Carbon corrosion mechanism on nitrogen-doped carbon support — A density functional theory study

In this work, density functional theory (DFT) calculations were used to investigate the mechanism of carbon corrosion on nitrogen-doped carbon support. Free energy diagrams were generated based on three proposed reaction pathways to evaluate corrosion mechanisms. The most energetically preferred mechanism on nitrogen-doped carbon was determined. The results show that the step of water dissociation to form ^#OH was the rate-determining step for gra-G-1N (graphene doped with graphitic N) and pyrr-G-1N (graphene doped with pyrrolic N). As for graphene doped with pyridinic N, the step of C^#OC^#O formation was critical. It was found that the control of nitrogen concentration was necessary for precisely designing optimized carbon materials. Abundance of nitrogen moieties aggravated the carbon corrosion. When the high potential was applied, specific types of graphitic N and pyridinic N were found to be favorable carbon modifications to improve carbon corrosion resistance. Moreover, the solvent effect was also investigated. The results provide theoretical insights and design guidelines to improve corrosion resistance in carbon support through material modification by inhibiting the adsorption of surface oxides (OH, O, and OOH).     

溶胶-凝胶法制备Li（MoO4）2：Eu及表征

用溶胶-凝胶法制备了平均粒径为2～3μm的小颗粒、高亮度的Li（2-x）（MoO4）2：Eu系列钼酸盐红色荧光体。用XRD、SEM、粒度分析和分子荧光光度计对荧光体进行了表征和研究。常规的固相反应合成Li（2-x）（MoO4）2：Eux系列红色荧光粉需要在900℃以上的高温才能够形成均一的固溶体，而采用溶胶-凝胶法制取，在700℃就可以形成均一的单相Li（2-x）（MoO4）2：Eux，在750℃就可得到发光亮度最高的荧光体。其亮度是常规固相反应于900℃制得的荧光体的124％。采用溶胶-凝胶法制取Li（2-x）（MoO4）2：Eux系列，可以在相当宽的实验条件范围内得到小粒径、窄分布和高亮度的荧光体，具有良好的颗粒形貌。     

一种双绕组电磁脱扣器的理论研究及控制策略

为满足智能电网对多层级配电网络的选择性保护要求,断路器中的脱扣器必须实现短路短延时保护功能.为此,本文提出一种双绕组电磁脱扣器,从理论分析和有限元仿真两个方向介绍其工作原理.设计了基于磁簧开关和时间继电器的控制模块,并给出时间继电器的控制策略.理论分析和有限元仿真表明,二次绕组具有去磁作用,可以实现短路短延时的目的.时间继电器的控制模块可对动作时间做出调整,从而可根据实际需要灵活改变短路短延时时长,具有很高的实用性.     

稀土在渗硼及硼的复合渗中的作用

本文综述了近十几年来稀土在渗硼及硼的复合渗中的作用以及稀土对渗层组织性能的研究概况，并对其作用机理作了初步探讨。     

一种基于结构相似性的图像质量评价指标

图像质量评价方法是控制传输、压缩和处理对图像质量影响的关键技术,也是多媒体系统中不可或缺的一部分。提出一种基于结构相似理论的图像质量评价指标,首先将待评价的图像分割成若干互不相交的图像块;然后分别计算图像块的显著性和结构相似度;最后以每个图像块的相对显著性作为权重,计算整幅图像的结构相似度。该模型时间复杂度低,同时实验表明该指标的性能明显优于传统指标。     

鄂尔多斯盆地延长气田马家沟组成藏条件分析

鄂尔多斯盆地马家沟组富含天然气,对其成藏条件进行研究,可很好的指导该区域天然气的勘探开发。本文以延长气田为例从烃源岩、储集层、盖层等方面分析了该区域天然气气藏形成的地质条件。