Strength of Cracked Steel Structural Components at Negative Temperatures

Predictions of the strength of cracked steel structural components at negative temperatures are considered. The elastoplastic stress–strain state of samples at destructive loads is studied by finite-element analysis.     

Thermochemical Stability of Extraction Systems for SNF Processing

Radiochemistry - Thermal stability of extraction systems containing N,N,N′,N?′-tetra-n-octyldiglycolamide (TODGA), di(N-ethyl-4-hexylanilide)...     

Special Features of Structure Formation in Deposited Metal Based on Alloyed Nickel Aluminide and its High-Temperature Properties

Metal Science and Heat Treatment - Special features of structure and phase formation in deposited metal based on alloyed Ni3 Al nickel aluminide formed due to high-gradient crystallization under...     

Optical Spectroscopic Analysis of the Quality of the Solvent Used for Gel-Spinning of Ultra-High-Molecular-Weight Polyethylene

Fibre Chemistry - An optical spectroscopic method for analyzing the quality of the solvent used for gel-spinning of ultra-high-molecular-weight polyethylene was proposed using Vaseline oil (VO) as...     

Improving the quality of layers deposited on rolling rolls by optimising the composition of flux-cored wires

ABSTRACT

Experiments were carried out to investigate the effect of adding carbon–fluorine compounds (the waste from metallurgical production) and nickel powder to the composition of flux-cored wires of the C–Si–Mn–Cr–W–V and C–Si–Mn–Cr–V–Mo alloying systems. The results show that the addition of these compounds to the composition of the charge for producing the wires of the 35V9Kh3SF and 25Kh5FMS types improves a large number of the characteristics of the deposited layer: reduces the extent of contamination with non-metallic inclusions, increases the hardness of the deposited layer, refines austenite grains and results in the formation of fine-dispersion carbides which in practice may improve the thermal resistance of rolling rolls, and also prevents the formation of a ferrite network which may have a beneficial effect on cracking resistance. The experimental results can be used to develop new compositions of flux-cored wires for hardfacing rolling rolls protected by Russian Federation patents. The hardfacing technologies of the rolls using these flux-cored wires with the C–Si–Mn–Cr–W and C–Si–Mn–Cr–V–Mo alloying systems are now produced by the ElSib company.     

A globally exponentially stable speed observer for a class of mechanical systems: experimental and simulation comparison with high-gain and sliding mode designs

It is shown in the paper that the problem of speed observation for mechanical systems that are partially linearisable via coordinate changes admits a very simple and robust (exponentially stable) solution with a Luenberger-like observer. This result should be contrasted with the very complicated observers based on immersion and invariance reported in the literature. A second contribution of the paper is to compare, via realistic simulations and highly detailed experiments, the performance of the proposed observer with well-known high-gain and sliding mode observers. In particular, to show that – due to their high sensitivity to noise, that is unavoidable in mechanical systems applications – the performance of the two latter designs is well below par.     

Dielectric Properties of Ultrathin CaF2 Ionic Crystals

Mechanically exfoliated 2D hexagonal boron nitride (h-BN) is currently the preferred dielectric material to interact with graphene and 2D transition metal dichalcogenides in nanoelectronic devices, as they form a clean van der Waals interface. However, h-BN has a low dielectric constant (≈3.9), which in ultrascaled devices results in high leakage current and premature dielectric breakdown. Furthermore, the synthesis of h-BN using scalable methods, such as chemical vapor deposition, requires very high temperatures (>900 °C) , and the resulting h-BN stacks contain abundant few-atoms-wide amorphous regions that decrease its homogeneity and dielectric strength. Here it is shown that ultrathin calcium fluoride (CaF₂) ionic crystals could be an excellent solution to mitigate these problems. By applying >3000 ramped voltage stresses and several current maps at different locations of the samples via conductive atomic force microscopy, it is statistically demonstrated that ultrathin CaF₂ shows much better dielectric performance (i.e., homogeneity, leakage current, and dielectric strength) than SiO₂, TiO₂, and h-BN. The main reason behind this behavior is that the cubic crystalline structure of CaF₂ is continuous and free of defects over large regions, which prevents the formation of electrically weak spots.