Storage and permeation of hydrogen molecule,atom and ions (H+ and H−) through silicon carbide nanotube; a DFT approach

The barriers for the encapsulation and decapsulation of hydrogen ions (cationic hydrogen and hydride), atom, and molecule through silicon carbide nanotube are thoroughly studied. DFT method is selected to measure the kinetic barriers for the passage of hydrogen atom, ions and molecule through nanotube via scanning potential energy surface. The kinetic barriers for the passage (encapsulation and decapsulation) of hydrogen are very important to understand the mechanism of hydrogen storage and release. The barriers for the permeation of H, H⁺ and H^? across SiC nanosheet are lower compared to hydrogen molecule (H₂). The exohedral and endohedral adsorption of hydrogen ions (cation and anion), atom and exohedral hydrogen molecule on silicon carbide are exothermic in nature. Whereas the encapsulation of hydrogen molecule in silicon carbide is endothermic. Electronic properties are analyzed through measurement of energy gap between highest occupied and lowest unoccupied molecular orbitals gap (G_H-L) and the density of state (DOS) spectra. The G_H-L analysis reveals that endohedral complexes have more pronounced effect on electronic properties compared to exohedral complexes. The SiC nanotube has highly favorable properties for storage and release of hydrogen ions, and atom.     

Peanut FAD2 Genotype and Growing Location Interactions Significantly Affect the Level of Oleic Acid in Seeds

The level of oleic acid is an important parameter in determining seed nutritional quality and oil stability. The level of oleic acid in peanut is genetically controlled by a pair of fatty acid desaturase genes (FAD2A and FAD2B), but the environmental conditions of the production sites can also have a significant effect. To investigate the effect of gene and environment interaction, 45 accessions were grown at three locations for 2 years. Environmental data were collected; individual plants were genotyped with functional SNP markers from FAD2A and FAD2B; and seed level of oleic acid was determined by gas chromatography. Three FAD2A/FAD2B genotypes (448G/no insertion 442A, 448A/no insertion 442A, and 448A/insertion 442A) were identified and designated as G/W, A/W, and A/A, respectively. A/A genotype averaged the highest level of oleic acid (80.0%), followed by A/W (56.0%), and then G/W (40.7%). Analysis of gene and environment interaction revealed that oleic acid phenotype plasticity could be explained by the interaction of FAD2 genotype and photothermal time, which quantified environmental conditions. The A/W genotype was the most sensitive to photothermal time changes. The oleic acid plasticity revealed in this study would be useful for breeders, farmers, and product processors.     

Spectroscopic and Simulation Analysis of Facile PEDOT:PSS Layer Deposition-Silicon for Perovskite Solar Cell

In this research work, we have characterized and simulated a well-known hole transport material (HTM) for perovskite solar cell (PSC) and conductive polyme     

Thermal Mixing of Impinging Laminar Streams of Shear-Thinning Fluids

Abstract

Thermal mixing behavior of shear-thinning fluids with the specified heat flux boundary condition at mixing zone walls is studied numerically to investigate the effect of Reynolds number (10 to 50), power-law index (0.6161 to 1), Nusselt number (10⁴ to 10⁶) for external air flows and dimensionless ambient temperature (?2.7 to 1.3). The temperature is a passive tracer that quantifies the degree of mixing in this study. Detailed kinematics shows the formation of recirculation zones at the mixing channel walls. Length required to achieve the well mixed condition (i.e., a flat temperature profile across the channel height) is shorter at low Reynolds number, convective heat transfer coefficient and ambient temperature, and high power-law index values. In the impingement zone, a faster reduction in mixing index has been observed with respect to mixing length at high power-law index and low Reynolds numbers, while Nusselt number and ambient temperature exert only a weak influence. Under appropriate conditions, significant energy exchange between the system and surroundings can occur and has been analyzed in detail in this work. This work finds its applications in the improved mixing as practiced in the processing and production of food-stuffs, fine chemicals, personal care products, etc.     

An enhanced security mechanism through blockchain for E-polling/counting process using IoT devices

Wireless Networks - One of the biggest challenges in political mayhem is visible during the election process where no stone is kept unturned in order to gain the power. Further, due to poll...     

A two stage neural network for choosing optimal ejection parameters in low altitude seat ejection based on novel injury parameter

Optimization and Engineering - Aircraft ejection systems are lifesaving devices used, in case of emergencies for military pilots. As per current literature the success rate of ejections happening...     

Powder Compaction Dies and Compressibility of Various Materials

Powder Metallurgy and Metal Ceramics - Powder compaction is the most crucial process in powder metallurgy since almost all the desired properties of a material, such as a shape, size, density,...     

Gate All Around Dopingless Nanotube TFET Biosensor with Si0.5Ge0.5 – Based Source

Silicon - Through this paper, we discuss how Tunnel Field Effect Transistors can be utilized for the detection of biomaterials hence acting as a biosensor. The device proposed is a 3-D Doping less...     

Functionally modified gelatin microspheres as a growth factor’s delivery system: development and characterization

One of the advances in biotechnology has been the development of the capability to produce large quantities of highly purified polypeptides and proteins. Unfortunately, the circulatory half-lives of many of these agents are short, usually of the order of minutes and the time required for a response in tissues is usually long compared to the half-life. Hence, there is always demand for polymeric systems which can deliver the proteins for prolonged period and also to protect the molecules from degradation. The present work was attempted to develop heparin-functionalized gelatin microspheres (HMS) to deliver heparin-binding growth factors particularly for wound-healing applications. The heparin conjugation was carried out using EDC/NHS coupling protocol. Heparin-binding EGF-like growth factor (HB-EGF) was loaded in HMS and its in vitro release behaviour in an environment with or without proteases was studied. The bioactivity of the HB-EGF released from the microspheres was assessed using NIH 3T3 mouse embryonic fibroblast culture. The extent of heparin modification was found to be 1.97 μmol/g of HMS and demonstrated significant protection against enzymatic degradation and sustained release of HB-EGF for more than 10 days. The bioactivity of HB-EGF released from the HMS was retained during the observed release period. The HMS was also found to be non-toxic as determined by calcein AM fluorescent staining. The overall study suggests that the HMS could be used as a growth factor’s delivery component in tissue engineering scaffolds particularly for wound-healing applications.