Removal of bis(2-ethylhexyl) phthalate at a sewage treatment plant

Bis(2-ethylhexyl) phthalate (DEHP) concentrations were measured at different stages in a full-scale sewage treatment plant (STP) and mass balances were calculated. The DEHP load to treatment process coming from the sewer system and the internal load comprising returned supernatants and filtrate from sludge treatment and excess secondary sludge were at the same level. The DEHP removal efficiency from the water phase at the STP was on average 94% of sewage DEHP, the main removal process being sorption to primary and secondary sludges. On average 29% of DEHP was calculated to be removed in the biological nitrifying-denitrifying activated sludge process, which was much less than expected from laboratory biodegradation studies described in literature. Monoethylhexyl phthalate, the primary biotransformation product of DEHP, was not detected at any treatment stage. Approximately 32% of DEHP in sewage was removed during anaerobic digestion of the sludge, while 32% remained in the digested and dewatered sludge.     

Photoswitchable Superabsorbency Based on Nanocellulose Aerogels

Chemical vapor deposition of a thin titanium dioxide (TiO₂) film on lightweight native nanocellulose aerogels offers a novel type of functional material that shows photoswitching between water‐superabsorbent and water‐repellent states. Cellulose nanofibrils (diameters in the range of 5–20 nm) with native crystalline internal structures are topical due to their attractive mechanical properties, and they have become relevant for applications due to the recent progress in the methods of their preparation. Highly porous, nanocellulose aerogels are here first formed by freeze‐drying from the corresponding aqueous gels. Well‐defined, nearly conformal TiO₂ coatings with thicknesses of about 7 nm are prepared by chemical vapor deposition on the aerogel skeleton. Weighing shows that such TiO₂‐coated aerogel specimens essentially do not absorb water upon immersion, which is also evidenced by a high contact angle for water of 140° on the surface. Upon UV illumination, they absorb water 16 times their own weight and show a vanishing contact angle on the surface, allowing them to be denoted as superabsorbents. Recovery of the original absorption and wetting properties occurs upon storage in the dark. That the cellulose nanofibrils spontaneously aggregate into porous sheets of different length scales during freeze‐drying is relevant: in the water‐repellent state they may stabilize air pockets, as evidenced by a high contact angle, in the superabsorbent state they facilitate rapid water‐spreading into the aerogel cavities by capillary effects. The TiO₂‐coated nanocellulose aerogels also show photo‐oxidative decomposition, i.e., photocatalytic activity, which, in combination with the porous structure, is interesting for applications such as water purification. It is expected that the present dynamic, externally controlled, organic/inorganic aerogels will open technically relevant approaches for various applications.     

Copolymerization of carbon monoxide with exo‐methylenecycloalkane and dienes: synthesis of functionalized aliphatic polyketones

Synthesis of functional aliphatic polyketones was achieved by co‐ and terpolymerization of the strained exo‐methylenecycloalkane, methylenecyclopropane (MCP), and also the dienes 1,5‐hexadiene, 1,7‐octadiene and 1,6‐heptadien‐4‐ol, with carbon monoxide and propene, using the dicationic palladium(II) phosphine complex [Pd(dppp) (NCCH₃)₂](BF₄)₂ (I) (dppp is 1,3‐bis(diphenyl‐phosphino)propane) as the catalyst precursor. The resulting MCP/CO copolymer contains both ring‐opened and cyclic microstructures. Ring‐opening copolymerization yields exo‐methylene functionalized polyketone. In contrast to hexadiene/carbon monoxide copolymer (Hx/CO), no ring structures were observed in the alternating octadiene/carbon monoxide (Oc/CO) and heptadien‐4‐ol/carbon monoxide (Hp‐ol/CO) copolymers. The remaining double bonds were left intact to yield polymers with olefinic functionalities in the side chains. © 2001 Society of Chemical Industry     

Dynamic analysis of a bistable actuator for digital hydraulics

A fast and small electromagnetic actuator, which requires a small amount of work to switch between two stable positions, for the use in digital hydraulics, is presented. A dynamic study of the bistable actuator as part of a new kind of hydraulic on/off valve is carried out. A prototype is built and measured to verify the analysis. The results show that with careful elaboration the design is feasible. Furthermore, the response times depend on driving frequencies and an optimal current density for minimal energy consumption in cyclic action can be found. A single on/off valve is a critical part of a digital hydraulic system.     

Increase of N2O Fluxes in Agricultural Peat and Sandy Soil under Elevated CO2 Concentration: Concomitant Changes in Soil Moisture, Groundwater Table and Biomass Production of Phleum pratense

The effects of elevated atmospheric CO₂ concentration on soil moisture, N₂O fluxes, and biomass production of Phleum pratense were studied in the laboratory. Farmed peat and sandy soil mesocosms sown with P. pratense were fertilized with a commercial fertilizer. In peat soil 10 g N m⁻² of commercial fertilizer were added and in sandy soil 15 g N m⁻². In both experiments, soil moisture was regulated with deionized water; 18 mesocosms were tended to keep equally moist, and the other 18 were watered with equal amounts of water. Nine mesocosms from both watering treatments were grown under ambient (360 μmol mol⁻¹) CO₂ concentration and the remaining nine under doubled (720 μmol mol⁻¹) CO₂. N₂O efflux was monitored using a closed chamber technique and a gas chromatograph. The elevated supply of CO₂ increased production of above- and belowground biomass, soil moisture and N₂O fluxes, but decreased the total N content in the aboveground biomass, especially for the sandy soil. In similar water levels, N₂O efflux from the sandy soil was the same magnitude as that from the peat soil. In addition to moisture, N availability was the main limiting factor for N₂O production, but C availability also seemed to regulate the denitrification activity. In addition to an increase in C availability the increase in the N₂O efflux under the raised CO₂ concentration also required a simultaneous increase in soil moisture.     

Design of non-paraxial array illuminators by step-transition perturbation approach

Abstract

We introduce an efficient Fourier-domain formulation of an approximate method to model non-paraxial diffractive elements. The method is based on evaluation of local field perturbations caused by abrupt surface-profile transitions. It facilitates fast parametric optimization of binary and four-level diffractive array illuminators in the non-paraxial domain of diffractive optics. Comparison with rigorous electromagnetic theory of gratings shows that optimization with the perturbation method gives accurate results if the smallest feature size in the surface profile is larger than one wavelength. Some binary designs are demonstrated using electron beam lithography.     

Volume integral equations in non-linear 3-D magnetostatics

In this paper a discussion of volume integral formulations in three-dimensional non-linear magnetostatics is presented. Integral formulations are examined in connection with Whitney's elements in order to find new approaches. A numerical algorithm based on a formulation implying properly the continuity conditions of magnetic field strength H, i.e. an h-type formulation, is introduced. Results of demanding application problems are shown demonstrating the characteristics of this kind of volume integral approach. In addition, a discussion of the parallelized version of the numerical code based on the h-type approach is presented appended with numerical results illustrating the advantages of combining integral formulations with concurrent computing.     

Improved Soft-Output RAKE Receiver for CDMA Mobile Terminals with High Data Rates

In this paper we propose a soft-output RAKE receiver for CDMA mobile terminals using low spreading factor and/or high-order modulation constellations for high data rates. Based on the outputs of theRAKE correlator fingers, the receiver produces symbol or bit metrics for soft decision decoding. The formulation of these metrics is derived analytically taking into account the multipath propagation, interfering users and channel estimation errors. Simulations show thata performance gain is achieved when low spreading factors or high-order modulation constellations are used.     

Densification of plasma-sprayed titanium and tantalum coatings

Thermal spraying of corrosion- resistant coatings of titanium and tantalum is difficult; dense coatings are not produced, and oxidation of these metals increases coating porosity. In this study, oxidation during plasma spraying was reduced with a shrouding system. Porosity and oxide content also were minimized by optimizing the spraying parameters. After optimization, the coatings still had open porosity and thus were incapable of protecting the substrate material against corrosion in water solutions containing 3 % NaCl. Therefore, posttreatments for improvement of corrosion resistance were studied. Electron beam fusion produced corrosion resistance equal to or better than that of bulk commercial samples of titanium and tantalum.