Piezoelectric properties of PVDF-conjugated polymer nanofibers

This study presents the development and characterization of PVDF-conjugated polymer nanofiber-based systems. Five different conducting polymers (CPs) were synthesized successfully and used to create the nanofiber systems. The CPs used are polyaniline (PANI), polypyrrole (PPY), polyindole (PIN), polyanthranilic acid (PANA), and polycarbazole (PCZ). Nanofiber systems were produced utilizing the Forcespinning® technique. The nanofiber systems were developed by mechanical stretching. No electrical field or post-process poling was used in the nanofiber systems. The morphology, structure, electrochemical and piezoelectric performance was characterized. All of the nanofiber PVDF/CP systems displayed higher piezoelectric performance than the fine fiber PVDF systems. The PVDF/PPY nanofiber system displays the highest piezoelectric performance of 15.56 V. The piezoelectric performance of the PVDF/CP nanofiber systems favors potential for an attractive source of energy where highly flexible membranes could be used in power actuators, sensors and portable, and wireless devices to mention some.     

Mode coupling contribution to radiation losses in curvatures for high and low numerical aperture plastic optical fibers

We have studied the optical power losses due to multiple curvatures in polymethylmetacrylate (PMMA) plastic optical fibers (POFs) of different numerical apertures (NAs) and attenuation. The fibers were tested for several configurations in order to assess the influence of different types of curved-to-straight fiber transitions in the amount of power radiation. We found that losses are below the standards for all tested fiber types, and thus, they are a suitable choice for local area network (LAN) applications. In addition, our results revealed the presence of modal interactions as confirmed using an experimental procedure to estimate the mode coupling strength for the same fibers.     

Automated estimation of rock fragment distributions using computer vision and its application in mining

Size distribution of rock fragments obtained from blasting and crushing in the mining industry has to be monitored for optimal control of a variety of processes before reaching the final grinding, milling and the froth flotation processes. Whenever feasible, mechanical sieving is the routine procedure to determine the cumulative rock weight distribution on conveyor belts or free falling off the end of transfer chutes. This process is tedious and very time consuming, even more so if a complete set of sieving meshes is used. A computer vision technique is proposed based on a series of segmentation, filtering and morphological operations specially designed to determine rock fragment sizes from digital images. The final step uses an area-based approach to estimate rock volumes. This segmentation technique was implemented and results of cumulative rock volume distributions obtained from this approach were compared to the mechanical fragment distributions. The technique yielded rock distribution curves which represents an alternative to the mechanical sieving distributions.     

Physiology of spinal anaesthesia and practical suggestions for successful spinal anaesthesia

There are numerous physiological effects of spinal anaesthesia. This chapter focuses on the physiological effects that are of clinical relevance to the anaesthesiologist, and provides suggestions for successful management of this simple and popular technique. The mechanisms and clinical significance of spinal-anaesthesia-induced hypotension, bradycardia and cardiac arrest are reviewed. The increasing popularity of ambulatory spinal anaesthesia requires knowledge that long-acting local anaesthetics, such as bupivacaine, impair the ability to void far longer than short-acting local anaesthetics, such as lidocaine. The importance of thermoregulation during spinal anaesthesia, and the clinical consequences of spinal-anaesthesia-induced hypothermia are reviewed. Effects of spinal anaesthesia on ventilatory mechanics are also highlighted. Lastly, the sedative and minimum-alveolar-concentration-sparing effects of spinal anaesthesia are discussed to reinforce the need for the judicious use of sedation in the perioperative setting.     

Crystallographic orientation dependence of the growth rate for GaAs low pressure organometallic vapor phase epitaxy

The complete crystallographic orientation dependence of the growth rate for GaAs low pressure organometallic vapor phase epitaxy (LPOMVPE) is determined using a previously described semi-empirical model. A set of LPOMVPE growth rate polar diagrams is presented for reactor temperatures near 550°C as well as near 700°C. Also, the variation of the growth rate polar diagrams as a function of process variables is given. The experimental data utilized in the semiempirical model was attained using a typical horizontal reactor LPOMVPE system and typical LPOMVPE process parameters.     

Social cost effectiveness of 2 systems of treatment of malnourished children, in Chile

Two approaches in the care of malnourished children were evaluated in order to ascertain both their medical and economical effectiveness. One was a group of 745 children under an ambulatory nutritional rehabilitation program that included health care, supplementary foods and nutrition education; a second group of 420 children attended Day Care Centers (8 hours a day and five days per week) where they received a balanced diet, psychomotor stimulation according to age, and health care. The evolution of nutritional status was followed up and plotted against the NCHS/WHO weight-for-height tables. The rate of recovery was unsatisfactory; below 50% in mild cases of malnutrition, and even less in the more severe cases. The average length of time for attaining normality was longer for moderate malnutrition and for the ambulatory program. When the calculation included a correction for the probability of recovery for each system, the advantage of the Day Care Centers became even more evident: the mean length of time for recovery was 33.2% less than the ambulatory program. The social cost per child, per day, was substantially lower in the ambulatory program. The integral calculus of social cost per child, per day, and the corrected mean time for recovery provided the social cost-effectiveness of nutritional recovery. This figure was clearly adventageous for the ambulatory program for all ages and degrees of malnutrition, exception made for moderately malnourished children below two years of age. In this case, the Day Care Centers appeared to be the most effective therapeutic alternative. This type of analysis is a contribution to the evaluation of medico-social programs for the recuperation of malnutrition. The advantage lies in the fact that it allows an optimization in the allocation of resources, when the previous step is the choice of best therapeutic alternative based upon the patient's age and nutritional status.     

Design recommendations for camera-based head-controlled interfaces that replace the mouse for motion-impaired users

This work focuses on camera-based systems that are designed for mouse replacement. Usually, these interfaces are based on computer vision techniques that capture the user’s face or head movements and are specifically designed for users with disabilities. The work identifies and reviews the key factors of these interfaces based on the lessons learnt by the authors’ experience and by a comprehensive analysis of the literature to describe the specific points to consider in their design. These factors are as follows: user features to track, initial user detection (calibration), position mapping, feedback, error recovery, event execution, profiles and ergonomics of the system. The work compiles the solutions offered by different systems to help new designers avoid problems already discussed by the others.     

Can a curved beam bistable mechanism have a secondary equilibrium that is more stable than its stress-free configuration?

A new concept for the geometry of a curved beam bistable micromechanical mechanism is proposed aiming at producing a secondary equilibrium state that is more stable (in terms of transformation force) than the primary, stress-free, configuration. The proposed geometry is simple and compatible with common MEMS mass-production processes. A parametric study is performed by means of a non-linear finite-elements analysis in order to study the post-buckling behavior and performance of the mechanism. Based on this analysis, we show that it is theoretically possible to have a mechanism that exhibits a secondary equilibrium state that is more stable than the stress-free configuration. We also find that the post-buckling response of the proposed design is very sensitive to a particular geometrical feature. Besides this particular weakness, the mechanism is rather robust with respect to geometrical inaccuracies. We report our findings with the hope of inspiring others to propose new ideas for overcoming this geometrical sensitivity.     

Applications of an oak extract on Petit Verdot grapevines. Influence on grape and wine volatile compounds

Petit Verdot vineyards were treated at veraison with a commercial aqueous French oak extract in order to determine if the extract’s volatile components can be transferred to grapes and then to wines. Three different formulations (25% (one application), 25% (four applications) and 100%) were tested, together with an eugenol and guaiacol standard solution to better follow their behaviour. The volatile compounds of treated grapes and their wines after alcoholic and malolactic fermentation and after 8 months were analysed by stir bar sorptive extraction and gas chromatography mass spectrometry (SBSE-GC–MS). The results showed that the grapes stored the volatile compounds mainly as non-volatile precursors, and some of these were released after winemaking. In the case of wines, it was possible to distinguish the control versus the ones from vineyard treatments. The different oak extract applications were evident only after alcoholic fermentation sampling, making it very interesting for young wines.     

Multifunctional coatings created using an antimicrobial polymer as a platform for titania precipitation on cotton

Titania precipitation on cotton has been achieved using a commercially available antimicrobial polymer, Reputex 20. The cotton swatches precipitated with titania retain antimicrobial activity, and we have also shown the ability to encapsulate diisopropylfluorophosphatase (DFPase), an enzyme capable of breaking down organofluorophosphates. Cotton swatches are easily prepared and precipitation occurs at room temperature in aqueous solutions at neutral pH. Both the antimicrobial properties of Reputex 20 and the hydrolytic activity of the DFPase enzyme are retained after titania precipitation, generating a cotton material exhibiting multifunctional properties. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43199.