Eight-node conforming straight-side quadrilateral element with high-order completeness (QH8-C1)

A new eight-node conforming quadrilateral element with high-order completeness, denoted as QH8-C1, is proposed in this article. First, expressions for the interpolation displacement function satisfying the requirements for high-order completeness in the global coordinate system are constructed. Second, the displacement function expression in global coordinates is transformed into isoparametric coordinates, and the relationships between the two series of coefficients for the two kinds of displacement function expressions are found. Third, the displacement function expression is modified to satisfy the requirements of nodal freedom and interelement boundary continuity. The key to the new element construction is the derivation of the linear relationship expressions among 12 coefficients of element displacement interpolation polynomials in the global and isoparametric coordinate systems. As a result, the relationship between quadratic completeness and interelement continuity is explicitly given, and a proof of the completeness and the continuity was conducted to theoretically guarantee the validity of the derivation results. Furthermore, in order to verify the correctness of the theoretical work, nine numerical examples were performed. The computation results from these examples demonstrate that QH8-C1 exhibited excellent performance, including high simulation accuracy, fast convergence, insensitivity to mesh distortion, and monotonic convergence.     

Mineralization of Para-Chlorobenzoic Acid in Water by Cobalt-Incorporated MCM-41 Catalyzed Ozonation

Cobalt-incorporated MCM-41(Co-MCM-41) was used as a heterogeneous catalyst for the ozonation of para-chlorobenzoic acid (p-CBA) in aqueous solution. Cobalt oxide supported on MCM-41(Co/MCM-41) was synthesized for comparison. Their textural properties were elucidated by various characterization techniques to understand the relationship between surface texture and catalytic activity. TOC removal at 60 min reached 91% with Co-MCM-41, 83% with Co/MCM-41 and only 52% with ozone alone, respectively. Observations from diffuse reflection spectroscopy demonstrated that different metal phases were formed in these cobalt-modified molecular sieves samples. Radical scavenger experiments indicated the formation of hydroxyl radicals that were responsible for the effective degradation of p-CBA. An integrated approach to the catalytic mechanism was proposed by considering the variation of pH in the course of ozonation as well as its subsequent influence on the dissociation of targeted compounds and surface charge of the catalyst. In the reusability experiments, the reused Co-MCM-41 was able to regain the same catalytic capability as the fresh one within 5 cycles. X-ray photoelectron spectroscopy results indicated that a part of Co²⁺ was oxidized to Co³⁺ after oxidation reaction.     

TiO2/MXene-Assisted LDI-MS for Urine Metabolic Profiling in Urinary Disease

Cancer remains an intractable medical problem. Rapid diagnosis and identification of cancer are critical to differentiate it from nonmalignant diseases. High-throughput biofluid metabolic analysis has potential for cancer diagnosis. Nevertheless, the present metabolite analysis method does not meet the demand for high-throughput screening of diseases. Herein, a high-throughput, cost-effective, and noninvasive urine metabolic profiling method based on TiO₂/MXene-assisted laser desorption/ionization mass spectrometry (LDI-MS) is presented for the efficient screening of bladder cancer (BC) and nonmalignant urinary disease. Combined with machine learning, TiO₂/MXene-assisted LDI-MS enables high diagnostic accuracy (96.8%) for the classification of patient groups (including 47 BC and 46 ureteral calculus (UC) patients) from healthy controls (113 cases). In addition, BC patients can also be identified from noncancerous UC individuals with an accuracy of 88.3% in the independent test cohort. Furthermore, metabolite variations between BC and UC individuals are investigated based on relative quantification, and related pathways are also discussed. These results suggest that this method, based on urine metabolic patterns, provides a potential tool for rapidly distinguishing urinary diseases and it may pave the way for precision medicine.     

灌浆技术在紫山灰坝迎灰坡裂缝处理中的应用

本文分析了紫山灰坝迎灰坡裂缝的成因，并介绍了充填式灌浆处理方法，效果良好。     

减压渣油与FCC油浆共炭化的化学组成变化

考察了齐鲁石化胜利炼油厂催化油浆（FCC）和胜利减压渣油（VR）在490℃，0.8MPa下不同混合比的原料和不同反应时间的中间产物的HS、TS、PS、P及其1h中间产物的HS和TS的^1H-NMR。数据结果反映了体系的反应速度。掺入FCC油浆抑制了VR的反应活性，降低了体系的反应速度，增加了基质的溶解度；1h中间产物的组成结构更接近于原料及反应体系的反应性和基质的溶解度；1h中间产物的芳香度越高，取代基越少，侧链越短，基质对VR中的活性反应组分在炭化早期生成的高度缩合物质的溶解度越大。     

高分子纳米LB膜的制备及其光刻性能研究

合成并表征了N-十六烷基丙烯酰胺（HDA）和对叔丁基苯酚甲基丙烯酸酯（BPhMA）的共聚物p（HDA-BPhMA）s。当HDA含量较高时，共聚物可在气，液界面上形成稳定，排列紧密的单分子薄膜，并可以Y型膜的方式沉积在各种固体基片上，形成多层均匀的Langrnuir-Blodgett（LB）膜。这种LB膜被成功地应用于光刻，获得了分辨率为0.5μm的LB膜图形。以该图形为抗蚀层，可将图形进一步转移至金属薄膜上，得到分辨率较高的金属图形，在图形转移的过程中，这种LB膜显示出较高的抗蚀性，有望作为纳米抗蚀薄膜材料在亚微米刻蚀领域得到应用。     

温度敏感葡聚糖凝胶的合成及其细胞相容性研究

合成了N-异丙基丙烯酰胺（NIPAAm）与葡聚糖的共聚水凝胶，利用红外光谱表征了单体和凝胶结构，研究了水凝胶在去离子水和细胞培养基中的温度响应性，并对凝胶进行了细胞培养和脱附研究．结果表明，共聚凝胶具有很好的温度敏感性和细胞相容性，可以通过控制温度变化，实现对细胞的无损伤脱附．     

柴达木盆地北缘断裂构造与油气聚集

柴达木盆地北缘地区油气藏严格地沿断裂展布,自北西向南东沿断裂带依次分布冷湖三号-七号油气聚集带、南八仙油气聚集带和马海油气聚集带.柴北缘地区断裂的形成与阿尔金山和祁连山在中新生代的剧烈挤压和走滑活动有关.断裂以逆断层为主,还有少量的同沉积正断层、平移断层等.断裂走向以NW向和NWW向为主,平面上呈弧形弯曲、平行、斜列、交叉展布的"S型"或"反S型"等组合类型,剖面组合样式主要有伸展构造、基底卷入型、盖层滑脱型等类型.其中,以基底卷入型和盖层滑脱型形成的构造油气藏最为发育.断裂不仅控制了生烃凹陷的展布及构造圈闭的形成,在一定程度上也控制了有利储集相带的展布.断裂活动形成的大量裂缝,改善了储层的物性条件.柴北缘地区普遍存在以断裂为油气运移通道形成的下生上储式油气藏.     

机器人骨骼-肌肉系统工程模拟的动态分析

用振动学理论对仿人机器人骨骼-肌肉系统工程模型进行了分析，并提出了一种控制振动的方法，提高仿人机器人运动精度和缩短达到稳定的时间，同时阐述了这种方法的可行性。     

供应链环境下的性能评价系统研究

在竞争全球化的趋势下，供应链管理越来越受到企业重视，供应链性能评价系统(supply Chain Performance Mea-surement System,SCPMS)是供应链管理的关键组成部分，然而企业却不愿意或没有能力建立有效的性能评价系统。总结了供应链性能评价的定义、发展过程及难点，在此基础上提供了一套供应链性能评价的方法，为企业快速建立集成供应链性能评价系统提供借鉴。