Spectral characterization and ASTER-based lithological mapping of an ophiolite complex: A case study from Neyriz ophiolite, SW Iran

The Neyriz ophiolite occurs along the Zagros suture zone in SW Iran, and is part of a 3000-km obduction belt thrusting over the edge of the Arabian continent during the late Cretaceous. This complex typically consists of altered dunites and peridotites, layered and massive gabbros, sheeted dykes and pillow lavas, and a thick sequence of radiolarites. Reflectance and emittance spectra of Neyriz ophiolite rock samples were measured in the laboratory and their spectra were used as endmembers in a spectral feature fitting (SFF) algorithm. Laboratory spectral reflectance measurements of field samples showed that in the visible through shortwave infrared (VNIR-SWIR) wavelength region the ultramafic and gabbroic rocks are characterized by ferrous-iron and Fe, MgOH spectral features, and the pillow lavas and radiolarites are characterized by spectral features of ferric-iron and AlOH. The laboratory spectral emittance spectra also revealed a wide wavelength range of SiO spectral features for the ophiolite rock units. After continuum removal of the spectra, the SFF classification method was applied to the VNIR + SWIR 9-band stack, and to the 11-band data set of SWIR and TIR data sets of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor, using field spectra as training sets for evaluating the potential of these data sets in discriminating ophiolite rock units. Output results were compared with the geological map of the area and field observations, and were assessed by the use of confusion matrices. The assessment showed, in terms of kappa coefficient, that the SFF classification method with continuum removal applied to the SWIR data achieved excellent results, which were distinctively better than those obtained using VNIR + SWIR data and TIR data alone.     

Effect of Mentha spicata L. and Mentha aquatica L. essential oils on the microbiological properties of fermented dairy product,kashk

The antibacterial activity of Mentha spicata and Mentha aquatica essential oils (EO) was tested against Staphylococcus aureus, Lactobacillus reuteri, Bifidobacterium animalis and Clostridium perfringens using agar well and disc diffusion techniques. Results showed that M. spicata EO had the highest inhibition activity against the studied microorganisms. Then, the antibacterial activity of both EO at 1500 and 2500 ppm was examined in industrial liquid kashk during the storage at 4 °C for 20 days. Both EO reduced the S. aureus viable count below 5 log CFU g^?1 after 4 days; however, the population of C. perfringens, L. reuteri and B. animalis decreased <1 log CFU g^?1 during the storage time. The least deteriorative effect on the lactic acid bacteria was related to M. aquatica. As revealed by organoleptic studies, kashk samples containing M. aquatica EO at 1500 and 2500 ppm were the most preferred samples.     

Attitude of Iranian physicians and nurses toward a clinical decision support system for pulmonary embolism and deep vein thrombosis

This research project sought to design and implement a computerized clinical decision support system (CDSS) that was able to identify patients who were at risk of pulmonary embolism (PE) and deep vein thrombosis (DVT), as well as produce reminders for prophylactic action for these diseases. The main purpose of the CDSS was to attempt to reduce the morbidity and mortality caused by embolism and thrombosis in patients admitted to hospitals. After implementation of this system in one of the large educational hospitals of Iran, a standard questionnaire was used, and interviews were conducted with physicians and nurses to evaluate the performance of the designed system for reducing the incidence of pulmonary embolism and thrombosis. From physicians and nurses’ point of view, a system which assists the medical staff in making better decisions regarding patient care, and also reminds pulmonary embolism and thrombosis preventive procedures with timely warnings, can influence patient care quality improvement and lead to the improved performance of the medical staff in preventing the incidence of pulmonary embolism and thrombosis.     

The release rate and antimicrobial activity of calcium-alginate films containing self-microemulsifying Thymus vulgaris essential oil against Escherichia coli and Staphylococcus aureus

The aim of this study was to fabricate antimicrobial calcium-alginate-based films containing the self-microemulsifying thyme essential oil (TEO) formulations using Tween 80 as the surfactant, and acetic (AA) or propionic (PA) acids as the cosurfactants. A Ca-alginate film containing nano-emulsified TEO as well as a neat Ca-alginate film were considered as the controls. The scanning electron microscopy micrographs showed a highly porous texture for SME films, which resulted in an increase in water vapor permeability and water absorption capacity of these films. The SME films released the TEO completely within 155 min and inhibited the growth of S. aureus and E. coli in in vitro antimicrobial tests. The population of S. aureus and E. coli reduced significantly in ground beef covered with SME films. The results of this study showed that self-microemulsifying TEO films could effectively increase the shelf life of ground beef by controlling its microbial population.     

Polybutadiene/polyhedral oligomeric silsesquioxane nanohybrid: investigation of various reactants in polyesterification reaction

Nano‐sized polyhedral oligomeric silsesquioxane (POSS) diol or ethylene glycol (EG) as diol monomer was incorporated into hydroxyl‐terminated polybutadiene (HTPBD) chain in the presence of fumaryl or thionyl chloride as extenders. Using these polyesterification reactions, two fumarate‐based polyesters and two polyester sulfites were synthesized. Each couple of polyesters and polyester sulfites includes a linear (diol:EG) and a nanohybrid macromer (diol:POSS). Full structural characterization was performed using Fourier transform infrared, ¹H NMR and ¹³C NMR spectroscopies. Gel permeation chromatography was undertaken to study polyesterification mechanisms by deconvolution of the obtained traces. Finally, differential scanning calorimetry, thermogravimetric analysis and cell culture were performed to evaluate the structure–property relationship for the synthesized macromers in comparison with unreacted HTPBD. © 2016 Society of Chemical Industry     

Poly1‐hexene: New impact modifier in HIPS technology

Poly1‐hexene was prepared using a conventional heterogeneous Ziegler–Natta catalyst and its stereoregularity was characterized using ¹³C‐NMR analysis. New kind of high impact polystyrene (HIPS) was prepared by radical polymerization of styrene in the presence of different amounts of synthesized poly1‐hexene (PH) as impact modifier (HIPS/PH) and compared with conventional high impact polystyrene with polybutadiene (HIPS/PB) as rubber phase. Scanning electron microscopy (SEM) revealed that the dispersion of poly1‐hexene in polystyrene matrix was more uniform compared with it in HIPS/PB. The impact strength of HIPS/PH was 29–79% and 80–289% higher than that in HIPS/PB and neat polystyrene, respectively. FTIR was used to confirm more durability of HIPS/PH samples toward ozonation. To study the effect of rubber type and amount on the T_gs of polystyrene, differential scanning calorimetry was employed. Results obtained from TGA demonstrated higher thermal stability of HIPS/PH sample in comparison with conventional HIPS/PB one. Our obtained results suggest new high impact polystyrene that in all studied aspects has better performance than the conventional HIPS. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43882.     

Automatic labeling of cerebral arteries in magnetic resonance angiography

Objectives

In order to introduce 4D flow magnetic resonance imaging (MRI) as a standard clinical instrument for studying the cerebrovascular system, new and faster postprocessing tools are necessary. The objective of this study was to construct and evaluate a method for automatic identification of individual cerebral arteries in a 4D flow MRI angiogram.

Materials and methods

Forty-six elderly individuals were investigated with 4D flow MRI. Fourteen main cerebral arteries were manually labeled and used to create a probabilistic atlas. An automatic atlas-based artery identification method (AAIM) was developed based on vascular-branch extraction and the atlas was used for identification. The method was evaluated by comparing automatic with manual identification in 4D flow MRI angiograms from 67 additional elderly individuals.

Results

Overall accuracy was 93 %, and internal carotid artery and middle cerebral artery labeling was 100 % accurate. Smaller and more distal arteries had lower accuracy; for posterior communicating arteries and vertebral arteries, accuracy was 70 and 89 %, respectively.

Conclusion

The AAIM enabled fast and fully automatic labeling of the main cerebral arteries. AAIM functionality provides the basis for creating an automatic and powerful method to analyze arterial cerebral blood flow in clinical routine.

     

Investigation of rare earth sealing of porous micro-arc oxidation coating formed on AZ91D magnesium alloy

Magnesium and its alloys have been used in many industries, but they are reactive and require protection against aggressive envi-ronments. In this study, oxide coatings were applied on AZ91D magnesium alloy using micro-arc oxidation (MAO) process. Then, in order to seal the pores of the MAO coatings, the samples were immersed in cerium bath for different times. The surface morphologies and composi-tions of the coatings were analyzed by scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS), respectively. The corrosion behavior of the coatings was investigated with electrochemical impedance spectroscopy (EIS) and potentiodynamic polariza-tion tests in 3.5 wt.% NaCl solution. The amount of the porosity of the coating was measured by electrochemical method. It was found that the sealing treatments by immersion in cerium bath successfully sealed the pores of the MAO coatings. The results of the corrosion tests showed that the MAO coating which was sealed in Ce bath for 10 min enhanced the corrosion resistance of the substrate significantly. Fur-thermore, this coating had the lowest amount of the porosity among the coatings.)