Synthesis of Hollow Three-Dimensional Channels LiNi_(0.5)Mn_(1.5)O_4 Microsphere by PEO Soft Template Assisted with Solvothermal Method

A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion.     

Influence of CO2 inleakage on the slight-alkalization of generator internal cooling water

The slight-alkalization of generator internal cooling water (GICW) is widely used to inhibit the corrosion of hollow copper conductor and thereby ensure the safe operation of the generator. CO₂ inleakage is increasingly identified as a potential security risk for GICW system. In this paper, the influence of CO₂ inleakage on the slight-alkalization of GICW was theoretically discussed. Based on the equilibriums of the CO₂-NaOH-H₂O system, CO₂ inleakage saturation was derived to quantify the amount of the dissolved CO₂ in GICW. This parameter can be directly calculated with the measured conductivity and the [Na⁺] of GICW. The influence of CO₂ inleakage on the slight-alkalization conditioning of GICW and the measurement of its water quality parameters were then analyzed. The more severe the inleakage, the narrower the water quality operation ranges of GICW, resulting in the more difficult the slight-alkalization conditioning of GICW. The temperature calibrations of the conductivity and the pH value of GICW show non-linear correlations with the amount of CO₂ inleakage and the NaOH dosage. This study provides insights into the influence of CO₂ inleakage on the slight-alkalization of GICW, which can serve as the theoretical basis for the actual slight-alkalization when CO₂ inleakage occurs.     

MOMEDA结合数学形态滤波的齿轮故障特征提取

为了实现齿轮故障特征的有效提取,针对齿轮早期故障振动信号非线性、非平稳且信噪比低的特点,提出了一种基于多点最优最小熵反卷积(MOMEDA)和数学形态滤波的齿轮故障特征提取方法。首先利用MOMEDA恢复信号中的周期性故障特征并实现信号的降噪,再运用形态差值滤波器对解卷积后的信号进行滤波以增强信号中的冲击特征,最后对滤波结果求取频谱以进行故障特征提取;通过对仿真结果和实验数据的分析验证了该方法的可行性和有效性。结果表明,该方法具有抑制噪声和提取周期性故障冲击特征的能力,能够实现齿轮故障特征的提取。     

南非铜尾矿回收铁选矿试验

为了综合回收现有南非铜尾矿中的有价铁元素，在试验室对该铜尾矿进行了回收铁的可选性试验研究。研究结果表明：该铜尾矿铁品位为59.36%，磁性铁含量为57.99%，当原矿磨矿细度为-0.074 mm 58%时，经两次磁选后，可获得产率为88.95%，铁品位为65.69%，铁回收率为98.43%的铁精矿。     

泳池式轻水反应堆内电磁线圈可控温辐照装置设计

本文设计了在泳池式轻水反应堆（简称泳池堆）内在线测量电磁线圈电性能的可控温辐照装置。采用MCNP程序进行中子物理计算，对泳池堆、线圈骨架的结构尺寸与物质组分进行了精细全尺寸模拟，得出辐照装置的发热功率和中子注量率。通过初步估算，使用ANSYS CFX进行了数值模拟，得出辐照装置内线圈在堆运行时的温度，并提出温度控制的方法。辐照装置采用铝材加工制造，并进行了垂直度测试、气压测试、检漏测试。增加了绝缘设计，将辐照装置与泳池堆之间进行绝缘。在线圈处预埋铠装热电偶，对线圈温度进行实时监测。在泳池堆内对电磁线圈进行辐照试验，结果表明，本文设计的辐照装置能满足电磁线圈在泳池堆孔道内进行辐照试验的要求，并可对电磁线圈进行实时温度控制。     

Sr_2MgSi_2O_7:Eu~(2+),Dy~(3+)-转换剂红色光夜光材料的制备及表征

将具有氧蒽结构的光转换剂加入Sr_2MgSi_2O_7:Eu~(2+),Dy~(3+)荧光粉,可以使夜光纤维的发射光谱红移,发出红色光。采用两种不同的偶联剂对发光材料和光转换剂进行偶联,制备一种能够发出红光的发光材料。借助荧光分光光度计、长余辉荧光测试仪检测红光发光性能,比较光转换剂对发光材料的包覆效果,以提高发光材料向光转换剂的能量传递效率,为开发新型的、发光性能较好的红色夜光纤维提供一定的理论依据。     

基于密钥共享的分层混合认证模型

随着信息时代的迅速发展,云计算数据访问安全已经成为了用户最关心的问题。身份认证技术是确保参与者在开放的网络环境中实现安全通信的一种重要手段,如何利用身份认证技术为云环境安全保驾护航,成为学者研究的热点。文中通过公钥基础设施(Public Key Infrastructure,PKI)颁发CA证书以在不同云服务间建立信任,将多个采用身份密码体制(Identity-Based Encryption,IBE)的云联合起来；采用分层身份加密体系,引入共享密钥技术,通过选取成环结构,提出一种PKI-IBE混合认证模型方案,并对方案的安全性进行分析,从理论上证明了云环境下PKI-IBE(Public Key Infrastructure-Identity-Based Encryption)同层成环模型提供服务的可行性。同时文中设计了一种基于该模型的签密技术,通过公私密钥对实现云内认证以及跨云认证。安全性理论证明与性能分析表明,该方案在计算量稍增加的前提下,保证了足够的安全性,更加满足云环境下的用户分属不同云域的认证以及用户安全访问的需求,有效解决了云环境中数据访问的安全问题。     

Mn掺杂三元固溶体系BNT-KBT-BT陶瓷的结构与性能研究

采用传统固相烧结法合成了Mn掺杂改性BNT基复合体系无铅压电陶瓷,并对其微观结构和电学性能进行了表征和研究.结果表明,Mn掺杂量小于0.6wt％时,样品均保持钙钛矿结构.掺杂量为0.30wt％时,陶瓷样品综合性能最佳,压电常数d33=174 pC/N,介电常数εr=9800,介电损耗tanδ=0.04,剩余极化强度Pr高达36μC/cm2,矫顽场强度Ec降至25 kV/cm,样品具有良好的温度稳定性.并通过扫描电镜中的成份面扫,探讨了Mn掺杂的占位分布和掺杂机制.