城市土壤环境监测点位布设应用述评

城市土壤环境质量与人体健康息息相关,日益受到人们关注.本文综述了城市土壤环境监测点位布设的应用进展,比较了各方法的优缺点,并对今后城市土壤环境监测点位布设方法的选取提出了建议,以期能为我国城市土壤环境监测和相关研究提供参考.     

乙二胺四乙酸四钠盐缓释微胶囊的制备与表征

The microcapsules with cores of ethylenediamine tetraacetic acid tetrasodium salt (Na4-EDTA) and walls of polyurea were synthesized via an interfacial polycondensation reaction with 2,4-tolylene diisocyanate as an oil-soluble monomer and diethyl triamine as a water-soluble monomer. Various manufacturing parameters, including the amount of emulsifier, agitation speed, stirring time and ratios of the wall materials to core materials, were altered to optimize process variables during the synthesis of microcap-sules, and the effects of these parameters on the characteristics of the microcapsules were examined. The structure, morphology, mean particle size and size distribution were characterized by optical microscope and scanning electron microscopy (SEM), showing that the mean diameter of optimal microspheres was approximately 6 μm, and microcapsules were spherical. In vitro release of Na4-EDTA from these microcapsules was performed in distilled water. Under the optimal preparation conditions, the Na4-EDTA re-lease profiles were biphasic with a burst release followed by a gradual release phase. After an initial burst, a continuous Na4-EDTA release was up to 5-7 days. The optimal synthesis conditions for the microcapsules with stable, good morphology and good con-trolled-release properties were as follows: emulsifier Span-80 10% (by mass), agitation speed 900 r&;#8226;min－1, stirring time 30 min, and the ratio of the wall materials to core materials 0.15.