Corrosion inhibition of mild steel in 1 M HCl using Tamarindus indica extract: electrochemical,surface and spectroscopic studies

Abstract

We report, here, the corrosion inhibition of mild steel specimen in 1?M HCl by tamarind fruit pulp aqueous (TFPA) extract. The inhibition property in the presence of TFPA extract is studied using weight loss, polarization measurement and electrochemical impedance spectroscopy (EIS). The inhibitor efficiency is found to vary from 74% to 88% (weight loss method) with TFPA concentration of 100–600?ppm. The reduction in Tafel slopes shows that TFPA acts as a mixed-type inhibitor. The adsorption of the inhibitor on the metal surface follows Langmuir isotherm. The standard Gibbs free energy of adsorption value of –40?kJ/mol suggests the chemisorption of inhibitor molecules via coordinate bond. AFM results exhibit a decrease in the surface roughness of mild steel, exposed to 1?M HCl from 299?±?12 to 154?±?6.6?nm, with increasing concentration of inhibitor from 0 to 600?ppm due to the uniform coverage of inhibitor molecules on the metal surface. X-ray photoelectron spectroscopy de-convoluted high resolution profiles of C 1?s (carbon) for mild steel exposed to 1?M HCl with 600?ppm inhibitor show major peaks corresponding to sp³ C–C/C–H (284.9?eV) and oxygen bondings in C–OH, C=O, COOH with a binding energy of 285.9, 286.9, 288.5?eV, respectively, thereby confirming the adsorption of organic moieties on mild steel surface. Fourier transform infrared spectroscopy further confirms the adsorption of inhibitor molecules on the metal surface. Therefore, tamarind fruit pulp extract is a potential corrosion inhibitor for mild steel, which is cost-effective, green and non-toxic.     

Transport and solvent sensing characteristics of styrene butadiene rubber nanocomposites containing imidazolium ionic liquid modified carbon nanotubes

Obtaining strong interfacial interaction between filler and polymer matrix is very crucial for the fabrication of polymer nanocomposites with superior performance. Present study is aimed to fabricate high performance styrene butadiene rubber (SBR) nanocomposites with imidazolium type ionic liquid modified multiwalled carbon nanotube (MWCNT). Ionic liquid facilitates the dispersion of MWCNT in rubber matrix and it is obvious from transmission electron microscopy images. Diffusion of toluene through SBR nanocomposite membranes has been investigated as a function of surface modified MWCNT (f-MWCNT) content to analyze the chain dynamics and filler-polymer interactions. O₂ gas barrier effect of nanocomposites with special reference to the filler loading is explored. The substantial improvement in the barrier effect in presence of filler interpreted on the grounds of a theoretical model describing permeability of heterogeneous systems. Finally solvent sensing characteristics of prepared nanocomposites are also analyzed and it is observed that prepared nanocomposites can be used as a flexible solvent sensor.     

Adjuvant properties of a biocompatible thermo-responsive polymer of N-isopropylacrylamide in autoimmunity and arthritis

To evaluate the thermo-responsive poly(N-isopropylacrylamide) (PNiPAAm) polymer as an adjuvant, we synthesized PNiPAAm through free radical polymerization and characterized it both in vitro and in vivo. The polymer when mixed with collagen type II (CII) induced antigen-specific autoimmunity and arthritis. Mice immunized with PNiPAAm–CII developed significant levels of CII-specific IgG response comprising major IgG subclasses. Antigen-specific cellular recall response was also enhanced in these mice, while negligible level of IFN-γ was detected in splenocyte cultures, in vitro. PNiPAAm–CII-immunized arthritic mouse paws showed massive infiltration of immune cells and extensive damage to cartilage and bone. As determined by immunostaining, most of the CII protein retained its native configuration after injecting it with PNiPAAm in naive mice. Physical adsorption of CII and the high-molecular-weight form of moderately hydrophobic PNiPAAm induced a significant anti-CII antibody response. Similar to CII, mice immunized with PNiPAAm and ovalbumin (PNiPAAm–Ova) induced significant anti-ovalbumin antibody response. Comparable levels of serum IFN-γ, IL-1β and IL-17 were observed in ovalbumin-immunized mice with complete Freund, incomplete Freund (CFA and IFA) or PNiPAAm adjuvants. However, serum IL-4 levels were significantly higher in PNiPAAm–Ova and CFA–Ova groups compared with the IFA–Ova group. Thus, we show for the first time, biocompatible and biodegradable thermo-responsive PNiPAAm can be used as an adjuvant in several immunological applications as well as in better understanding of the autoimmune responses against self-proteins.     

CuInxGa1−xSe2 thin films prepared by electron beam evaporation

CuIn_xGa_1−xSe₂ bulk compound of three different compositions x=0.75, 0.80 and 0.85 have been prepared using individual elements of copper, indium, gallium and selenium. Thin films of CuIn_xGa_1−xSe₂ have been deposited using the prepared bulk by electron beam evaporation method. The structural studies carried on the deposited films revealed that films annealed at 400 °C are crystalline in nature exhibiting chalcopyrite phase. The position of the (1 1 2) peak in the X-ray diffractogram corresponding to the chalcopyrite phase has been found to be dependent on the percentage of gallium in the films. The composition of the prepared bulk and thin films has been identified using energy dispersive X-ray analysis. The photoluminescence spectra of the CuIn_xGa_1−xSe₂ films exhibited sharp luminescence peaks corresponding to the band gap of the material.     

Steady laminar flow in a 90 degree planar branch

The flow characteristics of a Newtonian fluid in a two-dimensional, planar, right angled Tee branch are studied over a range of inlet Reynolds number of 10–800 by solving the Navier-Stokes equations using a finite element discretization. The effects of the branch length and the grid size on the interior flow field are examined to assess the accuracy of the solutions. In one case the computed velocity field is compared with the Laser Doppler anemometry measurements available in the literature and excellent agreement has been obtained. The computed velocity field is believed to be accurate within about 5%. Results are presented for two types of experimentally realizable boundary conditions—viz. equal exit pressure at the outlet of each branch and specified flow split between the branches. For the case of equal exit pressures the fractional flow in the main duct increases with increasing Reynolds number and the flow characteristics in the side branch become akin to that in a cavity. For the case of specified flow split, the number, size and strength of the recirculation zones increase as more fluid is forced to go into the side branch. The length of the side branch appears to have very little influence on the interior flow field, particularly at higher Reynolds number. This observation is rationalized as being due to the parabolized approximation becoming more valid at higher Reynolds numbers. The critical Reynolds number at which the first recirculation zone appears in the side branch increases with increasing fractional flow in the side branch and with decreasing side branch width.     

Telemedicine and tele-health services for cancer-care delivery in India

Noncommunicable diseases including cancer are emerging as major public health problems in India. Awareness of cancer and its management are being taken as a high priority at the national level because of the increase in the incidence of the disease in the country. Telemedicine provides expert-based health care to understaffed remote sites and advanced emergency care through modern telecommunication and information technologies. The incidence of cancer can be reduced if the people are aware of cancer and its root causes. Recently, the introduction of telemedicine in oncology plays a vital role. Telemedicine helps in prevention, early detection, a faster cure, palliative care and rehabilitation in the management of cancer. The status of telemedicine services for cancer care in Kerala, India, and how telemedicine can be an effective solution of cancer- care delivery in India are explored.     

Nonisothermal modeling of heat transfer inside an internal batch mixer

A nonisothermal transient process of temperature increase due to viscous heating was simulated for a 69 cm³ internal batch mixer (BM) using a computational fluid dynamics (CFD) software, Polyflow 3.9 form ANSYS, Inc., to obtain the temporal temperature distribution and characterize the heat transfer between polymer melt and mixer wall. The melt temperature obtained from simulation was verified with experiments. Starting from a uniform temperature of 463 K, when a rotation speed of 5.24 rad/s is imposed, viscous heating caused a maximum temperature rise of 3 K for a polyethylene (PE) resin, and 6 K for a polystyrene (PS) resin. The transient flow fields inside the batch mixer were characterized with velocity profiles and a mixing index parameter, which show that laminar flow dominates inside the mixer while a small percentage of elongational flow, converging flow, and recirculation flow is also present. © 2010 American Institute of Chemical Engineers AIChE J, 2011     

Nickel–Alumina Functionally Graded Materials by Electrophoretic Deposition

Electrophoretic deposition has been used to synthesize nickel–alumina, functionally graded materials from NiO and alumina suspensions in ethanol. Suspension stability and the kinetics of deposition were studied to determine optimum conditions. Deposition starts with an alumina suspension into which a stream of NiO suspension is injected at various flow rates to obtain the desired profiles. The latter were controlled by varying the deposition current density and component flow rate. The green bodies obtained were sintered in Ar/H₂ atmosphere to reduce the NiO to nickel. Various gradation profiles were obtained illustrating the facility of EPD to synthesize continuously graded materials. NiO was used as the precursor for nickel to alleviate settling and rough columnar deposit problems.