Fabrication of direct Z-scheme FeIn2S4/Bi2WO6 hierarchical heterostructures with enhanced photocatalytic activity for tetracycline hydrochloride photodagradation

A series of direct Z-scheme FeIn₂S₄/Bi₂WO₆ hierarchical heterostructures with intimate interface contacts were synthesized by in-situ growth route and characterized by systematical analyses. All as-prepared FeIn₂S₄/Bi₂WO₆ nanocomposites showed significantly enhanced photocatalytic activity towards photodegradation for the removal of tetracycline hydrochloride (TCH) in comparison with individual FeIn₂S₄ and Bi₂WO₆. Meanwhile, the highest photocatalytic degradation activity can be achieved by modulating adding amount of FeIn₂S₄ in FeIn₂S₄/Bi₂WO₆ nanocomposites and the optimized component ratio of FeIn₂S₄ to Bi₂WO₆ is determined to be 10 wt%. The enhanced photocatalytic activity could be ascribed to efficient separation between photogenerated holes and electrons based on the construction of direct Z-scheme system. The high photocatalytic stability of resultant 10 wt% FeIn₂S₄/Bi₂WO₆ nanocomposites was revealed through six successive recycling reactions. The main intermediate generated during TCH photodegradation was explored by HPLC-MS. Besides, the direct Z-scheme photocatalytic mechanism was confirmed by band position analysis, electron spin resonance (ESR) and active species capture experiment.     

深孔薄壁件挤压模CAD系统

介绍了利用ActiveXAutomation技术，以VB为开发工具，并采用参数化绘图研究开发的深孔薄壁件挤压模CAD系统。     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

对企业账面利润与现金流量关系的认识

本文阐述了企业账面利润与现金流量的关系 ,指出了企业账面利润与现金流量的四个不同点 ,并且提出了一个现代企业应如何在四个方面做好工作 ,正确处理好这两者的关系。     

遂昌县实践水能开发三大补偿机制的体会

介绍了遂昌县农村水电开发取得的成效及该县推行水电开发资源、经济和生态补偿制度的主要内容,分析了实践中存在的问题,提出了对策和措施。     

Kinetic analysis on spherulite growth rate of polypropylene catalloys

The kinetic analysis on melt-crystallization of polypropylene catalloys (PP-cats) was conducted through measuring their spherulite growth rates. A multiple melting behavior of PP-cats was found through differential scanning calorimetry (DSC) and the corresponding crystalline microstructures of PP-cats were studied by wide-angle X-ray diffraction (WAXD). The calculated T_m^o value of propylene homopolymer (PP) suggests an obvious melting point depression of PP-cats. Moreover, it is found that the existence of ethylene-propylene copolymer could result in the changes of crystalline microstructure of PP and the PP crystal is in favor of growing along (040) lattice plane of α-monoclinic crystal. The crystal growth rate of PP-cats decreases with the increase of ethylene-propylene copolymer content in PP-cats. A comparison of crystallization kinetics between PP-cats and virgin iPP through a modified Lauritzen-Hoffman model indicates that there appears a transition from regimes II to III in iPP and PP-cats containing low ethylene-propylene copolymer content. However, for the PP-cats containing high ethylene-propylene copolymer content, crystallization always processes in regime II. In addition, both calculated nucleation parameter (K_g) and the fold surface free energy (σ_e) for PP-cats increase with the increase of ethylene-propylene copolymer content, implying that the existence of ethylene-propylene copolymer is unfavorable for the surface nucleation of PP and regular folding of the molecule chain. It is believed that an increase in viscosity of the melts induced by different compositions could remarkably slow crystallization growth down, because under this condition surface nucleation dominates as compared with crystal growth.     

汽车NVH控制橡胶减震元件行业的现状与发展

汽车的NVH(Noise,Vibration and Harshness,即噪声、振动和不平顺性)特性是汽车的五大性能指标之一(另外四个性能指标为:安全性、经济性、环保性和可靠性)。汽车的NVH控制是通过控制汽车中有关     

基于频移键控的仿海豚哨声水声通信技术

针对水下隐蔽声通信的需求,该文提出一种基于频移键控的仿海豚哨声水声通信方法,通过模拟海豚哨声以降低通信信号被发现的概率,从而实现水下隐蔽声通信。该方法将信息调制生成的基带信号以一定比例与海豚哨声信号时频谱轮廓曲线相加获得合成哨声时频谱,再生成合成哨声作为仿生通信信号。接收端提取接收到的合成哨声与本地生成的存在固定频差的海豚哨声相干相乘,经过低通滤波获得频移键控信号进行信息解调,实现仿生通信。通过时频相关系数和Mel倒谱距离分析了通信信号仿生效果。仿真与海试试验验证了该方法的可行性,当码元宽度为0.1s时可在2km距离上实现有效通信,且时频相关系数不低于0.99。该方法调制解调原理简单,系统资源消耗更少,更易于工程实现,为仿生水声通信算法的实际应用提供技术支撑。