaCl naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene and pyrene were completely removed. About 98% of total PAHs removal was found at all initial pH values 3, 6, and 9 in the presence of electrolyte. Current study will be helpful in improving quality of petroleum industry wastewater containing PAHs.     

Latent Semantic Kernels

Kernel methods like support vector machines have successfully been used for text categorization. A standard choice of kernel function has been the inner product between the vector-space representation of two documents, in analogy with classical information retrieval (IR) approaches.Latent semantic indexing (LSI) has been successfully used for IR purposes as a technique for capturing semantic relations between terms and inserting them into the similarity measure between two documents. One of its main drawbacks, in IR, is its computational cost.In this paper we describe how the LSI approach can be implemented in a kernel-defined feature space.We provide experimental results demonstrating that the approach can significantly improve performance, and that it does not impair it.     

Some Implications of a Sample of Practical Turing Tests

A series of imitation games involving 3-participant (simultaneous comparison of two hidden entities) and 2-participant (direct interrogation of a hidden entity) were conducted at Bletchley Park on the 100th anniversary of Alan Turing’s birth: 23 June 2012. From the ongoing analysis of over 150 games involving (expert and non-expert, males and females, adults and child) judges, machines and hidden humans (foils for the machines), we present six particular conversations that took place between human judges and a hidden entity that produced unexpected results. From this sample we focus on features of Turing’s machine intelligence test that the mathematician/code breaker did not consider in his examination for machine thinking: the subjective nature of attributing intelligence to another mind.     

Earthquake-induced landslide mapping in the western Himalayas using medium resolution ASTER imagery

On 8 October 2005, a devastating earthquake struck northern Pakistan and several parts of Pakistani- and Indian-controlled Kashmir. The severely hit areas lie in close proximity to the most tectonically active region of the western Himalayas. The earthquake destroyed close to 400 000 houses and over 75 000 people lost their lives. The intensity of the earthquake was such that it triggered widespread landslides, which caused considerable destruction of the area's forests, and blocked the mountain roads and rivers. Satellite imagery-based analysis can be effectively used to provide critical geologic information for determining the causes of earthquakes, mapping of faults and lineaments, as well as for hazards and damage assessment mapping. In this study, Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) imagery acquired on 27 October 2005 was analysed to assess earthquake-induced land cover changes in severely hit areas. Image analysis techniques including intensity hue and saturation (IHS), principal component analysis (PCA), Normalized Difference Vegetation Index (NDVI) and Iterative Self-Organizing Data Analysis Technique (ISODATA) were applied on VNIR–SWIR bands of ASTER for the purpose of identification and mapping of landslides triggered by the earthquake in areas of northern Pakistan and Pakistani-controlled Kashmir. The techniques proved effective in identifying freshly exposed surfaces on mountain slopes, landslide scars and debris deposits. Accurate identification and mapping of landslides and slope failures can play an important role in post-earthquake damage assessment and hazards mapping in earthquake-prone mountainous areas.     

Microwave-assisted urea-modified sorghum biomass for Cr (III) elimination from aqueous solutions

The present study concentrated on the use of an agro-waste biodegradable sorghum biomass in its simple and modified forms for the binding of Cr (III) ions. A relatively new method of modification was adopted using urea under microwave irradiation. FTIR analysis showed the presence of oxygen and nitrogen bearing functional groups in unmodified (UMS) and modified (MS) sorghum biomass. The appearance of new bands and shifts in the peaks confirmed the modification. The influence of different process parameters such as the adsorbent dose, solution pH, contact time, agitation speed and initial metal ion concentration was studied thoroughly to evaluate optimum conditions for adsorption. Maximum adsorption for Cr (III) ions occurred at pH 5.0–6.0 using UMS and MS. Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm models in a non-linear fashion were used to explain the phenomenon. Maximum adsorption capacity was 7.03 and 16.36 mg of Cr (III) per gram of UMS and MS, respectively. Adsorption mechanism was explored by pseudo-first- and pseudo-second-order kinetic models, and it was found that the process followed pseudo-second-order kinetics. Thermodynamic study indicated the process favorability. The study concluded that urea modification under microwave irradiation produces a non-toxic and more effective adsorbent for Cr (III) remediation by inducing new nitrogen bearing functional groups to sorghum biomass.