Several ways to produce porous carbon monoliths by template assisted routes

Several ways to produce microporous and mesoporous carbon monoliths by template assisted synthesis routes are described. Pressed zeolite (HY) and silica powder tablets have been used as templates. Sucrose acts as a carbon precursor and as a binder between the carbon particles as well. In the case of zeolite template, the carbon porosity could be increased by additional loading of the template with ethene. Due to the balance between mechanic stability and porosity of the carbon monolith, an optimal amount of sucrose is required. The final products were characterized by low temperature nitrogen adsorption.     

Extended bisection method for parameter identification of the transient heat conduction equation for thermo-elastic deformations during drilling

A new interdisciplinary approach is discribed to identifying unknown parameters using an extended version of the known interval bisection method. This developed method is based on the use of finite elements for calibrating the simulation calculation. The resulting thermo-elastic deformations which occur in drilling processes with impaired cooling lubrication are to be used as correction values for tool positioning in the NC control. Based on the strong impact on workpiece temperature of machining, a simulation approach is presented for calculating the temperature fields and their thermo-elastic consequences. In addition, methods are presented to correct these effects. This paper particularly deals with the temperature fields of drilling operations. Special attention is paid to the technique employed for iterative numerical determination of the unknown heat flux η _w and heat transfer coefficient \(\bar {\gamma }\) values. Finally, the data obtained from experiments are compared with those achieved by numerical simulation in order to verify the efficiency of simulation and determination of parameters.     

R-Curve Behavior and Crack-Closure Stresses in Barium Titanate and (Mg,Y)-PSZ Ceramics

R -curves, process zones, and shielding stresses of barium titanate (BaTiO₃) and partially stabilized zirconia (PSZ) have been studied using compact-tension (CT) specimens. BaTiO₃ and PSZ exhibited pronounced R -curves that rose over similar crack lengths and showed steady-state toughnesses of 0.7 and 6.4 MPa·m^1/2, respectively. Both steady-state toughnesses were ∼80% larger than the initial fracture toughnesses. Ferroelastic domain switching was the main toughening mechanism in BaTiO₃, whereas, in PSZ, transformation toughening was the main toughening mechanism. The crack process zone and crack-opening-displacement (COD) profile of each material was studied in detail using atomic force microscopy. Crack-closure-stress distributions were extracted from the COD profiles, using weight-function methods. The resulting stress profiles indicated that compressive residual stresses of 40 MPa in BaTiO₃ and 400 MPa in PSZ acted in a limited region behind the crack tip. In the PSZ, crack bridging seemed to be a competing mechanism to transformation toughening.     

Essential instabilities of fronts: bifurcation, and bifurcation failure

Various instability mechanisms of fronts in reaction-diffusion systems are analysed; the emphasis is on instabilities that have the potential to create modulated (i.e. time-periodic) waves near the primary front. Hopf bifurcations caused by point spectrum with associated localized eigenfunctions provide an example of such an instability. A different kind of instability occurs if one of the asymptotic rest states destabilizes: these instabilities are caused by essential spectrum. It is demonstrated that, if the rest state ahead of the front destabilizes, then modulated fronts are created that connect the rest state behind the front with small spatially periodic patterns ahead of the front. These modulated fronts are stable provided the spatially periodic patterns are stable. If, on the other hand, the rest state behind the front destabilizes, then modulated fronts that leave a spatially periodic pattern behind do not exist.     

Characterization of an Invertebrate-Type Dopamine Receptor of the American Cockroach,Periplaneta americana

We have isolated a cDNA coding for a putative invertebrate-type dopamine receptor (Peadop2) from P. americana brain by using a PCR-based strategy. The mRNA is present in samples from brain and salivary glands. We analyzed the distribution of the PeaDOP2 receptor protein with specific affinity-purified polyclonal antibodies. On Western blots, PeaDOP2 was detected in protein samples from brain, subesophageal ganglion, thoracic ganglia, and salivary glands. In immunocytochemical experiments, we detected PeaDOP2 in neurons with their somata being located at the anterior edge of the medulla bilaterally innervating the optic lobes and projecting to the ventro-lateral protocerebrum. In order to determine the functional and pharmacological properties of the cloned receptor, we generated a cell line constitutively expressing PeaDOP2. Activation of PeaDOP2-expressing cells with dopamine induced an increase in intracellular cAMP. In contrast, a C-terminally truncated splice variant of this receptor did not exhibit any functional property by itself. The molecular and pharmacological characterization of the first dopamine receptor from P. americana provides the basis for forthcoming studies focusing on the significance of the dopaminergic system in cockroach behavior and physiology.     

Peanut varieties with reduced Ara h 1 content indicating no reduced allergenicity

Peanut allergy is a major cause of food‐induced severe anaphylactic reactions. To date, no medical care is available to prevent and treat peanut allergy and therefore hypoallergenic peanut varieties are of considerable health political and economic interest. Major allergens that induce IgE‐responses in peanut‐sensitive patients are Ara h 1, Ara h 2 and Ara h 3/4. In order to identify hypoallergenic peanuts, commercially locally available peanut varieties were screened for their allergen content. Ara h 1‐deficient peanuts from Southeast Asia were identified by SDS‐PAGE, immunoblotting, inhibition assays and ELISA. 2‐D PAGE analyses demonstrated the different compositions of the tested extracts and revealed a number of variations of the allergen patterns of peanuts from different varieties. Mediator release experiments of these peanut extracts demonstrated similar allergenicities as compared with standard peanut extract. These results indicate that the allergenicity of peanuts with reduced Ara h 1 content might be compensated by the other allergens, and thus do not necessarily cause a reduction of allergenicity.