An investigation of the drivers,barriers, and incentives for environmental management systems in the Malaysian food and beverage industry

Clean Technologies and Environmental Policy - Food production and consumption is one of the major causes of global environmental degradation. One way to address environmental impacts in the food...     

Review on Zinc Oxide Nanoparticles: Antibacterial Activity and Toxicity Mechanism

Nano-Micro Letters - Antibacterial activity of zinc oxide nanoparticles (ZnO-NPs) has received significant interest worldwide particularly by the implementation of nanotechnology to synthesize...     

Antibacterial responses of zinc oxide structures against Staphylococcus aureus, Pseudomonas aeruginosa and Streptococcus pyogenes

The antibacterial responses of zinc oxide (ZnO) structures against Staphylococcus aureus, Pseudomonas aeruginosa, and Streptococcus pyogenes were investigated. Two ZnO powder samples, one with rod-like (ZnO-1) and the other with plate-like (ZnO-2) structures, were characterized for their morphological, structural, and optical properties. The rods were 30–120 nm in diameter, and the plates were 40–100 nm thick. XRD results revealed the wurtzite crystallinity of ZnO with average crystallite sizes of 33.72 (ZnO-1) and 39.25 (ZnO-2) nm. ZnO-2 possessed a relatively higher green photoluminescence than that of ZnO-1, suggesting a relatively higher amount of oxygen vacancies in ZnO-2 structures. Optical density measurements showed that both ZnO samples inhibited the growth of S. aureus, P. aeruginosa, and S. pyogenes by 29–98% after 24 h of treatment. The most dramatic growth inhibition was observed in S. pyogenes with 96% and 98% inhibition for ZnO-1 and ZnO-2, respectively, leading to a probable bactericidal phenomenon. The toxicological effect on S. pyogenes was probably due to the absence of catalase, making the bacteria vulnerable to the harmful reactive oxygen species (ROS) released by ZnO. ZnO-1 induced higher inhibition toward S. aureus and P. aeruginosa than that of ZnO-2 because of the smaller particle size of rod structures compared to plate and slab structures. The adhesion of ZnO particles on the membrane of bacteria could be the underlying cause of zinc toxicity effect towards the bacteria. ZnO-1 possessed larger surface area and provided higher amount of zinc atom, thereby inducing higher level of toxicity toward the bacteria. Two possible mechanisms were proposed to explain the inhibition of bacteria, namely, ROS toxicity toward cellular constituents and interaction of zinc with bacteria membrane through adhesion of ZnO particle. Several ZnO morphological-antibacterial correlations were presented in this work.     

Microstructure,mechanical properties,electrical conductivity and wear behavior of high volume TiC reinforced Cu-matrix composites

This study deals with the processing, microstructure, mechanical properties, electrical conductivity and wear behavior of high volume titanium carbide reinforced copper matrix composites. The microstructural study revealed that the titanium carbide particles were distributed uniformly in the matrix phase. No interface debonding and micro-cracks were observed in the composite. The addition of alloying elements in the copper considerably increased the sintered density and properties. The composite hardness and strength increased with titanium carbide content and alloying elements in the matrix phase. The electrical conductivities of the composites were predicted using three point upper bound and two phase self consistent predictive models. The wear resistance of the composites was studied against high speed steel. Wear mechanisms were discussed by means of microscope observations on the worn surfaces. The ratio of titanium carbide average grain size to the mean free path of the binder was introduced as a parameter to determine wear performance.     

An efficient numerical technique based on the extended cubic B-spline functions for solving time fractional Black–Scholes model

Financial theory could introduce a fractional differential equation (FDE) that presents new theoretical research concepts, methods and practical implementations. Due to the memory factor of fractional derivatives, physical pathways with storage and inherited properties can be best represented by FDEs. For that purpose, reliable and effective techniques are required for solving FDEs. Our objective is to generalize the collocation method for solving time fractional Black–Scholes European option pricing model using the extended cubic B-spline. The key feature of the strategy is that it turns these type of problems into a system of algebraic equations which can be appropriate for computer programming. This is not only streamlines the problems but speed up the computations as well. The Fourier stability and convergence analysis of the scheme are examined. A proposed numerical scheme having second-order accuracy via spatial direction is also constructed. The numerical and graphical results indicate that the suggested approach for the European option prices agree well with the analytical solutions.

     

Development of high strength,porous mullite ceramic hollow fiber membrane for treatment of oily wastewater

Ceramic hollow fiber membranes (CHFMs) are known for their excellent characteristics including high surface area, compact design, and good chemical, thermal, and mechanical stabilities. Despite these interesting attributes, CHFMs are also prone to certain limitations, such as brittleness and high cost that hinder them from being commercialized. To mitigate this drawback, we have developed a high strength, porous ceramic hollow fiber membrane, derived from mullite–kaolinite powder, for efficient oil–wastewater separation. The superhydrophilic, low-cost mullite-based (CHFM) was successfully fabricated through combined phase inversion and sintering techniques. Prior to the fabrication, the as-received mullite–kaolinite was characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and Brunauer–Emmett–Teller (BET) analyses. Subsequently, operational parameters such as the effect of mullite content, sintering temperature, and air gap were optimized during the fabrication of mullite ceramic hollow fiber membrane. The resulting membranes were systematically characterized and evaluated in terms of morphology, porosity, mechanical strength, water flux, and oil–water separation. Increasing the mullite content, air gap, and sintering temperature enhanced the formation of microvoid structure. It is interesting to note that the mechanical strength of 86 MPa was obtained for the membrane containing 60 wt % of mullite sintered at 1450 °C and an air gap of 5 cm. The membrane induced a stable permeate water flux and oil rejection of mullite CHFM of 182 L/m²?h and 97.1%, respectively. As compared to kaolin ceramic counterparts, this porous mullite ceramic hollow fiber membrane can be used in various water treatment applications, including for the separation of oily wastewater due to its mechanical strength and water flux.     

Enhanced Photocatalytic Performance of One-Pot Flash Combustion Synthesized ZnO Nanoparticles: An Effect of Bi Doping

The present work was aimed to develop pure and varying concentration (1, 2, 3, 5%) of Bi doped ZnO nanomaterials for photocatalytic application through a simple one pot synthesis technique. The structural, morphological, optical and photocatalytic behavior of the prepared samples were characterized using different techniques. The XRD results of the Pristine and Bi doped ZnO nanomaterials confirm that the samples exhibit hexagonal wurtzite structure of the ZnO. The crystallite size of the Bi doped ZnO samples decrease and the 5% Bi-doped ZnO sample exhibits a smaller crystallite size of 12.87 nm. The FT-RAMAN spectra show that the structural organizations of the prepared samples and also the spectra indicate the obtained vibrational modes are due to the motions of Zn²⁺ ions and O vacancies in the ZnO lattice structure. The FESEM analysis shows the prepared samples exhibits aggregated spherical form for the pristine ZnO and the size of the particles reduced upon increasing Bi concentration. The EDAX analysis confirms the presence of all synthesized compounds without any secondary phase impurities. The optical results suggests higher absorption and lesser bandgap for 5% Bi-doped ZnO sample and the spectrum is red shifted. The photocatalytic performance of the prepared Bi doped ZnO was evaluated in the decolourization reaction of methyl green aqueous solution under black light illumination. Bi doped ZnO samples exhibited high photocatalytic activity than bare ZnO. The loading % was optimized and the best performance was achieved from the sample, which contained 3 wt% of Bi. The rate constants of the decolourization reactions were calculated, and the stability of the best-performed sample was investigated.

     

Fabrications and applications of low cost ceramic membrane from kaolin: A comprehensive review

The application of low cost ceramic membrane from kaolin has attracted much interest due to its excellent mechanical stability, chemical and thermal resistivity and most importantly, because it is cost effective, in some cases, compared to polymeric membranes. The advantage of kaolin based ceramic membrane is its thermal properties that allow sintering at much lower temperature than alumina. Although many studies have been made on the application of kaolin based ceramic membranes, detailed discussions were scarcely made and the information on the fabrication of ceramic membrane from kaolin is very limited. This article is aimed to make a comprehensive review on ceramic membrane from kaolin for its fabrication methods and applications. An attempt is also made to show the future direction of the R and D on the kaolin based ceramic membrane.