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排序方式: 共有395条查询结果,搜索用时 718 毫秒
1.
Brian Lawn David Marshall Rishi Raj Greg Hirth Trevor Page Julie Yeomans 《Journal of the American Ceramic Society》2021,104(1):23-26
Crystalline quartz has long been identified as among the weakest of abundant crustal minerals. This weakness is particularly evident around the α–β phase inversion at 573°C, in which Si–O bonds undergo a displacive structural transformation from trigonal to hexagonal symmetry. Here we present data using indentation testing methodologies that highlight the precipitous extent of the transformational weakening. Although the indentations are localized over relatively small specimen contact areas, the data quantify the essential deformation and fracture properties of quartz in a predominantly (but not exclusively) compressive stress field, at temperatures and pressures pertinent to conditions in the earth's crust. 相似文献
2.
Ludmil Drenchev Jerzy Sobczak Rajiv Asthana Savko Malinov 《Journal of Computer-Aided Materials Design》2003,10(1):35-54
Ordered porosity metal materials belong to a relatively new class of porous materials named gasars. This paper presents a mathematical model of the complex physical phenomena in the production of gasars. Analyses for heat transfer, solidification kinetics and gas diffusion were coupled to describe the formation of unique gasar structure. Several criterial functions were introduced to provide significant quantitative information about the relationship between the operating technological parameters and the final structure. The computational outcomes of the numerical simulation were compared with the characteristics of real gasar ingots. The model was applied to determine the boundary conditions that would provide approximately constant physical conditions on the solidification front. The structure sensitiveness of gasars with respect to the different technological parameters is discussed. 相似文献
3.
Volatilization resulting from the thermal decomposition of Si3 N4 causes the large weight loss and desintering phenomenon observed during pressureless sintering of Si3 N4 -5% MgO and sialon (z =2)-5% MgO. The addition of a few weight percent of Si to the powder suppresses this volatilazation and helps to achieve fully dense Si3 N4 components. 相似文献
4.
Crystallization of Polymer-Derived Silicon Carbonitride at 1873 K under Nitrogen Overpressure 总被引:1,自引:0,他引:1
Martin Friess Joachim Bill Jerzy Golczewski re Zimmermann Fritz Aldinger Ralf Riedel Rishi Raj 《Journal of the American Ceramic Society》2002,85(10):2587-2589
The chemical stability of an amorphous silicon carbonitride ceramic, having the composition 0.57SiC·0.43Si3 N4 ·0.49C is studied as a function of nitrogen overpressure at 1873 K. The ceramic suffers a weight loss at p N2 < 3.5 bar (1 bar = 100 kPa), does not show a weight change from 3.5 to 11 bar, and gains weight above 11 bar. The structure of the ceramic changes with pressure: it is crystalline from 1 to 6 bar, amorphous at ∼10 bar, and is crystalline above ∼10 bar. The weight-loss transition, at 3.5 bar, is in excellent agreement with the prediction from thermodynamic analysis when the activities of carbon, SiC, and Si3 N4 are set equal to those of the crystalline forms; this implies that the material crystallizes before decomposition. The amorphous to crystalline transition that occurs at ∼10 bar, and which is accompanied by weight gain, is likely to have taken place by a different mechanism. A nucleation and growth reaction with the atmospheric nitrogen is proposed as the likely mechanism. The supersaturation required to nucleate α-Si3 N4 crystals is calculated to be 30 kJ/mol. 相似文献
5.
6.
The irrigation in regions of brackish groundwater in many parts of the world results in the rise of the water-table very close to the groundsurface. The salinity of the productive soils is therefore increased. A proper layout of the ditch-drainage system and the prediction of the spatio-temporal variation of the water table under such conditions are of crucial importance in order to control the undesirable growth of the water-table. In this paper, an approximate solution of the nonlinear Boussinesq equation has been derived to describe the water-table variations in a ditch-drainage system with a random initial condition and transient recharge. The applications of the solution is discussed with the help of a synthetic example.Notations
a
lower value of the random variable representing the initial water-table height at the groundwater divide
-
a+b
upper value of the random variable representing the initial water-table height at the groundwater divide
-
h
variable water-table height measured from the base of the aquifer
-
K
hydraulic conductivity
-
L
half width between ditches
-
m
0
initial water-table height at the groundwater divide
-
N(t)
rate of transient recharge at time t
-
N
0
initial rate of transient recharge
-
P
N
0/K
-
S
Specific yield
-
t
time of observation
-
t
0
logarithmic decrement of the recharge function
-
T
Kt/SL
-
x
distance measured from the ditch boundary
-
X
x/L
-
Y
h/L
- Y
mean of Y
- Y
Variance of Y 相似文献
7.
A suspension of mica particles (40m diameter and 3.7 thick) obtained in a mechanically stirred Al-4 wt % Cu-1.5 wt % Mg melt was poured and solidified in a variety of moulds under different heat flow configurations. The resulting cast structure showed a non-uniform distribution of dispersed mica particles with mica-depleted and segregated zones due to their flotation before and during solidification. The experimentally observed profiles of mica-free regions deviate significantly from those computed on the basis of Stokes's law and freezing-time computations. In relatively thick castings, segregation of mica could be minimized by using low pouring temperatures and/or side as well as bottom chilling. It was found, however, that thin castings (12.5 mm) could easily be produced with a homogeneous distribution of mica particles. 相似文献
8.
Akshay Atwe Ankur Gupta Rishi Kant Mainak Das Ishan Sharma Shantanu Bhattacharya 《Microsystem Technologies》2014,20(7):1373-1381
We report a novel pH-sensitive hydrogel based micro-valve for metered flow that has applications in a laboratory made “Intelligent valving system”. The hydrogel solution was prepared through Chitosan and poly vinyl alcohol in acetic acid and crystallized using gluteraldehyde as the crosslinking agent in the form of thin wafers and it was found to be very sensitive to pH changes. The pore structure of hydrogel was investigated through Field Emission Scanning Electron Microscopy and thin wafers of the gel were physically placed inside PDMS microchannels. Flow metering in these channels was observed by controlled expansion of the hydrogel plug till complete valving was realized. This valving device was further precisely characterized with micro Particle Image Velocimetry using a solution containing fluorescent polymeric micro beads. The principle advantage of this hydrogel device is the smaller range of pH (varying between pH 3 and 7) over which the valving response is observed. 相似文献
9.
Influence of Grain Size on Ferroelastic Toughening and Piezoelectric Behavior of Lead Zirconate Titanate 总被引:1,自引:0,他引:1
Lead zirconate titanate specimens, at composition Zr48.9+- 1.0 / Ti51.1+-1.0 of grain sizes ranging from 0.5 to 15 (μm were prepared by hot pressing. The fracture toughness showed a 40% increase in the fine-grained specimens. Poling produced anisotropy in the fracture toughness. A tensor representation for the fracture toughness, now a function of the crack plane normal and the poling direction, is developed. The maximum and minimum values in the toughness tensor are shown to be related to the unpoled toughness by a simple phenomenological relationship. We also find that the piezoelectric coefficient, d33 , shows a slight increase for the fine-grained specimens, which is in conflict with the general view that smaller-grained materials can sustain vanishingly small values of spontaneous polarization. 相似文献
10.
Influence of Distributed Particle Size on the Determination of the Parabolic Rate Constant for Oxidation by the Powder Method 总被引:1,自引:0,他引:1
The established analysis for the study of oxidation using powder specimens is based on the assumption of monosized particles. The experiments, however, are conducted on powders with a distributed particle size. Here we present a statistical approach for the calculation of the rate constant for oxidation. The results of the analysis are applied to new data on oxidation studies of dense powders of silicon carbonitride amorphous ceramics. The monosized model requires a wide range of values for the rate constant to fit the short term and the long-term data, leading to considerable ambiguity in the estimate of the parabolic rate constant, k p , for oxidation. In contrast the statistical model fits over the entire range of data, yielding a much more reliable value for k p . For example, the monosized approach gave a value in the range 19.7 × 10−18 < k p < 2.7 × 10−18 m2 /s. In contrast, the statistical model yields a specific value of 4.5 × 10−18 m2 /s. 相似文献